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A molecular dynamics simulation of quartz at different temperatures both in the a and in the phase has been conducted. The - phase transition could be observed. A phonon analysis of the -phase confirms and rounds out in a quantitative way the origin of the incommensurate (ic) modulated phase. In particular it traces the optic soft mode at becoming (to a good approximation) a so-called rigid unit mode (RUM) at q0, and elucidates its coupling to the transverse acoustic mode which precipitates the incommensurate transition. This success underpins and illuminates the concept of RUMs and their role in structural phase transitions.  相似文献   
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Fossil charcoal, as direct evidence of palaeowildfires, has repeatedly been reported from several plant-bearing deposits from the Late Palaeozoic of the Northern Hemisphere. In contrast charcoal reports from the Late Palaeozoic deposits of the Southern Hemisphere are relatively rare in comparison to the Northern Hemisphere. Although the presence of pyrogenic coal macerals has repeatedly been reported from Late Palaeozoic coals from South America, no detailed anatomical investigations of such material have been published so far. Here is presented an anatomical analysis of charcoal originating from Early Permian sediments of the Quitéria Outcrop, Rio Bonito Formation, Paraná Basin, located in the central-eastern portion of Rio Grande do Sul, Brazil. This charcoal comes from two different coaly facies, and it was possible to scrutinize between three types, based on anatomical characters of the charcoal. Two of these charcoal types can be correlated to gymnosperm woods, and the other type corresponds to strongly permineralized bark with characteristic features of lycopsids. The presence of charcoal in different facies, ranging from parautochtonous to allochtonous origin, indicates that different vegetation types, i.e. plants which grew under wet conditions in the lowland as well as in the more dry hinterland, have experienced wildfires. Taking into account previous petrographic and lithological analyses from the facies in which the charcoal occurs and from the conditions of the wood and bark fragments, it was possible to speculate that the intensity of such wildfires most probably corresponds to forest-crown fires. Moreover, it is possible to state that wildfires have been a more or less common element in distinct Late Palaeozoic terrestrial ecosystems in the South American part of Gondwana. The data support previous assumptions on the occurrence of wildfires in the Early Permian of the Paraná Basin which were based solely on coal-petrographic data.  相似文献   
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The nature of the solubility of water as [4H]Si defects in quartz, and their role in providing a source of molecular water on heating, is investigated. Existing ab inito energy calculations on the incorporation of water in quartz are used to show that energetically 4H for Si substitution is likely to constitute the most prevalent mode of water uptake on the atomic scale in quartz under equilibrium conditions, and that the planar defects previously observed by a number of different authors by electron microscopy in wet quartz are likely to be planar rafts of aggregated [4H]Si defects which are formed on supersaturation. These new conclusions call into question the previous identification of the planar defects as high pressure water clusters and require that their role in the production of molecular water in the context of recent theories of hydrolytic weakening be re-assessed. Accordingly the existing ab initio results have been used to establish the characteristics of the phase diagram for the system quartz-water in the temperature and pressure range of interest in hydrolytic weakening. Additional electron-optical experiments on wet quartz show that, on annealing at temperature in the electron microscope, similar planar defects develop in wet quartz by a diffusion process. In the context of existing theories of hydrolytic weakening it is now proposed that the conversion of [4H]Si defects to molecular water, where this is dictated by the equilibrium phase diagram, leads to a relatively large increase in volume and to the appearance of the bubbles of free water and the nucleation of associated prismatic dislocation loops of Burgers vector b=1/3 a $\langle 11\bar 20\rangle $ as previously observed. Ultimately the development of these loops leads to dislocation-induced plasticity.  相似文献   
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Between 1995 and 2001, 16 measuring points at small and medium sized brooks in the Harz National Parks were sampled. The samples have been evaluated by means of hydrochemistry and macroinvertebrate biology. Although nearly all streams are largely uncontaminated by oxygen-consuming substances, they are settled only by a small number of macroinvertebrate species. There is a clear correlation between this number and pH. The reduction in species number with decrease of pH is mainly caused by the absence of most Ephemeroptera, some Coleoptera and Trichoptera. Comparing biological evaluation of acidity with physico-chemical measurements, a unacceptable underestimation was found. The reason could be that different sensitivities to acidification between regional populations seem to exist.

Despite of the low species number, there is a very specific macroinvertebrate fauna that emphasizes the conservation value of the Harz National Parks.  相似文献   

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From March 1989 until May 1995 overall 675 hauls were performed using a commercial stow net vessel to get information concerning spatial and seasonal distribution, length frequency distribution, stock situation and migration patterns of lampreys in the Elbe estuary in northern Germany.2217 river lampreys (Lampetra fluviatilis) and 10 sea lampreys (Petromyzon marinus) were caught during the whole study period. The river lamprey occurred in 40.3% of the performed stow net hauls. The catch success was highest in the western main channel, whereas the frequency of occurrence of river lampreys was only about 10.9% at the most upstream site in the southern marginal area. In 1989 and 1990 significantly more than 50% of the hauls contained river lampreys. In contrast, from 1991 to 1995 their frequency of occurrence was lower than 40%, in 1991 even lower than 20%. Sea lampreys occurred only at 6 from 9 sampled sites and were only observed in 1990 and 1992-1994.Total lengths of river lampreys varied between 7 and 46 cm. Based on the length frequency distribution, the following three size classes of river lampreys were separated: LF I (7 to 16 cm), LF II (17-26 cm) and LF III (27-46 cm). The majority of the caught individuals could be grouped in size class LF III. Total lengths of sea lampreys ranged between 69 and 85 cm and were restricted to only one size class (PM III).70% of all sea lampreys were caught in April and May. Most of the sea lampreys were observed in the eastern main channel. The maximum average abundance of river lampreys was observed with 6.75 Ind · m−3 · 10−6 in the same area in 1992. However, in 1993 and 1994 the highest average abundances of river lampreys occurred in the western main channel.Based on redundance analysis, a significant correlation between the abundances of lampreys and the environmental variables autumn, spring, summer, salinity, water temperature, grain size, new moon and first moon quarter was found. The downstream migrating river lampreys of size class LF I und the sea lampreys during their anadromous spawning migration showed highest abundances mainly in spring, whereas high abundances of river lampreys of size class LF II in the feeding phase occurred in summer. The presence of both size classes LF I and LF II confirms the successful reproduction of river lampreys in the catchment area of the Elbe. The observation of river lampreys of size class LF III during their anadromous spawning migration was closely correlated with the variable autumn. A spring spawning migration of river lampreys was not observed.  相似文献   
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