Experimental partitioning of trace elements into schreibersite with applications to IIG iron meteorites     

Nancy L. Chabot  Rachel H. Cueva  Andrew W. Beck  Richard D. Ash 《Meteoritics & planetary science》2020,55(4):726-743

Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed.  相似文献   

Models of aggradation versus progradation in the Himalayan Foreland   总被引：1，自引：0，他引：1  

Douglas W. Burbank  Richard A. Beck 《International Journal of Earth Sciences》1991,80(3):623-638

A frequent goal of decompaction analysis is to reconstruct histories of basin subsidence and tectonic loading. In marine environments, eustatic and paleobathymetric uncertainties limit the resolution of these reconstructions. Whereas in the terrestrial basins, these ambiguities are absent, it is still necessary to account for depositional slopes between localities in order to analyze three-dimensional patterns of subsidence. We define two end-members for depositional surfaces: aggradation and progradation. The relative importance of either end-member is a function of the interplay between the rate of net sediment accumulation and the rate of basin subsidence. The models predict the patterns of major drainages (transverse versus longitudinal) and the way in which provenance should be reflected within different portions of a basin. Consequently, paleocurrent and provenance data from the ancient stratigraphic record can be used to distinguish between these endmembers. The subhorizontal depositional surfaces that dominate during times of aggradation provide a well defined reference frame for regional analysis of decompacted stratigraphies and related subsidence. Depositional slopes during progradation can not be as precisely specified, and consequently yield greater uncertainties in reconstructions of subsidence. These models are applied to the Mio-Pliocene foreland basin of the northwestern Himalaya, where sequences of isochronous strata have been analyzed throughout the basin. These time-controlled data delineate a distinctive evolution from largely aggradational to largely progradational depositional geometries as deformation progressively encroaches on the foreland. Such a reconstruction of past depositional surfaces provides a well constrained reference frame for subsequent integration of subsidence histories from throughout the foreland.

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Zusammenfassung Ein häufiges Ziel der Dekompaktionsanalyse ist es die Beckenabsenkung und die tektonische Belastung zu rekonstruieren. In marinen Ablagerungsräumen limitieren eustatische und paläobathymetrische Unsicherheiten die Auflösung der Rekonstruktion. Bei terrestrischen Becken fehlen diese Zweideutigkeiten; es ist aber trotzdem notwendig, Rechenschaft über den Ablagerungshang zwischen verschiedenen Lokalitäten abzulegen, um dreidimensionale Subsidenzmuster zu analysieren. Wir definieren zwei Endglieder von Ablagerangsflächen: Aggradation und Progradation. Die relative Wichtigkeit des jeweiligen Endglieds ist eine Funktion des Zusammenspiels zwischen der Nettorate der Sedimentakkumulation und der Beckensubsidenz. Die Modelle sagen die Hauptentwässerungsmuster (quer- oder längsverlaufend) vorher, sowie den Weg in dem die Sedimentherkunft innerhalb verschiedener Bereiche des Beckens berücksichtigt werden sollte. Folglich können Paläoströmungs- und Herkunftsdaten alter stratigraphischer Überlieferungen benutzt werden, um zwischen den Endgliedern zu unterscheiden. Die subhorizontale Ablagerungsfläche welche zur Zeit der Aggradation dominant ist, liefert einen gut definierten Referenzrahmen für die regionale Analyse von dekomprimierten Formationen und der damit verknüpften Subsidenz. Ablagerangshänge während Progradation können nicht präzise spezifiziert werden und beinhalten daher größere Unsicherheiten bei der Rekonstruktion der Subsidenz. Diese Modelle wurden übertragen auf das miozäne bis pliozäne Vorgebirgsbecken des nordwestlichen Himalayas, wo Sequenzen von isochronen Schichten durch das gesamte Becken analysiert werden konnten. Diese zeitkontrollierten Daten schildern eine ganz bestimmte Entwicklung, die von einer hauptsächlich aggradierenden zu einer progradierenden Ablagerangsgeometrie verlief, während der die Deformation schrittweise in Richtung Vorland übergriff. Diese Rekonstruktion von ehemaligen Ablagerangsflächen liefert einen guten Referenzrahmen für die folgende Integration der Subsidenzgeschichte des gesamten Vorlands.

