Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family     

Romain de Mesmay  Pierre Metzger  Vincent Grossi  Sylvie Derenne 《Organic Geochemistry》2008,39(7):879-893

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.  相似文献   

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change   总被引：3，自引：0，他引：3  

Marc J. Metzger  Rik Leemans  Dagmar Schrter 《International Journal of Applied Earth Observation and Geoinformation》2005,7(4):253-267

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.  相似文献   

Marée de l'écorce: L'effet du dephasage dans l'analyse des observations     

J. Metzger 《Pure and Applied Geophysics》1954,29(1):71-83

Résumé L'amplitude relativeA de la marée de l'écorce se déduit du rapport entre les variations de pesanteur théorique et observée. La comparaison directe de leurs valeurs horaires permet de déterminer ce rapport, mais cette méthode néglige le déphasage éventuel de la marée de l'écorce par rapport aux forces génératrices. L'erreur (négative) qui en résulte sur les valeurs habituelles deA est d'environ 11% (en supposant un déphasage de 1 h), si l'on compare uniquement les amplitudes extrêmes; elle atteint 14% si l'on tient compte de l'ensemble des valeurs horaires.Si l'effet du déphasage se fait peu ressentir aux heures où la marée est importante, on conçoit qu'il introduise une erreur relative considérable sur les valeurs horaires correspondant à une marée faible. Le calcul montre cependant qu'on n'améliore guère lè résultat global en éliminant systématiquement ces dernières.

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Summary The relative amplitudeA of the earth tide is deduced from the ratio of the theoretical variations of gravity to the observed. The direct comparison of their hourly values allows the determination of this ratio, but this method neglects the eventual dephasing of the earth tide over the generating forces. The resulting (negative) error on the usual values ofA is about 11% (supposing a dephasing of 1 hour), if only extreme amplitudes are compared; it reaches 14% if the totality of the hourly values is taken into account.If the effect of the dephasing is slight at the hours when the tide has a great value, it is conceivable that it introduces a noticeable relative error on the hourly readings corresponding to a low value. The computation shows nevertheless that the total result is little improved by systematic elimination of the latter.

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利用步长模拟对青藏高原涡度方差测量法的质量评价   总被引：1，自引：0，他引：1  

S. Metzger  马耀明  T.Markkanen  M. G 《地球科学进展》2006,21(12):1260-1267

利用痕迹模拟方法对青藏高原两处地方涡度方差的测量数据进行了质量分析，揭示了其空间和时间结构。分析表明高达1/3的测量没有达到必要的数据正确假设。尽管这样对潜热、CO2、动量通量的测量基本通过测试，可以适用于基础研究，但是经常发现特定的风矢量违背基本假设条件。感热通量的测量允许使用不间断的连续测量法，然而由于局地地形的影响少量评估指数未能合理解释，但能够指示出组织结构及用于导出边界层中尺度流体模型假说。  相似文献   

Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer     

John A. Izbicki  Christen E. Petersen  Kenneth J. Glotzbach  Loren F. Metzger  Allen H. Christensen  Gregory A. Smith  David O’Leary  Miranda S. Fram  Trevor Joseph  Heather Shannon 《Applied Geochemistry》2010

About 1.02 × 10⁶ m³ of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 10⁶ m³ of water were extracted between July 2007 and February 2008. On the basis of Cl⁻ data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection.  相似文献   

Projected climate change impacts on spatial distribution of bioclimatic zones and ecoregions within the Kailash Sacred Landscape of China,India, Nepal     

Robert J. Zomer  Antonio Trabucco  Marc J. Metzger  Mingcheng Wang  Krishna P. Oli  Jianchu Xu 《Climatic change》2014,125(3-4):445-460

Rapidly accelerating climate change in the Himalaya is projected to have major implications for montane species, ecosystems, and mountain farming and pastoral systems. A geospatial modeling approach based on a global environmental stratification is used to explore potential impacts of projected climate change on the spatial distribution of bioclimatic strata and ecoregions within the transboundary Kailash Sacred Landscape (KSL) of China, India and Nepal. Twenty-eight strata, comprising seven bioclimatic zones, were aggregated to develop an ecoregional classification of 12 ecoregions (generally defined by their potential dominant vegetation type), based upon vegetation and landcover characteristics. Projected climate change impacts were modeled by reconstructing the stratification based upon an ensemble of 19 Earth System Models (CIMP5) across four Representative Concentration Pathways (RCP) emission scenarios (i.e. 63 impact simulations), and identifying the change in spatial distribution of bioclimatic zones and ecoregions. Large and substantial shifts in bioclimatic conditions can be expected throughout the KSL area by the year 2050, within all bioclimatic zones and ecoregions. Over 76 % of the total area may shift to a different stratum, 55 % to a different bioclimatic zone, and 36.6 % to a different ecoregion. Potential impacts include upward shift in mean elevation of bioclimatic zones (357 m) and ecoregions (371 m), decreases in area of the highest elevation zones and ecoregions, large expansion of the lower tropical and sub-tropical zones and ecoregions, and the disappearance of several strata representing unique bioclimatic conditions within the KSL, with potentially high levels of biotic perturbance by 2050, and a high likelihood of major consequences for biodiversity, ecosystems, ecosystem services, conservation efforts and sustainable development policies in the region.  相似文献   

