Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations     

B. Andersen  V. Domingo  A. Jiménez  A. Jones  S. Korzennik  P. L. Pallé  F. Pérez Hernández  C. Régulo  T. Roca Cortés  L. L. Tomás 《Solar physics》1988,116(2):391-399

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.  相似文献   

Rapid photo-oxidation of Mn(II) mediated by humic substances     

Peter S Nico  Cort AnastasioRobert J Zasoski 《Geochimica et cosmochimica acta》2002,66(23):4047-4056

The oxidation of Mn(II) by O₂ to Mn(III) or Mn(IV) is thermodynamically favored under the pH and pO₂ conditions present in most near surface waters, but the kinetics of this reaction are extremely slow. This work investigated whether reactive oxygen species, produced through illumination of humic substances, could oxidize Mn at an environmentally relavent rate. The simulated sunlight illumination of a solution containing 200 μM Mn(II) and 5 mg/L Aldrich humic acid buffered at pH 8.1 produced ∼19 μM of oxidized Mn (MnO_x where x is between one and two) after 45 minutes. The major oxidants reponsible for this reaction appear to be photoproduced superoxide radical anion, O₂⁻, and singlet molecular oxygen, ¹O₂. The dependencies of MnO_x formation on Mn(II), humic acid, and H⁺ concentration were characterized. A kinetic model based largely on published rate constants was established and fit to the experimental data. As expected, analysis of the model indicates that the key reaction rate controlling MnO_x production is the rate of decomposition of a MnO₂⁺ complex formed from the reaction of Mn(II) with O₂⁻. This rate is strongly dependent on the Mn(II) complexing ligands in solution. The MnO_x production in the seawater sample taken from Bodega Bay, USA and spiked with 200 μM Mn(II) was well reproduced by the model. Extrapolations from the model imply that Mn photo-oxidation should be a significant reaction in typical surface seawaters. Calculated rates, 5.8 to 55 pM h⁻¹, are comparable to reported rates of biological Mn oxidation, 0.07 to 89 pM h⁻¹. Four fresh water samples that were spiked with 200 μM Mn(II) also showed significant MnO_x production. Based on these results, it appears that Mn photo-oxidation could constitute a significant, and apparently unrecognized geochemical pathway in natural waters.  相似文献   

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico     

Juan Pérez Quezadas  Victor M. Heilweil  Alejandra Cortés Silva  Luis Araguas  María del Rocío Salas Ortega 《Hydrogeology Journal》2016,24(8):1953-1966

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.  相似文献   

The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley     

Robin W. Renaut  R. Bernhart Owen  Tim K. Lowenstein  Gijs De Cort  Emma Mcnulty  Jennifer J. Scott  Anthony Mbuthia 《Sedimentology》2021,68(1):108-134

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.  相似文献   

TITAN2D simulations of pyroclastic flows at Cerro Machín Volcano,Colombia: Hazard implications     

H.F. Murcia  M.F. Sheridan  J.L. Macías  G.P. Cortés 《Journal of South American Earth Sciences》2010,29(2):161-170

Cerro Machín is a dacitic tuff ring located in the central part of the Colombian Andes. It lies at the southern end of the Cerro Bravo–Cerro Machín volcanic belt. This volcano has experienced at least six major explosive eruptions during the last 5000 years. These eruptions have generated pyroclastic flows associated with Plinian activity that have traveled up to 8 km from the crater, and pyroclastic flows associated with Vulcanian activity with shorter runouts of 5 km from the source. Today, some 21,000 people live within a 8 km radius of Cerro Machín. The volcano is active with fumaroles and has shown increasing seismic activity since 2004, and therefore represents a potentially increasing threat to the local population. To evaluate the possible effects of future eruptions that may generate pyroclastic density currents controlled by granular flow dynamics we performed flow simulations with the TITAN2D code. These simulations were run in all directions around the volcano, using the input parameters of the largest eruption reported. The results show that an eruption of 0.3 km³ of pyroclastic flows from a collapsing Plinian column would travel up to 9 km from the vent, emplacing a deposit thicker than 60 m within the Toche River valley. Deposits >45 m thick can be expected in the valleys of San Juan, Santa Marta, and Azufral creeks, while 30 m thick deposits could accumulate within the drainages of the Tochecito, Bermellón, and Coello Rivers. A minimum area of 56 km² could be affected directly by this kind of eruption. In comparison, Vulcanian column-collapse pyroclastic flows of 0.1 km³ would travel up to 6 km from the vent depositing >45 m thick debris inside the Toche River valley and more than 30 m inside the valleys of San Juan, Santa Marta, and Azufral creeks. The minimum area that could be affected directly by this kind of eruption is 33 km². The distribution and thickness of the deposits obtained by these simulations are consistent with the hazard map presented by INGEOMINAS (Geological Survey of Colombia) in 2002. The composite map of the simulated flow deposits suggests that after major explosive events such as these, the generation of lahars is probable.  相似文献   

