Nutrient Inputs, Phytoplankton Response, and CO2 Variations in a Semi-Enclosed Subtropical Embayment, Kaneohe Bay, Hawaii     

Patrick Drupp  Eric Heinen De Carlo  Fred T. Mackenzie  Paul Bienfang  Christopher L. Sabine 《Aquatic Geochemistry》2011,17(4-5):473-498

The marine shelf areas in subtropical and tropical regions represent only 35% of the total shelf areas globally, but receive a disproportionately large amount of water (65%) and sediment (58%) discharges that enter such environments. Small rivers and/or streams that drain the mountainous areas in these climatic zones deliver the majority of the sediment and nutrient inputs to these narrow shelf environments; such inputs often occur as discrete, episodic introductions associated with storm events. To gain insight into the linked biogeochemical behavior of subtropical/tropical mountainous watershed-coastal ocean ecosystems, this work describes the use of a buoy system to monitor autonomously water quality responses to land-derived nutrient inputs and physical forcing associated with local storm events in the coastal ocean of southern Kaneohe Bay, Oahu, Hawaii, USA. The data represent 2.5 years of near-real time observations at a fixed station, collected concurrently with spatially distributed synoptic sampling over larger sections of Kaneohe Bay. Storm events cause most of the fluvial nutrient, particulate, and dissolved organic carbon inputs to Kaneohe Bay. Nutrient loadings from direct rainfall and/or terrestrial runoff produce an immediate increase in the N:P ratio of bay waters up to values of 48 and drive phytoplankton biomass growth. Rapid uptake of such nutrient subsidies by phytoplankton causes rapid declines of N levels, return to N-limited conditions, and subsequent decline of phytoplankton biomass over timescales ranging from a few days to several weeks, depending on conditions and proximity to the sources of runoff. The enhanced productivity may promote the drawing down of pCO₂ and lowering of surface water column carbonate saturation states, and in some events, a temporary shift from N to P limitation. The productivity-driven CO₂ drawdown may temporarily lead to air-to-sea transfer of atmospheric CO₂ in a system that is on an annual basis a source of CO₂ to the atmosphere due to calcification and perhaps heterotrophy. Storms may also strongly affect proximal coastal zone pCO₂ and hence carbonate saturation state due to river runoff flushing out high pCO₂ soil and ground waters. Mixing of the CO₂-charged water with seawater causes a salting out effect that releases CO₂ to the atmosphere. Many subtropical and tropical systems throughout the Pacific region are similar to Kaneohe Bay, and our work provides an important indication of the variability and range of CO₂ dynamics that are likely to exist elsewhere. Such variability must be taken into account in any analysis of the direction and magnitude of the air?Csea CO₂ exchange for the integrated coastal ocean, proximal and distal. It cannot be overemphasized that this research illustrates several examples of how high frequency sampling by a moored autonomous system can provide details about ecosystem responses to stochastic atmospheric forcing that are commonly missed by traditional synoptic observational approaches. Finally, the work exemplifies the utility of combining synoptic sampling and real-time autonomous observations to elucidate the biogeochemical and physical responses of coastal subtropical/tropical coral reef ecosystems to climatic perturbations.  相似文献   

Reviews on books,internet and scientific media     

Sabine Tesch 《Environmental Earth Sciences》2011,62(4):897-898

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Preliminary Interlaboratory Trial for ISO/DIS 12010: Determination of Short Chain Polychlorinated Alkanes (SCCP) in Water     

Sabine Geiß  Nicole Lettmann  Aurélien Rey  Herbert Lepper  Birgit Körner  Silvio Mais  Theodor Prey  Bettina Hilger  Moana Engelke  Stephan Lebertz  Claudine Chatellier  George Sawal  Dirk Löffler  Tom Schillings 《洁净——土壤、空气、水》2011,39(6):537-542

A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C₁₀–C₁₃ and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.  相似文献   

Sex-specific biochemical and histological differences in gonads of sea urchins (Psammechinus miliaris) and their response to phenanthrene exposure     

Schäfer S  Abele D  Weihe E  Köhler A 《Marine environmental research》2011,71(1):70-78

