Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal     

A. van Geen  K. Radloff  Z. Aziz  Z. Cheng  M.R. Huq  K.M. Ahmed  B. Weinman  S. Goodbred  H.B. Jung  Y. Zheng  M. Berg  P.T.K. Trang  L. Charlet  J. Metral  D. Tisserand  S. Guillot  S. Chakraborty  A.P. Gajurel  B.N. Upreti 《Applied Geochemistry》2008

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.  相似文献   

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry     

Martha Gledhill  Constant M. G. van den Berg 《Marine Chemistry》1995,50(1-4)

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.  相似文献   

A Gamma/Dirichlet model for estimating uncertainty in age-specific abundance of Norwegian spring-spawning herring     

Host  Gudmund; Berg  Erlend; Schweder  Tore; Tjelmeland  Sigurd 《ICES Journal of Marine Science》2002,59(4):737-748

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Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties   总被引：1，自引：0，他引：1  

Elena Piñero  Eulàlia Gràcia  Francisca Martínez-Ruiz  Juan Cruz Larrasoaña  Alexis Vizcaino  Gemma Ercilla 《Geo-Marine Letters》2007,27(2-4):279-288

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.  相似文献   

The Creation of a National Agricultural Land Use Dataset: Combining Pycnophylactic Interpolation with Dasymetric Mapping Techniques     

Alexis Comber  Chris Proctor  Steve Anthony 《Transactions in GIS》2008,12(6):775-791

Agricultural Census data is summarised over spatially coarse reporting units for reasons of farm confidentiality. This is problematic for research at a local level. This article describes an approach combining dasymetric and volume preserving techniques to create a national land use dataset at 1 km² resolution. The results for an English county are compared with contemporaneous aggregated habitat data. The results show that the accurate estimates of local agricultural land use (Arable and Grass) patterns can be estimated when individual 1 km squares are combined into blocks of > 9 squares, thereby providing local estimates of agricultural land use. This in turn allows more detailed modelling of land uses related to specific livestock and cropping activities. The dataset created by this work has been subject to extensive external validation through its incorporation into a number of other national models: nitrate leaching (e.g. MAGPIE, NEAP‐N), waste, and pathogen modelling related to agricultural activity.  相似文献   

An integral equation approach for 2.5-dimensional forward and inverse electromagnetic scattering     

Aria Abubakar  Peter M van den Berg  Tarek M Habashy 《Geophysical Journal International》2006,165(3):744-762

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Towards non-linear inversion for characterization of time-lapse phenomena through numerical modelling     

A. Abubakar  P.M. van den Berg  J.T. Fokkema 《Geophysical Prospecting》2003,51(4):285-293

We compare two geophysical survey measurements of the same type made at different times in order to characterize the change in the geological medium during the elapsed time. The aim of this study is to develop a strategy using a full non-linear inversion algorithm as the interpretation tool. In this way, not only the location and the form of the changes are recovered, but also the changes in the material parameters of the geological medium can be estimated. In order to solve this fully non-linear problem, the so-called ‘multiplicative regularized contrast source inversion’ (MR-CSI) method is employed. The unique property of this iterative method is that it does not solve the forward problem at each iterative step. This makes it possible to use the non-linear inversion algorithm for large-scale computation problems. The numerical results show that by taking into account the non-linear nature of the problem, interpretation of the time-lapse data can be significantly improved, compared with that obtained using linear inversion.  相似文献   

用MODIS遥感资料分析四川盆地气溶胶光学厚度时空分布特征   总被引：25，自引：1，他引：25       下载免费PDF全文

李成才  刘启汉等 《应用气象学报》2003,14(1):1-7

利用MODIS卫星遥感光学厚度产品，分析了四川盆地光学厚度分布和季节变化特征。由于受沙尘天气的影响，春季四川盆地具有最大的平均光学厚度。盆地内几个大值区中，西部成都一带的中心常年维持，季节变化小；南部中心位于宜宾到重庆沿长江流域一带；东部南充到重庆间的大值中心，季节变化大，在夏季消失。光学厚度分布和季节变化的数据结果为研究区域气候变化提供了依据。  相似文献   

Seismic velocities of granulite-facies xenoliths from Central Ireland: Implications for lower crustal composition and anisotropy     

