Titanite dates crystallization: Slow Pb diffusion during super‐solidus re‐equilibration     

Michael I. H. Hartnady  Christopher L. Kirkland  Chris Clark  Catherine V. Spaggiari  R. Hugh Smithies  Noreen J. Evans  Brad J. McDonald 《Journal of Metamorphic Geology》2019,37(6):823-838

Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10^?22 to 5 × 10^?25 m²/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.  相似文献   

NASA Landsat program accomplishments continue to make a difference II     

Kamlesh Lulla  M. Duane Nellis  Brad Rundquist 《国际地球制图》2013,28(5)

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Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material     

Youjuan Li  Brian R. Jicha  Wanfeng Zhang  Wen Chen  Brad S. Singer  Dewen Zheng  Huaiyu He 《Geostandards and Geoanalytical Research》2023,47(3):657-668

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.  相似文献   

Establishing Quaternary as a formal internationa Period/System     

James G. Ogg Brad Pillans 《《幕》》2008,31(2):230-233

Despite being the most widely used unit infield mapping and having the greatest number of active researchers, the interval known as Quaternary is unique among the chronostratigraphic subdivisions of the Geological Time Scale （GTS） in having the most controversial definition and rank. After more than 100 years of debate, the base of the Quaternary is now widely recognized at -2.6 Ma, marking a dramatic and so-far irreversible shift to the ice-age-dominated world of oscillating glacial advances over the northern continents.  相似文献   

Optimal water depth management on river-fed National Wildlife Refuges in a changing climate     

Sam Nicol  Brad Griffith  Jane Austin  Christine M. Hunter 《Climatic change》2014,124(1-2):271-284

The prairie pothole region (PPR) in the north-central United States and south-central Canada constitutes the most important waterfowl breeding area in North America. Projected long-term changes in precipitation and temperature may alter the drivers of waterfowl abundance: wetland availability and emergent vegetation cover. Previous studies have focused on isolated wetland dynamics, but the implications of changing precipitation on managed, river-fed wetlands have not been addressed. Using a structured decision making (SDM) approach, we derived optimal water management actions for 20 years at four river-fed National Wildlife Refuges (NWRs) in North and South Dakota under contrasting increasing/decreasing (+/?0.4 %/year) inflow scenarios derived from empirical trends. Refuge pool depth is manipulated by control structures. Optimal management involves setting control structure heights that have the highest probability of providing a desired mix of waterfowl habitat, given refuge capacities and inflows. We found optimal seasonal control structure heights for each refuge were essentially the same under increasing and decreasing inflow trends of 0.4 %/year over the next 20 years. Results suggest managed pools in the NWRs receive large inflows relative to their capacities. Hence, water availability does not constrain management; pool bathymetry and management tactics can be greater constraints on attaining management objectives than climate-mediated inflow. We present time-dependent optimal seasonal control structure heights for each refuge, which are resilient to the non-stationary precipitation scenarios we examined. Managers can use this information to provide a desired mixture of wildlife habitats, and to re-assess management objectives in reserves where pool bathymetry prevents attaining the currently stated objectives.  相似文献   

Post-peak,fluid-mediated modification of granulite facies zircon and monazite in the Trivandrum Block,southern India     

Richard J. M. Taylor  Chris Clark  Ian C. W. Fitzsimons  M. Santosh  M. Hand  Noreen Evans  Brad McDonald 《Contributions to Mineralogy and Petrology》2014,168(2):1-17

