Ozone production due to emissions from vegetation burning     

Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献   

Feasibility study of a multiple flyby mission of main belt asteroids     

A. Brahic  J. Breton  J. Caubel  A. Cazenave  P. Cruvellier  Y. Dupuis  B. Lago  J.F. Minster  A. Perret  A. Scribot 《Icarus》1979,40(3):423-433

Specific information on the surface morphology, composition, mean density, and internal structure of asteroids, which is necessary to advance our understanding of asteroids, can be obtained only by a detailed investigation of individual bodies: this will require space missions to individual targets. Since an essential characteristic of the asteroids is their variety, several objects must be visited. The Ariane launcher developed presently in Europe makes a multiple flyby mission possible. The first results of our feasibility study are particularly encouraging: during one revolution, five to six preselected main belt asteroids may be approached to within 1000 km with relative velocities which lie between 3 and 14 km/sec using a total impulse correction on the order of 1 to 2 km/sec. The weight of the spacecraft, excluding the engine and the propellant, would be at least 250 kg. This allows a scientific payload of 50 to 60 kg, in which priority will be given to an imaging system and radar altimeter.  相似文献   

Variscan ore formation and metamorphism at the Felbertal scheelite deposit (Austria): constraining tungsten mineralisation from Re–Os dating of molybdenite     

Johann G. Raith  Holly J. Stein 《Contributions to Mineralogy and Petrology》2006,152(4):505-521

The Felbertal scheelite deposit in the Eastern Alps has been regarded as the type locality for stratabound scheelite deposits. It is hosted by a Cambro-Ordovician metavolcanic arc sequence with minor Variscan granitoids (∼ 340 Ma) in the central Tauern Window. Re–Os model ages for molybdenite from the Felbertal tungsten deposit range between ∼ 358 and ∼ 336 Ma and record several pulses of magmatic-hydrothermal-metamorphic molybdenite formation. Molybdenite ages from the K2 orebody, a scheelite-rich quartz mylonite in the Western ore field, indicate that both mineralisation and mylonite are Variscan in age and suggest that the shear zone was active for ∼ 20 million years. Early stage tungsten mineralisation (Scheelite 1) in quartzitic ores in the Eastern ore field, which is free of molybdenite, yielded very low to near blank levels of Re and Os and thus could not be dated. However, molybdenite from scheelite–quartz stringers, previously interpreted as a feeder stockwork to quartzitic scheelite ore of presumed Cambrian age, yielded Variscan Re–Os ages of ∼ 342 and ∼ 337 Ma. Dating of molybdenite contained in scheelite ores thus far provides no indication of a Cambrian component to the tungsten mineralisation. Our data are consistent with a model of either granite intrusion-related ore formation and coeval metamorphic overprint during the Early Carboniferous or, alternatively, molybdenite formation may be exclusively attributed to Variscan metamorphism (see Stein 2006).  相似文献   

Fluid overpressure in layered intrusions: formation of a breccia pipe in the Eastern Bushveld Complex, Republic of South Africa     

Sonja L. Boorman  James B. McGuire  Alan E. Boudreau  Johann F. Kruger 《Mineralium Deposita》2003,38(3):356-369

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Extreme value theory based on the r largest annual events: a robust approach     

D. J. Dupuis 《Journal of Hydrology》1997,200(1-4):295-306

In Smith (1986, J. Hydrol. 86, 27–43), a family of statistical distributions and estimators for extreme values based on a fixed number r > = 1 of the largest annual events are presented. The method of estimation was numerical maximum likelihood. In this paper, we consider the robust estimation of parameters in such families of distributions. The estimation technique, which is based on optimal B-robust estimates, will assign weights to each observation and give estimates of the parameters based on the data which are well modeled by the distribution. Thus, observations which are not consistent with the proposed distribution can be identified and the validity of the model can be assessed. The method is illustrated on Venice sea level data.  相似文献   

Assimilating continental mean temperatures to reconstruct the climate of the late pre-industrial period     

Anastasios Matsikaris  Martin Widmann  Johann Jungclaus 《Climate Dynamics》2016,46(11-12):3547-3566

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Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria     

Falk Händel  Gaisheng Liu  Johann Fank  Franz Friedl  Rudolf Liedl  Peter Dietrich 《Hydrogeology Journal》2016,24(8):2079-2091

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.  相似文献   

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments     

Hélène Dupuis  Alain Weill  Kristina Katsaros  Peter K. Taylor 《Annales Geophysicae》1995,13(10):1065-1074

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.  相似文献   

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite     

Sven-Ulf Weber  Michael Grodzicki  Werner Lottermoser  Günther J. Redhammer  Gerold Tippelt  Johann Ponahlo  Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.  相似文献   

Parameterisation of the vertical transport in a small thermally stratified lake     

Christoph von Rohden  Karl Wunderle  Johann Ilmberger 《Aquatic Sciences - Research Across Boundaries》2007,69(1):129-137

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