‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry     

Haosheng Wu  Roman Bttger  Frdric Couffignal  Jens Gutzmer  Joachim Krause  Frans Munnik  Axel D. Renno  Ren Hübner  Michael Wiedenbeck  Ren Ziegenrücker 《Geostandards and Geoanalytical Research》2019,43(4):531-541

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.  相似文献   

Wet Fault or Dry Fault? A Laboratory Approach to Remotely Monitor the Hydro-Mechanical State of a Discontinuity Using Controlled-Source Seismics     

Joachim Place  Oshaine Blake  Daniel Faulkner  Andreas Rietbrock 《Pure and Applied Geophysics》2014,171(11):2887-2897

Stress variation and fluid migration occur in deformation zones, which are expected to affect seismic waves reflected off or propagating across such structures. We developed a basic experimental approach to monitor the mechanical coupling with respect to seismic coupling across a single discontinuity between a granite sample in contact with a steel platen. Piezoceramics located on the platen were used to both generate and record the P and S wave fields reflected off the discontinuity at normal incidence. This way, normal (B _n ) and tangential (B _t ) compliances were calculated using Schoenberg’s linear slip theory (Schoenberg, J Acoust Soc Am 68:1516–1521, 1980) when the roughness, the effective pressure (P _eff, up to 200 MPa), and the nature of the filling (gas or water) vary. We observe that increasing the effective pressure decreases B _n and B _t , which is interpreted as the effect of the closure of the voids at the interface, permitting more seismic energy to be transmitted across the interface. Values of B _n are significantly higher than those of B _t at low P _eff (<60–80 MPa) in dry conditions, and significantly drop under water-saturated conditions. The water filling the voids therefore helps to transmit the seismic energy of compressional waves across the interface. These results show that the assumption B _n  ≈ B _t commonly found in some theoretical approaches does not always stand. The ratio B _n /B _t actually reflects the type of saturating fluids and the effective pressure, in agreement with other experimental studies. However, we illustrate that only the relative variations of this ratio seem to be relevant, not its absolute value as suggested in previous studies. Consequently, the use of B _n against B _t plots may allow effective pressure variation and the nature of the pore fluid to be inferred. In this respect, this experimental approach at sample scale helps to pave the way for remotely monitoring in the field the hydro-mechanical state of deformation zones, such as seismogenic faults, fractured reservoirs, or lava conduits.  相似文献   

Spatial Periodic Boundary Condition for MODFLOW     

Tariq Laattoe  Vincent E.A. Post  Adrian D. Werner 《Ground water》2014,52(4):606-612

Small‐scale hyporheic zone (HZ) models often use a spatial periodic boundary (SPB) pair to simulate an infinite repetition of bedforms. SPB's are common features of commercially available multiphysics modeling packages. MODFLOW's lack of this boundary type has precluded it from being effectively utilized in this area of HZ research. We present a method to implement the SPB in MODFLOW by development of the appropriate block‐centered finite‐difference expressions. The implementation is analogous to MODFLOW's general head boundary package. The difference is that the terms on the right hand side of the solution equations must be updated with each iteration. Consequently, models that implement the SPB converge best with solvers that perform both inner and outer iterations. The correct functioning of the SPB condition in MODFLOW is verified by two examples. This boundary condition allows users to build HZ‐bedform models in MODFLOW, facilitating further research using related codes such as MT3DMS and PHT3D.  相似文献   

Reply to “Comment on ‘Small-scale heterogeneities below the Lanzhou CTBTO seismic array,from seismic wavefield fluctuation’ by Li Lei”     

Xuzhang Shen  Joachim R. R. Ritter 《Journal of Seismology》2011,15(1):171-172

  相似文献   

Impacts of Methane on Carbon Dioxide Storage in Brine Formations          下载免费PDF全文

Mohamad R. Soltanian  Mohammad A. Amooie  David R. Cole  Thomas H. Darrah  David E. Graham  Susan M. Pfiffner  Tommy J. Phelps  Joachim Moortgat 《Ground water》2018,56(2):176-186