Analysis of the solar low-ℓ p-mode asymmetries using wavelets     

Régulo  C.  Roca Cortés  T. 《Solar physics》2001,200(1-2):381-391

It is presently widely accepted that the solar low p modes show asymmetric profiles when their power spectrum is analysed and that the fact of fitting symmetric profiles yields systematic effects in the obtained frequencies which could affect the results of inversions. In this paper the low p-mode profiles are analysed using wavelets to denoise the power spectra of the modes. This denoising method is applied both to artificial data generated by Kosovichev (the Hare and Hound exercise) and to real data obtained with the GOLF instrument. The asymmetries as well as the frequencies obtained are studied in both cases. The results show that although the obtained p-mode profiles present a slightly negative asymmetry, the use of symmetric profiles to fit the power spectra does not introduce any systematic effect in the obtained frequencies.  相似文献   

Secular variations in the spectrum of solar p-modes     

A. Jiménez  P. L. Pallé  C. Régulo  T. Roca Cortés 《Solar physics》1994,152(1):253-260

The solar p-mode spectrum of very low I is measured with high accuracy for a long enough period of time so as to allow the search for solar cycle variations. In this paper solar cycle variations of the frequency and energy of the modes are confirmed. Moreover, a slight variation,within errors, of its rotational splitting with the solar cycle, is suggested.  相似文献   

Structure of the 5-minute solar oscillations 1976–1980     

A. Claverie  G. R. Isaak  C. P. McLeod  H. B. Van Der Raay  T. Roca Cortès 《Solar physics》1981,74(1):51-57

The discrete structure in the 5 min velocity oscillations of the solar surface has been confirmed by a re-analysis of data obtained between 1976 and 1979, and in addition a preliminary analysis of 1980 data show excellent consistency of the determined frequencies over the five year period. It is further shown that atmospheric transparency, as measured by the power in the solar intensity fluctuations, shows no correlation with the measured amplitude of the velocity fluctuations, over 2 orders of magnitude.Proceedings of the 14th ESLAB Symposium on Physics of Solar Variations, 16–19 September 1980, Scheveningen, The Netherlands.  相似文献   

Validation and Application of Plants as Biomonitors of Trace Element Atmospheric Pollution – A Co-Ordinated Effort in 14 Countries     

B. Smodiš  M. L. Pignata  M. Saiki  E. CortÉs  N. Bangfa  B. Markert  B. Nyarko  J. Arunachalam  J. Garty  M. Vutchkov  H. Th. Wolterbeek  E. Steinnes  M. C. Freitas  A. Lucaciu  M. Frontasyeva 《Journal of Atmospheric Chemistry》2004,49(1-3):3-13

The International Atomic Energy Agency (IAEA) organized a co-ordinated research project (CRP) on Validation and application of plants as biomonitors of trace element atmospheric pollution analysed by nuclear and related techniques involving 14 participating countries. The CRPs objective was to identify appropriate bioindicators for local and/or regional application and validate them for general air pollution monitoring. Activities included quantification studies, research into spatial and time resolution for particular organisms, and physiological studies. A number of suitable bioindicators were identified in different parts of the globe and tested during the CRP. Sampling strategies were reviewed and the recommended approach adopted by the group. Appropriate sample preparation procedures were assessed and harmonised to the degree allowed by different geographic and climatic conditions in the participating countries. Two interlaboratory comparison exercises were carried out on lichen and moss materials. Results confirmed definite improvement in analytical performance of the participating laboratories, but also revealed possible inconsistencies due to different sample processing procedures. Several monitoring surveys were carried out and consequently pollution maps drawn for extended areas or countries. Overall results confirmed applicability of lower plants for assessing the degree of atmospheric pollution and provided several countries with effective monitoring tools not used before.  相似文献   

Analyses of possible changes in intense and extreme wind speeds over northern Europe under climate change scenarios   总被引：1，自引：0，他引：1  

S. C. Pryor  R. J. Barthelmie  N. E. Clausen  M. Drews  N. MacKellar  E. Kjellstr?m 《Climate Dynamics》2012,38(1-2):189-208

Dynamical downscaling of ECHAM5 using HIRHAM5 and RCA3 for a northern European domain focused on Scandinavia indicates sustained extreme wind speeds with long recurrence intervals (50?years) and intense winds are not likely to evolve out of the historical envelope of variability until the end of C21st. Even then, significant changes are indicated only in the SW of the domain and across the central Baltic Sea where there is some evidence for relatively small magnitude increases in the 50?year return period wind speed (of up to 15%). There are marked differences in results based on the two Regional Climate Models. Additionally, internal (inherent) variability and initial conditions exert a strong impact on projected wind climates throughout the twenty-first century. Simulations of wind gusts by one of the RCMs (RCA3) indicate some evidence for increased magnitudes (of up to +10%) in the southwest of the domain and across the central Baltic Sea by the end of the current century. As in prior downscaling of ECHAM4, dynamical downscaling of ECHAM5 indicates a tendency towards increased energy density and thus wind power generation potential over the course of the C21st. However, caution should be used in interpreting this inference given the high degree of wind climate projection spread that derives from the specific AOGCM and RCM used in the downscaling.  相似文献