Laser Ablation (U-Th-Sm)/He Dating of Zircons: Analytical Age Bias and its Consequence for Studying Detrital Zircon Populations     

Julien Léger  Raphaël Pik  Bouchaïb Tibari  Sébastien Ternois  Mary Ford  Chantal Peiffert  Julien Mercadier 《Geostandards and Geoanalytical Research》2023,47(2):219-242

The in situ (U-Th-Sm)/He and U/Pb laser-ablation double-dating procedure is a valuable method that can provide a large dataset relatively efficiently in contrast with conventional bulk helium thermochronometry. In this study, we evaluate the potential age error associated with the double ablation procedure and report the in situ (U-Th-Sm)/He double-ablation dating of 249 zircons from the Fish Canyon Tuff locality. With LA-ICP-MS pseudo-depth profiling and 3D numerical modelling, we show that the concentric double-ablation procedure in minerals with U-Th-Sm zoning can generate a significant (U-Th-Sm)/He age error (positive or negative), resulting in over-scattering and/or an offset of the mean age. Pseudo-depth profiling is insufficient to predict the individual age error, partly because of the superimposed ablations. To evaluate the consequence of this inherent bias, we confront a synthetic age distribution to the error expected for U-Th-Sm zoned zircons analysed with double-ablation (U-Th-Sm)/He thermochronometry. As expected, a strong age bias causes the spreading of peak ages, downgrading the original signal. Yet, the throughput of the ablation-based method can allow intra- and inter-sample peak age identification and comparison, and the coupling of (U-Th-Sm)/He and U/Pb ages extends our ability to deconvolute a multimodal age spectrum.  相似文献   

Geoarchaeological Investigations in Mesoamerica Move into the 21st Century: A Review     

Nicholas P. Dunning  Carmen McCane  Tyler Swinney  Matthew Purtill  Jani Sparks  Ashley Mann  Jon‐Paul McCool  Chantal Ivenso 《Geoarchaeology》2015,30(3):167-199

Over the past thirty years, geoarchaeology has moved from the fringe to mainstream status within Mesoamerican archaeological investigations. This review focuses on works published since the year 2000. Five themes are identified as central to recent studies: (1) the correlation of environmental change and cultural history; (2) anthropogenic environmental impacts; (3) ancient land cover, land use, and diet; (4) archaeological prospection; and (5) provenance studies. These themes are often interwoven in the application of complex systems approaches that allow scientists to more accurately model the intricacies of ancient human–environment interactions.  相似文献   

Discussion: Sedimentology,stable‐isotope geochemistry and palaeoenvironment of dolostones capping late Precambrian glacial sequences in Australia     

T. H. Donnelly 《Australian Journal of Earth Sciences》2013,60(1-2):99-101

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The impact of disposal of fine-grained sediments from maintenance dredging works on SPM concentration and fluid mud in and outside the harbor of Zeebrugge     

Michael Fettweis  Matthias Baeye  Claudio Cardoso  Arvid Dujardin  Brigitte Lauwaert  Dries Van den Eynde  Thomas Van Hoestenberghe  Joris Vanlede  Luc Van Poucke  Carlos Velez  Chantal Martens 《Ocean Dynamics》2016,66(11):1497-1516

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Four-element CODAR beam forming     

Jeans  P. Donnelly  R. 《Oceanic Engineering, IEEE Journal of》1986,11(2):296-303

An HF radar called the Coastal Ocean Dynamics Applications Radar (CODAR) is presently being used in several forms to measure ocean surface parameters. The original version was developed by the National Oceanic and Atmospheric Administration (NOAA) and utilizes a four-element receive array. The array consists of four equally spaced elements arranged on a circle with a radius of 0.2151 wavelengths (at 25.4 MHz). It was designed to measure ocean currents using a direction-finding technique based on an extension to a simple two-element interferometer. The problem of determining the bearing of a radiating source can be readily shown to be equivalent to that incurred in spectral estimation. In an attempt to improve upon the processing of existing data, modern nonlinear spectral estimation techniques are applied in a beam-forming bearing estimation procedure and compared against several direction-finding algorithms. Enhancement of bearing estimators via analysis of the eigenstructure of a spatial correlation matrix is included. Antenna response patterns are calculated and used to investigate properties of direction-finding algorithms. Simulated data are used for a comparison of direction finding and beam forming. The asymmetrical bias of each method is investigated to determine its effect on the error in estimating the angle of arrival of a radar target.  相似文献   

