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1.
Traditional numerical methods for the delineation of wellhead protection areas span deterministic and probabilistic approaches. They provide time-related capture zones. However, none of the existing approaches identifies the groundwater contribution areas related to each source or sink. In this work, the worthiness of the so-called double delineation approach was extended. This task was achieved by simple postprocessing of its dual outputs leading to a highly efficient screening tool. In the particular context of geothermal resources management through the well doublets of the Dogger aquifer in the Paris Basin (France), the approach was extended to forecast the compositional heat breakthrough at production wells. Hence, cold-water breakthrough and temperature decline in production wells are timely assessed in low-enthalpy geothermal reservoirs. The method quantifies how groundwater volumes are moving through space and time between any couple of source and sink. It provides unprecedented tools advancing the enhanced understanding of water resources systems functioning. It is highly recommended to implement the presented concepts in the current and future generations of community groundwater models.  相似文献   
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The present study was dedicated to investigate an effective, economical and convenient method for strengthening brick infill walls, i.e. the use of externally-bonded expanded steel plates. A total of 30 plastered wall assemblies were tested under monotonic diagonal loading to investigate the contribution of these plates to the load capacities, ductilities and rigidities of brick walls. The plate thickness, bolt spacing and location of the plates in the wall were the parameters of the test program. The experiments indicated that application of the plates on the outermost fine plaster layer significantly improves the diagonal load–deflection behaviour of infill walls and reducing the bolt spacing provides the strengthened walls with higher load capacity values. An analytical expression was developed for estimating the diagonal load capacities of plated brick walls. The analytical load estimates were found to be in close agreement with the experimental values.  相似文献   
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The removal of heavy metals such as Ni(II), Zn(II), Al(III), and Sb(III) from aqueous metal solutions was investigated using novel, cost effective, seaweed derived sorbents. Studies with a laboratory scale fixed‐bed sorption column, using a seaweed waste material (referred to as waste Ascophyllum product (WAP)) from the processing of Ascophyllum nodosum as biosorbent, demonstrated high removal efficiencies (RE) for a variety of heavy metals including Ni(II), Zn(II) and Al(III), with 90, 90 and 74% RE achieved from initial 10 mg/L metal solutions, respectively. The presence of Sb(III) in multi component metal solutions suppressed the removal of Ni(II), Zn(II) and Al(III), reducing the RE to 28, 17 and 24%, respectively. The use of Polysiphonia lanosa as a biosorbent showed a 67% RE for Sb(III), both alone and in combination with other metals. Potentiometric and conductometric titrations, X‐ray photoelectron and mid‐infrared spectroscopic analysis demonstrated that carboxyl, alcohol, sulfonate and ether groups were heavily involved in Sb(III) binding by P. lanosa. Only carboxyl and sulfonate groups were involved in Sb(III) binding by WAP. Furthermore, a greater amount of weak acidic groups (mainly carboxylic functions) were involved in Sb(III) binding by P. lanosa, compared to WAP which involved a greater concentration of strong acidic groups (mainly sulfonates).  相似文献   
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The leaching processes along the flow path and over abstraction of the alluvial aquifer, the principal aquifer in delta Tokar, by the agricultural and domestic sectors and natural factors, have led to its salinization which may be due to interaction between geological formations and adjacent brackish and saline water bodies as well as seawater transgression. The main objectives of this study are to assess the hydrochemical characteristics of the groundwater and to delineate the locations and the sources of aquifer salinization. Water samples in the project area were chemically analyzed for major cations and anions at the laboratory by the standard analytical procedures. Chemical data and water level measurements were manipulated using GIS techniques for hydro chemical and flow direction maps and piper diagram for chemical facies and SPSS software for statistical analyses such as basic statistics (mean and standard deviation) and Spearman’s correlation matrix. The general flow direction of the groundwater is from Southwest towards East and Northeast. The hydraulic gradient is relatively steeper at the apex of the delta (0.06) and amounts to 0.005 at the distal part of the delta. The average transmissivity value of the water bearing formations was found to be about 4.5?