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Résumé L'analyse de décompaction a souvent pour but de reconstituer l'histoire de la subsidence d'un bassin et de la charge tectonique. Dans les milieux marins, de telles reconstitutions sont limitées par des incertitudes de caractère eustatique et paléobathymétrique. Par contre, ces ambiguïtés ne se présentent pas dans le cas des bassins continentaux, où il convient néanmoins de tenir compte de la pente de la surface de dépôt entre les divers points considérés pour établir un schéma tridimensionnel de la subsidence. Nous définissons deux situations extrêmes pour les surfaces de dépôt: l'aggradation et la progradation. L'importance relative de ces deux extrêmes est fonction de l'interaction entre le taux d'accumulation net des sédiments et le taux de subsidence du bassin. Les modèles prévoient la répartition des drainages principaux (transverse ou longitudinal) et la manière dont l'origine des sédiments peut se répercuter dans les diverses parties d'un bassin. Il en résulte que des informations fournies par les relevés stratigraphiques à propos des paléocourants et de la source des sédiments peuvent être utilisées pour faire la distinction entre les deux cas extrêmes. Les surfaces de dépôt subhorizontales, qui prédominent pendant les périodes d'aggradation, fournissent un bon cadre de référence pour les analyses régionales de formations décompactées et de la subsidence qui leur est associée. Les surfaces de dépôt inclinées qui se présentent au cours des progradations ne peuvent pas être définies de manière aussi précise et engendrent par conséquent plus d'incertitude dans la reconstitution de la subsidence. Les auteurs appliquent ces modèles au bassin mio-pliocène d'avant-pays de l'Himalaya nord-occidental, dans lequel des séquences de couches isochrones ont été suivies à travers tout le bassin. Ces données, chronologiquement définies, fournissent l'image d'une évolution nette, depuis des géométries typiques d'aggradation jusqu' à des géométries typiques de progradation, au fur et à mesure de l'emprise progressive de la déformation sur l'avant-pays. Une telle reconstitution des surfaces de dépôt anciennes fournit un bon cadre de référence en vue de l'intégration ultérieure de l'histoire de la subsidence dans l'ensemble de l'avant-pays.

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Cycling of trace metals (Mn, Fe, Mo, U, V, Cr) in deep pore waters of intertidal flat sediments     

Melanie Beck  Olaf Dellwig  Hans-Jürgen Brumsack 《Geochimica et cosmochimica acta》2008,72(12):2822-2840

Trace metals (Mn, Fe, Mo, U, Cr, V) were studied in pore waters of an intertidal flat located in the German Wadden Sea. The study system is an example of a permeable tidal flat system where pore water exchange is affected by tidal driven pressure gradients besides diffusion. Permanently installed in situ samplers were used to extract pore waters down to 5 m depth throughout one year. The samplers were either located close to the tidal flat margin or in central parts of the tidal flat. Despite dynamic sedimentological and hydrological conditions, the general trends with depth in deep tidal flat pore waters are remarkably similar to those observed in deep sea environments. Rates of trace metal cycling must be comparably large in order to maintain the observed pore water profiles. Trace metals further show similar general trends with depth close to the margin and in central parts of the tidal flat. Seasonal sampling revealed that V and Cr vary concurrent with seasonal changes in dissolved organic carbon (DOC) concentration. This effect is most notable close to the tidal flat margin where sulphate, DOC, and nutrients vary with season down to some metres depth. Seasonal variations of Mn, Fe, Mo, and U are by contrast limited to the upper decimetres of the sediment. Their seasonal patterns depend on organic matter supply, redox stratification, and particulate matter deposited on sediment surfaces. Pore water sampling within one tidal cycle provides evidence for pore water advection in margin sediments. During low tide pore water flow towards the creekbank is generated by a hydraulic gradient suggesting that deep pore waters may be seeping out of creekbank sediments. Owing to the enrichment of specific elements like Mn in pore water compared to sea water, seeping pore waters may have an impact on the chemistry of the open water column. Mass balance calculations reveal that the impact of deep pore waters on the Mn budget in the open water column is below 4%. Mn deep pore water discharge of the whole Wadden Sea is estimated to be about 9% of the total dissolved riverine Mn input into the Southern North Sea.  相似文献   