Abrupt climate change as an important agent of ecological change in the Northeast U.S. throughout the past 15,000 years     

Bryan N. Shuman  Paige Newby  Jeffrey P. Donnelly 《Quaternary Science Reviews》2009,28(17-18):1693-1709

We use a series of tests to evaluate two competing hypotheses about the association of climate and vegetation trends in the northeastern United States over the past 15 kyrs. First, that abrupt climate changes on the scale of centuries had little influence on long-term vegetation trends, and second, that abrupt climate changes interacted with slower climate trends to determine the regional sequence of vegetation phases. Our results support the second. Large dissimilarity between temporally close fossil pollen samples indicates large vegetation changes within 500 years across >4° of latitude at ca 13.25–12.75, 12.0–11.5, 10.5, 8.25, and 5.25 ka. The evidence of vegetation change coincides with independent isotopic and sedimentary indicators of rapid shifts in temperature and moisture balance. In several cases, abrupt changes reversed long-term vegetation trends, such as when spruce (Picea) and pine (Pinus) pollen percentages rapidly declined to the north and increased to the south at ca 13.25–12.75 and 8.25 ka respectively. Abrupt events accelerated other long-term trends, such as a regional increase in beech (Fagus) pollen percentages at 8.5–8.0 ka. The regional hemlock (Tsuga) decline at ca 5.25 ka is unique among the abrupt events, and may have been induced by high climatic variability (i.e., repeated severe droughts from 5.7 to 2.0 ka); autoregressive ecological and evolutionary processes could have maintained low hemlock abundance until ca 2.0 ka. Delayed increases in chestnut (Castanea) pollen abundance after 5.8 and 2.5 ka also illustrate the potential for multi-century climate variability to influence species' recruitment as well as mortality. Future climate changes will probably also rapidly initiate persistent vegetation change, particularly by acting as broad, regional-scale disturbances.  相似文献   

Biogeochemical and hydrographic controls on chromophoric dissolved organic matter distribution in the Pacific Ocean     

Chantal M. Swan  David A. Siegel  Norman B. Nelson  Craig A. Carlson  Elora Nasir 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(12):2175-2192

Recent in situ observations of chromophoric dissolved organic material (CDOM) in the Pacific Ocean reveal the biogeochemical controls on CDOM and indicate predictive potential for open-ocean CDOM in diagnosing particulate organic matter (POM) remineralization rates within ocean basins. Relationships between CDOM and concentrations of dissolved oxygen, nutrients and inorganic carbon in the subthermocline waters of the Pacific reflect the relative influences of water mass ventilation and water-column oxidative remineralization. Apparent in situ oxygen utilization (AOU) accounts for 86% and 61% of variance in CDOM abundance, respectively, in Antarctic Intermediate Water and North Pacific Intermediate Water. In the deep waters of the Pacific below the zone of remineralization, AOU explains 26% of CDOM variability. The AOU–CDOM relationship results from competing biogeochemical and advective processes within the ocean interior. Dissolved organic carbon (DOC) is not statistically linked to the CDOM or AOU distributions, indicating that the majority of CDOM production occurs during the remineralization of sinking POM and thus potentially provides key information about carbon export. Once formed in the ocean interior, CDOM is relatively stable until it reaches the surface ocean where it is destroyed by solar bleaching. Susceptibility to bleaching confers an additional tracer-like quality for CDOM in water masses with active convection, such as mode waters that appear as subsurface CDOM minima. In the surface ocean, atypically low CDOM abundance highlights a region of unusually extreme oligotrophy: the subtropical South Pacific gyre. For these hyper-oligotrophic waters, the present CDOM observations are consistent with analysis of in situ radiometric observations of light attenuation and reflectance, demonstrating the accuracy of the CDOM spectrophotometric observations. Overall, we illustrate how CDOM abundance in the ocean interior can potentially diagnose rates of thermohaline overturning as they affect regional biogeochemistry and export. We further show how relative surface ocean CDOM abundances are driven in large part by processes occurring in the deep layers of the ocean. This is particularly significant for the interpretation of the global surface distribution of CDOM using satellite remote sensing.  相似文献   