×?103 m2/s, whereas, the storage coefficient was about 0.28. A hydrochemical study identified the locations and the sources of aquifer salinization and delineated their areas of influence. The investigation indicates that the aquifer water quality is significantly modified as groundwater flows from the southwestern parts of the study area, where the aquifer receives its water by lateral underflow from Khor Baraka flood plain, to the central and northeastern parts, with few exceptions of scattered anomalous concentration pockets in the deltaic plain. Significant correlation between TDS and/or EC with the major components of Na+, Cl?, and SO 4 ?2 ions is an indication of seawater influence on the groundwater salinity. Moreover, Cl?, SO 4 2? , and Na+ are predominant ions followed by Ca2+ and HCO 3 ? . Hence, four types of groundwater can be chemically distinguished: Na–Ca–SO4–Cl– facies, Na–Cl–SO4–HCO3– facies, Na–Ca–Mg–SO4–Cl–HCO3 facies, and Na–Ca–Mg–Cl–SO4 facies. The processes that govern changes in groundwater composition as revealed by chemical and statistical analyses are mainly associated with over-abstraction, biodegradation, marine intrusions, and carbonate saturation.  相似文献   
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Five years down the road from Kyoto, the Protocol that bears that city’s name still awaits enough qualifying ratifications to come into force. While attention has been understandably focussed on the ratification process, it is time to begin thinking about the next steps for the global climate regime, particularly in terms of a deeper inclusion of developing countries’ concerns and interests. This paper begins doing so from the perspective of the developing countries. The principal argument is that we need to return to the basic principles outlined in the Framework Convention on Climate Change in searching for a north-south bargain on climate change. Such a bargain may be achievable if we can realign the policy architecture of the climate regime to its original stated goals of sustainable development.  相似文献   
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Electron spin resonance of allowed (Δm=0) and forbidden (Δm=±1) hyperfine transitions of Mn2+ in sodalite, Na8(Al6Si6O24)Cl2, is reported. No fine structure other than the central M=∣+1/2>?∣?1/2> transition is observed. From intensity ratios of forbidden to allowed transitions and doubling of allowed lines in powder spectra the crystal field parameter |D| was estimated as equal to (8±5) 10?3 cm?1. The g-value for the spectrum was obtained as equal to 2.0033±0.0005. The hyperfine structure constant |A| was 83±1 gauss, equal to (77±1) 10?4 cm?1.  相似文献   
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A moderate-size earthquake (Mw = 6.2) occurred on 3 February 2002 (07:11:28 GMT) in the Sultanda??-Çay region of southwest Turkey. The mainshock was followed by a strong aftershock of Mw = 6.0 just 2 h after the mainshock, at 09:26:49 GMT. A temporary seismic network of 27 vertical component seismometers was installed to monitor aftershock activity. One thousand sixty nine aftershocks (0.2 < ML < 3.3) were recorded during the period from 5 to 10 February 2002. We analyzed the P and S arrival times and P wave first motion data to obtain high-quality hypocenters and focal mechanisms, which revealed fine details of the fault zone. We infer that the mainshock has ruptured a segment of the Sultanda? Fault Zone that is approximately 37 km long and 7 km wide at depth. The average slip over the rupture plane during the mainshock is estimated to be 32 cm. The linear distribution of the aftershocks and the location of the mainshock epicenter suggest that rupture has initiated in the eastern bending of the fault and propagated unilaterally to the west. The majority of fault plane solutions indicate E–W to ESE–WNW striking oblique–normal faulting mechanisms with an average dip angle of 62° N ± 10° . The high-resolution aftershock seismicity image also shows that faulting involved a complex array of synthetic and possibly antithetic structures during the evolution of the aftershock sequence. The steady increase of the b value towards the west implies that the highest moment release of the mainshock occurred to the west of the epicenter. The study clearly shows the activation of the WNW–ESE-trending Sultanda? Fault Zone along the southern margin of the Ak?ehir-Afyon Graben (AAG). The westernmost end of the aftershock activity corresponds to a structurally complex zone distinct from the main rupture. It is characterized by both ENE–WSW- and NNE–SSW-trending oblique-slip normal faulting mechanisms, the latter being associated with the NNE–SSW-trending Karam?k Graben. The intersection of these two grabens, AAG and Karam?k Graben, provides abundant faults available for failure in this region. The occurrence pattern of large events in recent years indicates a possible migration of earthquakes from east to west. Thus, we conclude that this has an important implication for earthquake hazard for the city of Afyon, which lies along the same fault line and only 20 km west of the termination point of the aftershock zone.  相似文献   
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