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Jennifer L. Mercer Meixun Zhao Steven M. Colman 《Estuarine, Coastal and Shelf Science》2005,63(4):675-682
Alkenone unsaturation indices (UK37 and UK′37) have long been used as proxies for surface water temperature in the open ocean. Recent studies have suggested that in other marine environments, variables other than temperature may affect both the production of alkenones and the values of the indices. Here, we present the results of a reconnaissance field study in which alkenones were extracted from particulate matter filtered from the water column in Chesapeake Bay during 2000 and 2001. A multivariate analysis shows a strong positive correlation between UK37 (and UK′37) values and temperature, and a significant negative correlation between UK37 (and UK′37) values and nitrate concentrations. However, temperature and nitrate concentrations also co-vary significantly. The temperature vs. UK37 relationships (UK37=0.018 (T)−0.162, R2=0.84, UK′37=0.013 (T)−0.04, R2=0.80) have lower slopes than the open-ocean equations of Prahl et al. [1988. Further evaluation of long-chain alkenones as indicators of paleoceanographic conditions. Geochimica et Cosmochimica Acta 52, 2303–2310] and Müller et al. [1998. Calibration of the alkenone paleotemperature index UK′37 based on core-tops from the eastern South Atlantic and the global ocean (60°N–60°S). Geochimica et Cosmochimica Acta 62, 1757–1772], but are similar to the relationships found in controlled studies with elevated nutrient levels and higher nitrate:phosphate (N:P) ratios. This implies that high nutrient levels in Chesapeake Bay have either lowered the UK37 vs. temperature slope, or nutrient levels are the main controller of the UK37 index. In addition, particularly high abundances (>5% of total C37 alkenones) of the tetra-unsaturated ketone, C37:4, were found when water temperatures reached 25 °C or higher, thus posing further questions about the controls on alkenone production as well as the biochemical roles of alkenones. 相似文献
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We are investigating the effects of in vivo exposure of prototypical enzyme inducing agents on hepatic biotransformation enzyme expression in largemouth bass (Micropterus salmoides), a predatory game fish found throughout the United States and Canada. The current study targeted those genes involved in biotransformation and oxidative stress that may be regulated by Ah-receptor-dependent pathways. Exposure of bass to beta-naphthoflavone (beta-NF, 66 mg/kg, i.p.) elicited a 7-9-fold increase in hepatic microsomal cytochrome P4501A-dependent ethoxyresorufin O-deethylase (EROD) activities, but did not affect cytosolic GST catalytic activities toward 1-chloro-2,4-dinitrobenzene (CDNB) or 5-androstene-3,17-dione (ADI). Glutathione S-transferase A (GST-A) mRNA expression exhibited a transient, but non-significant increase following exposure to beta-NF, and generally tracked the minimal changes observed in GST-CDNB activities. Expression of the mRNA encoding glutamate-cysteine ligase catalytic subunit (GCLC), the rate-limiting enzyme in glutathione (GSH) biosynthesis, was increased 1.7-fold by beta-NF. Changes in GCLC mRNA expression were paralleled by increases in intracellular GSH. In summary, largemouth bass hepatic CYP1A-dependent and GSH biosynthetic pathways, and to a lesser extent GST, are responsive to exposure to beta-NF. 相似文献
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A non-steady, two-dimensional, compressible mathematical model of a fluid with constant viscosity and thermal conductivity is given in order to represent a thin atmospheric layer located at 60 km height, as a function of a known initial vertical distribution of temperature, chemical concentrations of minor components and assumed free boundary conditions.The purpose of this paper is to determine the influence of convective laminar processes in the vertical distribution of minor constituents in a thermal interface. Only three minor components are considered, atomic oxygen, molecular oxygen and ozone. Numerical solutions of the stated timedependent convection problem for different Rayleigh numbers show a marked influence of the established flow pattern upon the distribution of minor constituents. In all cases, an enhancement of mean concentration gradients in relatively small regions adjacent to the warmer and colder boundaries was observed. 相似文献
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V. Gallagher M. Feely H. Högelsberger G. R. T. Jenkin A. E. Fallick 《Mineralium Deposita》1992,27(4):314-325
Mo mineralization within the Galway Granite at Mace Head and Murvey, Connemara, western Ireland, has many features of classic porphyry Mo deposits including a chemically evolved I-type granite host, associated K- and Si-rich alteration, quartz vein(Mace Head) and granite-hosted (Murvey) molybdenite, chalcopyrite, pyrite and magnetite mineralization and a gangue assemblage which includes quartz, muscovite and K-feldspar. Most fluid inclusions in quartz veins homogenize in the range 100–350°C and have a salinity of 1–13 eq. wt.% NaCl. They display Th-salinity covariation consistent with a hypothesis of dilution of magmatic water by influx of meteoric water. CO2-bearing inclusions in an intensely mineralized vein at Mace Head provide an estimated minimum trapping temperature and pressure for the mineralizing fluid of 355°C and 1.2 kb and are interpreted to represent a H2O-CO2 fluid, weakly enriched in Mo, produced in a magma chamber by decompression-activated unmixing from a dense Mo-bearing NaCl-H2O-CO2 fluid. 34S values of most sulphides range from c. 0 at Murvey to 3–4 at Mace Head and are consistent with a magmatic origin. Most quartz vein samples have 18O of 9–10.3 and were precipitated from a hydrothermal fluid with 18O of 4.6–6.7. Some have 18O of 6–7 and reflect introduction of meteoric water along vein margins. Quartz-muscovite oxygen isotope geothermometry combined with fluid inclusion data indicate precipitation of mineralized veins in the temperature range 360–450°C and between 1 and 2 kb. Whole rock granite samples display a clear 18O-D trend towards the composition of Connemara meteoric waters. The mineralization is interpreted as having been produced by highlyfractionated granite magma; meteoric water interaction postdates the main mineralizing event. The differences between the Mace Head and Murvey mineralizations reflect trapping of migrating mineralizing fluid in structural traps at Mace Head and precipitation of mineralization in the granite itself at Murvey. 相似文献
8.