Female and male individuals of the same species often differ with respect to their susceptibility to toxicant stress. In the present study, sea urchins (Psammechinus miliaris) of both sexes were exposed to high (150 μg L?1) and environmentally relevant (5 μg L?1) concentrations of phenanthrene over 10 days. While food intake was significantly decreased following exposure to 150 μg L?1 phenanthrene, histological indices (lipofuscin accumulation, fibrosis, oocyte atresia), energetic status (energy charge, sum adenylates, AMP/ATP ratio) as well as ascorbate levels in the gonads showed either little or no effect upon phenanthrene exposure. However, most parameters (vitamin C, energy charge, sum adenylates, AMP/ATP ratio, ATP and ADP concentrations, lipofuscin content, fibrosis) significantly differed between male and female animals. This study illustrates the difficulties to identify toxic injury in reproductive tissue as it may be superimposed by gametogenesis and spawning of gametes.  相似文献   

Significance of vertical flux as a sink for surface water DMSP and as a source for the sediment surface in coastal zones of northern Europe     

Sauveur Belviso  Grard Thouzeau  Sabine Schmidt  Marit Reigstad  Paul Wassmann  Elena Arashkevich  Jacqueline Stefels 《Estuarine, Coastal and Shelf Science》2006,68(3-4):473

In April 1997 and 1998 the significance of sedimentation as a sink for epipelagic dimethylsulphoniopropionate (DMSP) production and as a source for marine sediments was reassessed using a newly designed sediment trap. The behaviour of the traps in immersion was monitored continuously and the collection efficiency was evaluated with ²³⁴Th measurements. Net DMS(P) fluxes were corrected for some physical and biological losses during the whole sedimentation process providing reliable estimates of gross DMSP fluxes. It is shown that daily losses by sedimentation account for between 0.1% and 16% of seawater particulate DMSP (DMSPp) standing stocks, and between 3% and 75% of daily DMSPp production. In the Malangen fjord we observed temporal increases of DMSP production and standing stocks which resulted also in increases of DMSP vertical fluxes and DMS(P) concentrations at the sediment surface. This result illustrates how tight the coupling can be between pelagos and benthos, and confirms that DMS(P) concentration in the sediment was a reliable diagnostic indicator of vertical export from overlying waters in Malangen fjord. In Ullsfjord, however, DMS(P) concentrations in the sediment were poorly indicators of Phaeocystis pouchetii export during the early stage of growth of a bloom. The high load of DMS(P) in Balsfjord's sediments could neither be attributed to local vertical sedimentation nor to short-term lateral advection of fresh DMSP-containing phytoplanktonic material, and provides indication that this tracer sometimes also can be misleading. The highest loads of DMS(P) in sediments and the fastest rates of sedimentation occurred in the Southern Bight of the North Sea.  相似文献   

Th sorption and export models in the water column: A review   总被引：2，自引：3，他引：2  

Nicolas Savoye  Claudia Benitez-Nelson  Adrian B. Burd  J. Kirk Cochran  Matthew Charette  Ken O. Buesseler  George A. Jackson  Matthieu Roy-Barman  Sabine Schmidt  Marc Elskens 《Marine Chemistry》2006,100(3-4):234

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.  相似文献   

Sub-lethal effects of metal exposure: physiological and behavioural responses of the estuarine bivalve Macoma balthica     

Duquesne S  Liess M  Bird DJ 《Marine environmental research》2004,58(2-5):245-250

Variation in glycogen concentration, condition index (CI) and filtration activity were measured in the bivalve Macoma balthica buried in sediment and experimentally exposed to cadmium (Cd). The stress due to elevated but sub-lethal concentrations (300 ppb Cd) affected the overall fitness of the organism as all parameters monitored responded significantly. Lower concentrations tested (10, 30 and 100 ppb) only induced a significant decrease in filtration activity, which may play a protective role, enabling the organism to slow down its metabolic activity and preserving the integrity of its reserves (reflected by stable CI and glycogen levels). Hence, the various endpoints selected show different thresholds. Our results also demonstrate that under high exposure, small individuals loose proportionally more glycogen per unit of weight than larger ones, thus confirming the higher sensitivity of small individuals to metal contamination. Furthermore, exposure to intermediate concentration (30 ppb) seems to be beneficial to the small individuals as indicated by their high CI values compared to the control. These results showed thus that non-sigmoidal concentration-response relationship and sizes of individuals should be considered in monitoring programmes and risk assessment.  相似文献   

Modeling, parameterization and evaluation of monitoring methods for CO2 storage in deep saline formations: the CO2-MoPa project     