Diffusion induced Li isotopic fractionation during the cooling of magmatic rocks: The case of pyroxene phenocrysts from nakhlite meteorites   总被引：1，自引：0，他引：1  

P. Beck  M. Chaussidon  Ph. Gillet 《Geochimica et cosmochimica acta》2006,70(18):4813-4825

Ion-microprobe was used to measure Li abundances and isotopic compositions in pyroxenes from three Martian meteorites belonging to the nakhlite family. The profiles performed across augite crystals from Northwest Africa 817 show a large isotopic zoning from crystal cores (δ⁷Li ∼ 0‰) to rims (δ⁷Li ∼ +20‰) while Li abundances are almost constant (∼9.2 μg/g). Unlike NWA 817, the pyroxene studied in the Miller Range 03346 nakhlite shows a zoning in Li abundance, with concentrations increasing from ∼2.5 μg/g in the core to ∼9 μg/g in the rim. The augite rim (δ⁷Li = +7‰) is slightly enriched in ⁷Li with regard to the core (δ⁷Li = +4‰), but most of the isotopic variations observed occur at an intermediate position along the profile, where δ⁷Li falls down to ∼−11‰. In the case of Nakhla, Li concentrations in augite increase from cores (∼3.5 μg/g) to rims (∼6.5 μg/g), while the δ⁷Li variation is restricted (i.e., between δ⁷Li = +6.0 and +12.6‰). For the three meteorites the Li abundances were also measured in the groundmass, which was found to be enriched in lithium (∼10 μg/g). Conventional magmatic and post-magmatic processes such as alteration and fractional crystallization, fail to explain the dataset obtained on nakhlites. Degassing processes, which were previously proposed to explain the Li distribution in shergottite crystals, cannot result in the strong decoupling between Li abundances and isotopic composition observed in nakhlites. We suggest that the original magmatic Li distributions (concentrations and isotopic compositions) in nakhlites have been modified by diffusion of Li from the Li-rich groundmass towards the pyroxene crystals during sub-solidus cooling. Diffusion appears to have been efficient for NWA 817 and MIL 03346 but, apparently, did not produce a significant migration of Li in Nakhla, possibly because of the lower abundance of groundmass in the latter. Diffusion induced Li redistributions may also affect terrestrial porphyric rocks but very specific cooling rates are required to quench the diffusion profiles as observed in two of the present nakhlites.  相似文献   

High rate anaerobic treatment of Sago wastewater using HUASB with PUF as carrier     

J. Rajesh Banu M.Sc  M.Phil.  Ph.D.  S. Kaliappan B.E.  M.E.  Ph.D.  D. Beck 《International Journal of Environmental Science and Technology》2006,3(1):69-77