In the context of geological carbon sequestration (GCS), carbon dioxide (CO₂) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH₄). In this multicomponent multiphase displacement process, CO₂ competes with CH₄ in terms of dissolution, and CH₄ tends to exsolve from the aqueous into a gaseous phase. Because CH₄ has a lower viscosity than injected CO₂, CH₄ is swept up into a ‘bank’ of CH₄‐rich gas ahead of the CO₂ displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO₂ front. On the other hand, the emergence of gaseous CH₄ is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO₂ if the cap rock is compromised. Open fractures or faults and wells could result in CH₄ contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH₄‐CO₂ mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH₄‐rich (up to 90 mol%) gas as a consequence of CO₂ injection, with important implications for the risk assessment of future GCS projects.  相似文献   

Effects of volume on travel distance of mass movements triggered by the 2005 Kashmir earthquake,in the Northeast Himalayas of Pakistan   总被引：1，自引：1，他引：0  

Muhammad Basharat  Joachim Rohn 《Natural Hazards》2015,77(1):273-292

  相似文献   

Zircon fission‐track ages from Newfoundland—A proxy for high geothermal gradients and exhumation before opening of the Central Atlantic Ocean     

Arne P. Willner  Stuart N. Thomson  Johannes Glodny  Hans‐Joachim Massonne  Rolf L. Romer  Cees R. van Staal  Alexandre Zagorevski 《地学学报》2019,31(1):1-10

Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.  相似文献   

The first field-based descriptions of pumping-induced saltwater intrusion and upconing     

Georg Houben  Vincent E. A. Post 《Hydrogeology Journal》2017,25(1):243-247

Development of the ideas about the equilibrium between freshwater and saline water has received considerable attention in the literature, but little has been written so far about the earliest scientific works about well salinization. Based on a review of the literature from the second half of the 19th century and the early 20th century, this historical note explores how insights into groundwater abstraction and saltwater intrusion developed, and examples of the earliest field studies are provided. Fundamental research was driven by the need for increasing water supply, but the progress of science did not lead to sustainable management practices everywhere. Research outcomes were shared between scientists of different countries, marking the beginning of coastal hydrogeology as a scientific specialization in the first decade of the 20th century.  相似文献   

Intergranular coesite and coesite inclusions in dolomite from the Dabie Shan: Constraints on the preservation of coesite in UHP rocks          下载免费PDF全文

Penglei Liu  Hans‐Joachim Massonne  Junfeng Zhang  Yao Wu  Zhenmin Jin 《地学学报》2017,29(3):154-161

Intergranular coesite is extremely rare in, and bears crucial information on the formation and preservation of, ultrahigh‐pressure (UHP) rocks. Here, we report the first occurrence of intergranular coesite in a metasedimentary rock, which occurs in the Ganjialing area in the Dabie Shan, east‐central China, and contains abundant coesite inclusions in both garnet and dolomite. We investigated the content of structural water in these minerals with Fourier transform infrared spectroscopy. Our new results undermine the ubiquity of the “pressure‐vessel” model and highlight the role of reaction kinetics in preserving coesite due to the availability of water in UHP rocks.  相似文献   

Higher-order compositional modeling with Fickian diffusion in unstructured and anisotropic media     

Joachim Moortgat  Abbas Firoozabadi 《Advances in water resources》2010

We present advances in compositional modeling of two-phase multi-component flow through highly complex porous media. Higher-order methods are used to approximate both mass transport and the velocity and pressure fields. We employ the Mixed Hybrid Finite Element (MHFE) method to simultaneously solve, to the same order, the pressure equation and Darcy's law for the velocity. The species balance equation is approximated by the discontinuous Galerkin (DG) approach, combined with a slope limiter. In this work we present an improved DG scheme where phase splitting is analyzed at all element vertices in the two-phase regions, rather than only as element averages. This approximation is higher-order than the commonly employed finite volume method and earlier DG approximations. The method reduces numerical dispersion, allowing for an accurate capture of shock fronts and lower dependence on mesh quality and orientation. Further new features are the extension to unstructured grids and support for arbitrary permeability tensors (allowing for both scalar heterogeneity, and shear anisotropy). The most important advancement in this work is the self-consistent modeling of two-phase multi-component Fickian diffusion. We present several numerical examples to illustrate the powerful features of our combined MHFE–dg method with respect to lower-order calculations, ranging from simple two component fluids to more challenging real problems regarding CO₂ injection into a vertical domain saturated with a multi-component petroleum fluid.  相似文献