Matthias J. Raab Roderick W. Brown Kerry Gallagher Andrew Carter Klaus Weber 《Tectonophysics》2002,349(1-4)
Namibia's passive continental margin records a long history of tectonic activity since the Proterozoic. The orogenic belt produced during the collision of the Congo and Kalahari Cratons in the Early Proterozoic led to a zone of crustal weakness, which became the preferred location for tectonism during the Phanerozoic. The Pan-African Damara mobile belt forms this intraplate boundary in Namibia and its tectonostratigraphic zones are defined by ductile shear zones, where the most prominent is described as the Omaruru Lineament–Waterberg Thrust (OML–WT). The prominance of the continental margin escarpment is diminished in the area of the Central and Northern Zone of the Damara belt where the shear zones are located. This area has been targeted with a set of 66 outcrop samples over a 550-km-long, 60-km-broad coast-parallel transect from the top of the escarpment in the south across the Damara sector to the Kamanjab Inlier in the north. Apatite fission track age and length data from all samples reveal a regionally consistent cooling event. Thermal histories derived by forward modelling bracket this phase of accelerated cooling in the Late Cretaceous. Maximum palaeotemperatures immediately prior to the onset of cooling range from ca. 120 to ca. 60 °C with the maximum occurring directly south of the Omaruru Lineament. Because different palaeotemperatures indicate different burial depth at a given time, the amount of denudation can be estimated and used to constrain vertical displacements of the continental crust. We interpret this cooling pattern as the geomorphic response to reactivation of basement structures caused by a change in spreading geometry in the South Atlantic and South West Indian Oceans. 相似文献
9.
A method is described for evaluating the ‘partial derivatives’ of globally averaged top-of-atmosphere (TOA) radiation changes
with respect to basic climate model physical parameters. This method is used to analyse feedbacks in the Australian Bureau
of Meteorology Research Centre general circulation model. The parameters considered are surface temperature, water vapour,
lapse rate and cloud cover. The climate forcing which produces the changes is a globally uniform sea surface temperature (SST)
perturbation. The first and second order differentials of model parameters with respect to the forcing (i.e. SST changes)
are estimated from quadratic least square fitting. Except for total cloud cover, variables are found to be strong functions
of global SST. Strongly non-linear variations of lapse rate and high cloud amount and height appear to relate to the non-linear
response in penetrative convection. Globally averaged TOA radiation differentials with respect to model parameters are also
evaluated. With the exception of total cloud contributions, a high correlation is generally found to exist, on the global
mean level, between TOA radiation and the respective parameter perturbations. The largest non-linear terms contributing to
radiative changes are those due to lapse rate and high cloud. The contributions of linear and non-linear terms to the overall
radiative response from a 4 K SST perturbation are assessed. Significant non-linear responses are found to be associated with
lapse rate, water vapour and cloud changes. Although the exact magnitude of these responses is likely to be a function of
the particular model as well as the imposed SST perturbation pattern, the present experiments flag these as processes which
cannot properly be understood from linear theory in the evaluation of climate change sensitivity.
Received: 16 January 1997/Accepted: 9 May 1997 相似文献
10.
Scheelite-mineralized microtonalite sheets occur on the SE margin of the end-Caledonian Leinster Granite in SE Ireland. Scheelite,
polymetallic sulphides and minor cassiterite occur in veins in the microtonalites, disseminated throughout the greisened microtonalite
sheets and in the adjacent wallrocks. Two major mineralized vein types occur in the microtonalite sheets: (1) Scheelite ± arsenopyrite ± pyrrhotite
occur in quartz-fluorite veins, generally without a muscovite selvage; (2) Sphalerite ± chalcopyrite ± pyrite ± galena ± cassiterite ± stannite
occur in quartz + fluorite veins with a coarse muscovite selvage and are often intergrown with the muscovite. Quartz-hosted
fluid inclusions were examined from representative samples of both vein types using petrographic, microthermometric and laser
Raman spectroscopic techniques. Three distinct types of fluid inclusions have been recognized. Primary, vapour rich Type 1
inclusions in quartz from the scheelite-mineralized veins are of H2O-CO2-CH4-N2 ± H2S ± NaCl composition and formed between 360–530 °C. Primary and secondary, liquid-rich Type 2 fluid inclusions in the base
metal sulphide-mineralized veins are of H2O-CH4-N2 ± H2S-NaCl composition and formed between 340–480 °C. They also occur as pseudosecondary and secondary inclusions in scheelite-mineralized
veins. Late dilute, low temperature H2O-NaCl + KCl fluid inclusions may be related to late-Caledonian convection of meteoric waters around the cooling Leinster
Granite batholith.
Received: 4 September 1996 / Accepted: 23 May 1997 相似文献