Sago industry is one of the major small-scale sectors in India and over 800 units are located in the southern State of Tamilnadu. Processing of sago generates enormous quantities of high strength wastewater requiring systematic treatment prior to disposal. The present study is an attempt to treat the sago wastewater using Hybrid Upflow Anaerobic Sludge Blanket (HUASB) reactor, which offers the advantages of both fixed film and up flow anaerobic sludge blanket treatment. HUASB reactor with a volume of 5.6 L was operated at Organic Loading Rates varying from 10.7 to 24.7 kg COD/m³.day. After 130 days of startup, the reactor produced appreciable decrease in COD of wastewater and removed solids efficiently. The COD removal varied from 91–87%. While the removal of Total Solids was in the range of 61–57%, that of volatile solids varied from 70–67%. The ideal OLR for the reactor was 23.5 kg COD/m³.day. The findings of the study open up newer possibilities of design low cost and compact onsite treatment systems with very short retention periods.  相似文献   

Reconstruction of sea level pressure fields over the Eastern North Atlantic and Europe back to 1500   总被引：3，自引：7，他引：3  

J. Luterbacher  E. Xoplaki  D. Dietrich  R. Rickli  J. Jacobeit  C. Beck  D. Gyalistras  C. Schmutz  H. Wanner 《Climate Dynamics》2002,18(7):545-561

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The red bed controversy revisited: shape analysis of Colorado Plateau units suggests long magnetization times     

Myrl E. Beck  Jr.  Russell F. Burmester  Bernard A. Housen 《Tectonophysics》2003,362(1-4):335-344

Several Triassic and earliest Jurassic sedimentary units from the Colorado Plateau region have distributions of virtual geomagnetic poles (VGPs) that are highly elongate along the path of apparent polar wander (APW). This suggests that the remanent magnetizations measured in these units were acquired over an extended period of time, possibly approaching 35 m.y., and are not precisely coeval with the stratigraphic age of the rock. Comparison with other paleomagnetic studies shows that the observed elongation is not a general attribute of the age of the rock, nor is it related to paleolatitude. The rocks that yield elongate VGP distributions are dominantly red to brown mudstones, and it is possible that their remanence is dominated by a slowly acquired chemical remanent magnetization, as suggested by Larson et al. [J. Geophys. Res. 87 (1982) 1081] and other authors. However, several superficially similar units from the Colorado Plateau have nearly circular VGP distributions. The process by which remanence is acquired in clastic sedimentary rocks merits further study.  相似文献   

Absolute velocity of North America during the Mesozoic from paleomagnetic data     

Myrl E. Beck  Jr.  Bernard A. Housen 《Tectonophysics》2003,377(1-2):33

We use paleomagnetic data to map Mesozoic absolute motion of North America, using paleomagnetic Euler poles (PEP). First, we address two important questions: (1) How much clockwise rotation has been experienced by crustal blocks within and adjacent to the Colorado Plateau? (2) Why is there disagreement between the apparent polar wander (APW) path constructed using poles from southwestern North America and the alternative path based on poles from eastern North America? Regarding (1), a 10.5° clockwise rotation of the Colorado Plateau about a pole located near 35°N, 102°W seems to fit the evidence best. Regarding (2), it appears that some rock units from the Appalachian region retain a hard overprint acquired during the mid-Cretaceous, when the geomagnetic field had constant normal polarity and APW was negligible.We found three well-defined small-circle APW tracks: 245–200 Ma (PEP at 39.2°N, 245.2°E, R=81.1°, root mean square error (RMS)=1.82°), 200–160 Ma (38.5°N, 270.1°E, R=80.4°, RMS=1.06°), 160 to 125 Ma (45.1°N, 48.5°E, R=60.7°, RMS=1.84°). Intersections of these tracks (the “cusps” of Gordon et al. [Tectonics 3 (1984) 499]) are located at 59.6°N, 69.5°E (the 200 Ma or “J1” cusp) and 48.9°N, 144.0°E (the 160 Ma or “J2” cusp). At these times, the absolute velocity of North America appears to have changed abruptly.North America absolute motion also changed abruptly at the beginning and end of the Cretaceous APW stillstand, currently dated at about 125 and 88 Ma (J. Geophys. Res. 97 (1992b) 19651). During this interval, the APW path degenerates into a single point, implying rotation about an Euler pole coincident with the spin axis.Using our PEP and cusp locations, we calculate the absolute motion of seven points on the North American continent. Our intention is to provide a chronological framework for the analysis of Mesozoic tectonics. Clearly, if APW is caused by plate motion, abrupt changes in absolute motion should correlate with major tectonic events. This follows because large accelerations reflect important changes in the balance of forces acting on the plate, the most important of which are edge effects (subduction, terrane accretion, etc.). Some tectonic interpretations: (1) The J1 cusp may be associated with the inception of rifting of North America away from land masses to the east; the J2 cusp seems to mark the beginning of rapid spreading in the North Atlantic. (2) The J2 cusp signals the beginning of a period of rapid northwestward absolute motion of western North America; motion of tectonostratigraphic terranes in the westernmost Cordillera seems likely to have been directed toward the south during this interval. (3) The interval 88 to 80 Ma saw a rapid decrease in the paleolatitude of North America; unless this represents a period of true polar wander, terrane motion during this time should have been relatively northward.  相似文献   