S. Bauer  H. Class  M. Ebert  V. Feeser  H. G?tze  A. Holzheid  O. Kolditz  Sabine Rosenbaum  W. Rabbel  D. Sch?fer  A. Dahmke 《Environmental Earth Sciences》2012,67(2):351-367

Capture and geological sequestration of CO₂ from large industrial sources is considered a measure for reducing anthropogenic emissions of CO₂ and thus mitigating climate change. One of the main storage options proposed are deep saline formations, as they provide the largest potential storage capacities among the geologic options. A thorough assessment of this type of storage site therefore is required. The CO₂-MoPa project aims at contributing to the dimensioning of CO₂ storage projects and to evaluating monitoring methods for CO₂ injection by an integrated approach. For this, virtual, but realistic test sites are designed geometrically and fully parameterized. Numerical process models are developed and then used to simulate the effects of a CO₂ injection into the virtual test sites. Because the parameterization of the virtual sites is known completely, investigation as well as monitoring methods can be closely examined and evaluated by comparing the virtual monitoring result with the simulation. To this end, the monitoring or investigation method is also simulated, and the (virtual) measurements are recorded and evaluated like real data. Application to a synthetic site typical for the north German basin showed that pressure response has to be evaluated taking into account the layered structure of the storage system. Microgravimetric measurements are found to be promising for detecting the CO₂ phase distribution. A combination of seismic and geoelectric measurements can be used to constrain the CO₂ phase distribution for the anticline system used in the synthetic site.  相似文献   

Features of coastal upwelling regions that determine net air-sea CO<Subscript>2</Subscript> flux   总被引：1，自引：0，他引：1  

Debby Ianson  Richard A. Feely  Christopher L. Sabine  Lauren W. Juranek 《Journal of Oceanography》2009,65(5):677-687

The influence of the coastal ocean on global net annual air-sea CO₂ fluxes remains uncertain. However, it is well known that air-sea pCO₂ disequilibria can be large (ocean pCO₂ ranging from ∼400 μatm above atmospheric saturation to ∼250 μatm below) in eastern boundary currents, and it has been hypothesized that these regions may be an appreciable net carbon sink. In addition it has been shown that the high productivity in these regions (responsible for the exceptionally low surface pCO₂) can cause nutrients and inorganic carbon to become more concentrated in the lower layer of the water column over the shelf relative to adjacent open ocean waters of the same density. This paper explores the potential role of the winter season in determining the net annual CO₂ flux in temperate zone eastern boundary currents, using the results from a box model. The model is parameterized and forced to represent the northernmost part of the upwelling region on the North American Pacific coast. Model results are compared to the few summer data that exist in that region. The model is also used to determine the effect that upwelling and downwelling strength have on the net annual CO₂ flux. Results show that downwelling may play an important role in limiting the amount of CO₂ outgassing that occurs during winter. Finally data from three distinct regions on the Pacific coast are compared to highlight the importance of upwelling and downwelling strength in determining carbon fluxes in eastern boundary currents and to suggest that other features, such as shelf width, are likely to be important.  相似文献   

Econometric analysis to differentiate effects of various ship safety inspections   总被引：1，自引：1，他引：0  

Sabine Knapp  Philip Hans Franses   《Marine Policy》2008,32(4):653-662

This article provides a refined technique to measure and interpret variables associated with the quality of an inspection—be it port state control or vetting inspections towards the probability of a very serious, serious or less serious casualty. It concentrates on filtering out the effect of variables such as detention, the port state control regime that inspected the vessel, time in-between inspections, deficiencies found during an inspection and the effect of vetting inspections. The consensus amongst policy makers in the shipping industry is that data cannot be combined to target vessels. While this article does demonstrate that the decrease in the probability of casualty is stronger for the South American Region, the Indian Ocean Region and Australia versus North Europe, North America or the Caribbean, it also demonstrates that the data can be combined to target vessels for inspections. Since the time in-between inspections and detention is mostly not significant towards decreasing the probability of casualty, these results reflect the lack of coordination amongst port state control regimes and industry inspections. Due to this lack of coordination and trust, a ship might be inspected in several regimes during a relative short time period where the benefit of an inspection can be easily saturated. Our recommendation on direct policy implication is to promote the harmonization of inspection databases across port state control regimes, preferably with the coordination of the development of the Global Integrated Ship Information System (GISIS) of the International Maritime Organization (IMO), to review the policy of a release of a vessel from detention and to increase cooperation amongst regimes with respect to the follow up of the rectification of deficiencies.  相似文献