L-shell photoionization cross-sections for Fe XIXXIX and Fe XXXX recombination rate coefficients     

D. Donnelly  K. L. Bell  F. P. Keenan 《Monthly notices of the Royal Astronomical Society》1999,307(3):595-604

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Water and Boating Activity as Dispersal Vectors for <Emphasis Type="Italic">Schinus terebinthifolius</Emphasis> (Brazilian pepper) Seeds in Freshwater and Estuarine Habitats     

Melinda J. Donnelly  Linda J. Walters 《Estuaries and Coasts》2008,31(5):960-968

Schinus terebinthifolius (Brazilian pepper), a native of South America, is currently naturalized in 20 countries worldwide and can alter native systems by displacing flora and forming monotypic stands. The primary described mechanism of seed dispersal is through consumption of fruits by birds and mammals. We evaluated an alternative dispersal method by evaluating the potential for S. terebinthifolius growing in freshwater and estuarine environments to disperse via water currents. Specifically, we: (1) determined the duration fruits remained buoyant in three salinities, (2) estimated the viability of seeds after 7 days in water, (3) estimated the dispersal rate of floating solitary fruits, and (4) examined the role of boat wakes in moving seeds above mean high water at the shoreline. The length of time fruits floated in 0 ppt water (4.9 days) was significantly less than 15 ppt saltwater (6.2 days), and 30 ppt saltwater (6.9 days). After 7 days, over 13% of seeds remained viable in 0 ppt, 15 ppt, and 30 ppt water. By combining mean dispersal rates and the mean number of days fruits floated, we calculated individual fruits could be transported 16.9 km in 0 ppt and over 22 km in 15 and 30 ppt water. To increase germination, seeds must be stranded above the intertidal zone. Wind wakes alone never achieved this result; however, boat wakes plus wind wakes significantly increased the movement of fruits above the intertidal region into drier soils. The use of both vertebrate dispersal vectors and water dispersal may potentially increase the rate of invasion, establishment, and survival of S. terebinthifolius in freshwater and estuarine environments.  相似文献   

The inter-relationship of hard X-ray and EUV bursts during solar flares     

A. Gordon Emslie  John C. Brown  Richard F. Donnelly 《Solar physics》1978,57(1):175-190

A comparison is made between the flux-versus-time profile in the EUV band and the thick target electron flux profile as inferred from hard X-rays for a number of moderately large solar flares. This complements Kane and Donnelly's (1971) study of small flares. The hard X-ray data are from ESRO TD-1A and the EUV inferred from SFD observations.Use of a ₂ minimising method shows that the best overall fit between the profile fine structures obtains for synchronism to 5 s which is within the timing accuracy. This suggests that neither conduction nor convection is fast enough as the primary mechanism of energy transport into the EUV flare and rather favours heating by the electrons themselves or by some MHD wave process much faster than acoustic waves.The electron power deposited, for a thick target model, is however far greater than the EUV luminosity for any reasonable assumptions about the area and depth over which EUV is emitted. This means that either most of the power deposited is conducted away to the optical flare or that only a fraction 1–10% of the X-ray emitting electrons are injected downwards. Recent work on H flare heating strongly favours the latter alternative - i.e. that electrons are mostly confined in the corona.  相似文献