Vegetation changes in the Jornada Basin from 1858 to 1998   总被引：1，自引：1，他引：1  

R.P. Gibbens  R.P. McNeely  K.M. Havstad  R.F. Beck  B. Nolen 《Journal of Arid Environments》2005,61(4):651-668

Notes made by land surveyors in 1858 were utilized to estimate cover of grasses and shrubs on the Jornada Experimental Range (JER) and the Chihuahuan Desert Range Research Center (CDRRC) in the northern Chihuahuan Desert in southern New Mexico, USA. Portions of these areas have been previously assessed for historical vegetation dynamics but the entire 84,271 ha assessed in the 19th century has not been examined in total. In 1858, fair to very good grass cover occurred on 98% and 67% of the JER and CDRRC, respectively. Shrubs were present throughout both properties but 45% of the JER and 18% of the CDRRC were shrub free. Reconnaissance surveys, made to determine carrying capacity for livestock were made in 1915–1916 and 1928–1929 on the JER and in 1938 on the CDRRC, show that shrubs had made large increases in area occupied at the time of the surveys. Vegetation type maps were made of both properties in 1998. Mesquite (Prosopis glandulosa) was the primary dominant on 59% of the JER in 1998 and creosotebush (Larrea tridentata) was the primary dominant on 27% of the area. On the CDRRC mesquite and creosotebush were primary dominants on 37% and 46% of the area, respectively. Grass cover has decreased greatly with the increase in shrubs and only shrub control efforts have maintained the once abundant black grama (Bouteloua eriopoda) as a primary dominant on 1% or less of the area on both properties.  相似文献   

The First Solar Seeing Profile Measurement with Two Apertures and Multiple Guide Regions     

Deqing Ren  Gang Zhao  Xin Wang  Christian Beck  Robert Broadfoot 《Solar physics》2018,293(1):1

The sky brightness is a critical parameter for estimating the coronal observation conditions for a solar observatory. As part of a site-survey project in Western China, we measured the sky brightness continuously at the Lijiang Observatory in Yunnan province in 2011. A sky brightness monitor (SBM) was adopted to measure the sky brightness in a region extending from 4.5 to 7.0 apparent solar radii based on the experience of the Daniel K. Inouye Solar Telescope (DKIST) site survey. Every month, the data were collected manually for at least one week. We collected statistics of the sky brightness at four bandpasses located at 450, 530, 890, and 940 nm. The results indicate that aerosol scattering is of great importance for the diurnal variation of the sky brightness. For most of the year, the sky brightness remains under 20 millionths per airmass before local Noon. On average, the sky brightness is less than 20 millionths, which accounts for 40.41% of the total observing time on a clear day. The best observation time is from 9:00 to 13:00 (Beijing time). The Lijiang Observatory is therefore suitable for coronagraphs investigating the structures and dynamics of the corona.  相似文献