Riana van den Berg  J. Stephen Daly  Matthew H. Salisbury   《Tectonophysics》2005,407(1-2):81-99

V_p and V_s values have been measured experimentally and calculated for granulite-facies lower crustal xenoliths from central Ireland close to the Caledonian Iapetus suture zone. The xenoliths are predominantly foliated and lineated metapelitic (garnet–sillimanite–K-feldspar) granulites. Their metapelitic composition is unusual compared with the mostly mafic composition of lower crustal xenoliths world-wide. Based on thermobarometry, the metapelitic xenoliths were entrained from depths of c. 20–25 ± 3.5 km and rare mafic granulites from depths of 31–33 ± 3.4 km. The xenoliths were emplaced during Lower Carboniferous volcanism and are considered to represent samples of the present day lower crust.V_p values for the metapelitic granulites range between 6.26 and 7.99 km s^{− 1} with a mean value of 7.09 ± 0.4 km s^{− 1}. Psammite and granitic orthogneiss samples have calculated V_p values of 6.51 and 6.23 km s^{− 1}, respectively. V_s values for the metapelites are between 3.86 and 4.34 km s^{− 1}, with a mean value of 4.1 ± 0.15 km s^{− 1}. The psammite and orthogneiss have calculated V_s values of 3.95 and 3.97 km s^{− 1}, respectively.The measured seismic velocities correlate with density and with modal mineralogy, especially the high content of sillimanite and garnet. V_p anisotropy is between 0.15% and 13.97%, and a clear compositional control is evident, mainly in relation to sillimanite abundance. Overall V_s anisotropy ranges from 1% to 11%. Poisson's ratio (σ) lies between 0.25 and 0.35 for the metapelitic granulites, mainly reflecting a high V_p value due to abundant sillimanite in the sample with the highest σ. Anisotropy is probably a function of deformation associated with the closure of the Iapetus ocean in the Silurian as well as later extension in the Devonian. The orientation of the bulk strain ellipsoid in the lower crust is difficult to constrain, but lineation is likely to be NE–SW, given the strike-slip nature of the late Caledonian and subsequent Acadian deformation.When corrected for present-day lower crustal temperature, the experimentally determined V_p values correspond well with velocities from the ICSSP, COOLE I and VARNET seismic refraction lines. Near the xenolith localities, the COOLE I line displays two lower crustal layers with in situ V_p values of 6.85–6.9 and 6.9–8.0 km s^{− 1}, respectively. The upper (lower velocity) layer corresponds well with the metapelitic granulite xenoliths while the lower (higher velocity) layer matches that of the basic granulite xenoliths, though their metamorphic pressures suggest derivation from depths corresponding to the present-day upper mantle.  相似文献   

Why chromatic imaging matters     

Joel Sanchez-Bermudez  Florentin Millour  Fabien Baron  Roy van Boekel  Laurent Bourgès  Gilles Duvert  Paulo J. V. Garcia  Nuno Gomes  Karl-Heinz Hofmann  Thomas Henning  Jacob W. Isbell  Bruno Lopez  Alexis Matter  J-Uwe Pott  Dieter Schertl  Eric Thiébaut  Gerd Weigelt  John Young 《Experimental Astronomy》2018,46(3):457-473

During the last two decades, the first generation of beam combiners at the Very Large Telescope Interferometer has proved the importance of optical interferometry for high-angular resolution astrophysical studies in the near- and mid-infrared. With the advent of 4-beam combiners at the VLTI, the u ? v coverage per pointing increases significantly, providing an opportunity to use reconstructed images as powerful scientific tools. Therefore, interferometric imaging is already a key feature of the new generation of VLTI instruments, as well as for other interferometric facilities like CHARA and JWST. It is thus imperative to account for the current image reconstruction capabilities and their expected evolutions in the coming years. Here, we present a general overview of the current situation of optical interferometric image reconstruction with a focus on new wavelength-dependent information, highlighting its main advantages and limitations. As an Appendix we include several cookbooks describing the usage and installation of several state-of-the art image reconstruction packages. To illustrate the current capabilities of the software available to the community, we recovered chromatic images, from simulated MATISSE data, using the MCMC software SQUEEZE. With these images, we aim at showing the importance of selecting good regularization functions and their impact on the reconstruction.  相似文献