Field measurements of horizontal forward motion velocities of terrestrial dust devils: Towards a proxy for ambient winds on Mars and Earth     

M.R. Balme  A. Pathare  S.M. Metzger  M.C. Towner  S.R. Lewis  A. Spiga  L.K. Fenton  N.O. Renno  H.M. Elliott  F.A. Saca  T.I. Michaels  P. Russell  J. Verdasca 《Icarus》2012,221(2):632-645

Dust devils – convective vortices made visible by the dust and debris they entrain – are common in arid environments and have been observed on Earth and Mars. Martian dust devils have been identified both in images taken at the surface and in remote sensing observations from orbiting spacecraft. Observations from landing craft and orbiting instruments have allowed the dust devil translational forward motion (ground velocity) to be calculated, but it is unclear how these velocities relate to the local ambient wind conditions, for (i) only model wind speeds are generally available for Mars, and (ii) on Earth only anecdotal evidence exists that compares dust devil ground velocity with ambient wind velocity. If dust devil ground velocity can be reliably correlated to the ambient wind regime, observations of dust devils could provide a proxy for wind speed and direction measurements on Mars. Hence, dust devil ground velocities could be used to probe the circulation of the martian boundary layer and help constrain climate models or assess the safety of future landing sites.We present results from a field study of terrestrial dust devils performed in the southwest USA in which we measured dust devil horizontal velocity as a function of ambient wind velocity. We acquired stereo images of more than a 100 active dust devils and recorded multiple size and position measurements for each dust devil. We used these data to calculate dust devil translational velocity. The dust devils were within a study area bounded by 10 m high meteorology towers such that dust devil speed and direction could be correlated with the local ambient wind speed and direction measurements.Daily (10:00–16:00 local time) and 2-h averaged dust devil ground speeds correlate well with ambient wind speeds averaged over the same period. Unsurprisingly, individual measurements of dust devil ground speed match instantaneous measurements of ambient wind speed more poorly; a 20-min smoothing window applied to the ambient wind speed data improves the correlation. In general, dust devils travel 10–20% faster than ambient wind speed measured at 10 m height, suggesting that their ground speeds are representative of the boundary layer winds a few tens of meters above ground level. Dust devil ground motion direction closely matches the measured ambient wind direction.The link between ambient winds and dust devil ground velocity demonstrated here suggests that a similar one should apply on Mars. Determining the details of the martian relationship between dust devil ground velocity and ambient wind velocity might require new in situ or modelling studies but, if completed successfully, would provide a quantitative means of measuring wind velocities on Mars that would otherwise be impossible to obtain.  相似文献   

Investigating mesoscale eddy characteristics in the Luzon Strait region using altimetry     

Trott  Corinne B.  Metzger  E. Joseph  Yu  Zhitao 《Ocean Dynamics》2021,71(6-7):679-698

Ocean Dynamics - The circulation in the northern South China Sea (SCS) strongly responds to anticyclonic eddies that shed from the Kuroshio intruding across Luzon Strait. An eddy tracking algorithm...  相似文献   

A spatially explicit methodology for a priori estimation of field survey effort in environmental observation networks     

Carlos Guerra  Marc J. Metzger  João Honrado  Joaquim Alonso 《International journal of geographical information science》2013,27(10):2077-2098

When establishing environmental monitoring programmes, it crucial to make reliable cost estimates, especially where a field survey is involved. This paper presents a methodology for creating a spatial measure of a field survey effort (SE). A set of relevant variables affecting a SE (e.g. areas with rough terrain, or distant from the main road network) was classified using fuzzy sets and then combined to produce spatially explicit effort indicators, which were integrated to a single measure using an analytic hierarchy process (AHP). To evaluate this approach and identify the limits for its application, three spatially nested case studies were used to test the spatial expression of SE and the scalable capacity of the method itself. The presented methodology could cope with variations in the scale and data resolution, retrieving a coherent estimate of SE across the different case studies. The presented methodology is therefore useful for (i) testing the network designs for sampling bias related to SE, (ii) comparing alternative sampling designs, (iii) assessing the sampling costs and (iv) supporting the human and logistical resource management.  相似文献   

Use of LIDAR in landslide investigations: a review   总被引：13，自引：0，他引：13  

Michel Jaboyedoff  Thierry Oppikofer  Antonio Abellán  Marc-Henri Derron  Alex Loye  Richard Metzger  Andrea Pedrazzini 《Natural Hazards》2012,61(1):5-28

This paper presents a short history of the appraisal of laser scanner technologies in geosciences used for imaging relief by high-resolution digital elevation models (HRDEMs) or 3D models. A general overview of light detection and ranging (LIDAR) techniques applied to landslides is given, followed by a review of different applications of LIDAR for landslide, rockfall and debris-flow. These applications are classified as: (1) Detection and characterization of mass movements; (2) Hazard assessment and susceptibility mapping; (3) Modelling; (4) Monitoring. This review emphasizes how LIDAR-derived HRDEMs can be used to investigate any type of landslides. It is clear that such HRDEMs are not yet a common tool for landslides investigations, but this technique has opened new domains of applications that still have to be developed.  相似文献