The quarry at Kottavattom in the Trivandrum Block of southern India contains spectacular examples of fluid-assisted alteration of high-grade metamorphic rocks. Garnet-biotite gneiss has undergone a change in mineral assemblage to form submetre scale orthopyroxene-bearing patches, later retrogressed to form an amphibole-bearing lithology. These patches, often referred to as arrested or incipient charnockite, crosscut the original metamorphic foliation and are typically attributed to passage of a low aH₂O fluid through the rock. Whilst this conversion is recognised as a late stage process, little detailed chronological work exists to link it temporally to metamorphism in the region. Zircon and monazite analysed from Kottavattom not only record metamorphism in the Trivandrum Block but also show internal, lobate textures crosscutting the original zoning, consistent with fluid-aided coupled dissolution-reprecipitation during formation of the orthopyroxene-bearing patches. High-grade metamorphism at the quarry occurred between the formation of metamorphic monazite at ~585 Ma and the growth of metamorphic zircon at ~523 Ma. The fluid-assisted alteration of the garnet-biotite gneiss is poorly recorded by altered zircon with only minimal resetting of the U–Pb system, whereas monazite has in some cases undergone complete U–Pb resetting and records an age for fluid infiltration at ~495 Ma. The fluid event therefore places the formation of the altered patches at least 25 Myr after the zircon crystallisation in the garnet-biotite gneiss. The most likely fluid composition causing the modification and U–Pb resetting of zircon and monazite is locally derived hypersaline brine.  相似文献   

Neutron star retention and millisecond pulsar production in globular clusters     

Melvyn B. Davies  & Brad M. S. Hansen 《Monthly notices of the Royal Astronomical Society》1998,301(1):15-24

We investigate the conditions by which neutron star retention in globular clusters is favoured. We find that neutron stars formed in massive binaries are far more likely to be retained. Such binaries are likely to then evolve into contact before encountering other stars, possibly producing a single neutron star after a common envelope phase. A large fraction of the single neutron stars in globular clusters are then likely to exchange into binaries containing moderate-mass main-sequence stars, replacing the lower-mass components of the original systems. These binaries will become intermediate-mass X-ray binaries (IMXBs), once the moderate-mass star evolves off the main sequence, as mass is transferred on to the neutron star, possibly spinning it up in the process. Such systems may be responsible for the population of millisecond pulsars (MSPs) that has been observed in globular clusters. Additionally, the period of mass-transfer (and thus X-ray visibility) in the vast majority of such systems will have occurred 5–10 Gyr ago, thus explaining the observed relative paucity of X-ray binaries today, given the MSP population.  相似文献   

The importance of interactions for mass loss from satellite galaxies in cold dark matter haloes     

Alexander Knebe  Chris Power  Stuart P. D. Gill  Brad K. Gibson 《Monthly notices of the Royal Astronomical Society》2006,368(2):741-750

We investigate the importance of interactions between dark matter substructures for the mass loss they suffer whilst orbiting within a sample of high-resolution galaxy cluster mass cold dark matter (CDM) haloes formed in cosmological N -body simulations. We have defined a quantitative measure that gauges the degree to which interactions are responsible for mass loss from substructures. This measure indicates that interactions are more prominent in younger systems when compared to older more relaxed systems. We show that this is due to the increased number of encounters a satellite experiences and a higher mass fraction in satellites. This is in spite of the uniformity in the distributions of relative distances and velocities of encounters between substructures within the different host systems in our sample.
Using a simple model to relate the net force felt by a single satellite to the mass loss it suffers, we show that interactions with other satellites account for ∼30 per cent of the total mass loss experienced over its lifetime. The relation between the age of the host and the importance of interactions increases the scatter about this mean value from ∼25 per cent for the oldest to ∼45 per cent for the youngest system we have studied. We conclude that satellite interactions play a vital role in the evolution of substructure in dark matter haloes and that a significant fraction of the tidally stripped material can be attributed to these interactions.  相似文献   

On the origin of fluorine in the Milky Way     

Agostino Renda  Yeshe Fenner  Brad K. Gibson  Amanda I. Karakas  John C. Lattanzio  Simon Campbell  Alessandro Chieffi  Katia Cunha  Verne V. Smith 《Monthly notices of the Royal Astronomical Society》2004,354(2):575-580

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On the in situ aqueous alteration of soils on Mars     

Ronald Amundson  Stephanie Ewing  Brad Sutter  Oliver Chadwick  Michelle Walvoord 《Geochimica et cosmochimica acta》2008,72(15):3845-3864

Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO₄, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface.  相似文献