Argon isotope fractionation induced by stepwise heating     

Mario Trieloff  Martina Falter  Ekaterina V. Korochantseva  Rainer Altherr 《Geochimica et cosmochimica acta》2005,69(5):1253-1264

Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by ⁴⁰Ar-³⁹Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by ³⁸Ar/³⁶Ar and ⁴⁰Ar/³⁶Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric ⁴⁰Ar/³⁶Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems.In ⁴⁰Ar-³⁹Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly precise dating technique. Our results also indicate the importance of thermally activated diffusion as a possible fractionation mechanism, e.g., for hydrothermal gas exhalations, or for carbonaceous carrier phases such as “Q” in meteorites that have been suggested as carriers of highly fractionated noble gas residues from the early solar nebula.  相似文献   

An applied model for the height of the daytime mixed layer and the entrainment zone     

Ekaterina Batchvarova  Sven-Erik Gryning 《Boundary-Layer Meteorology》1994,71(3):311-323

A model is presented for the height of the mixed layer and the depth of the entrainment zone under near-neutral and unstable atmospheric conditions. It is based on the zero-order mixed-layer height model of Batchvarova and Gryning (1991) and the parameterization of the entrainment zone depth proposed by Gryning and Batchvarova (1994). However, most zero-order slab type models of mixed-layer height may be applied. The use of the model requires only information on those meteorological parameters that are needed in operational applications of ordinary zero-order slab type models of mixed-layer height: friction velocity, kinematic heat flux near the ground and potential temperature gradient in the free atmosphere above the entrainment zone. When information is available on the horizontal divergence of the large-scale flow field, the model also takes into account the effect of subsidence, although this is usually neglected in operational models of mixed-layer height owing to lack of data. Model performance is tested using data from the CIRCE experiment.  相似文献   

Campanian Climatic Change: Isotopic Evidence from Far East, North America, North Atlantic and Western Europe          下载免费PDF全文

Yuri D. Zakharov  Yasunari Shiget  Kazushige Tanabe  Yasuhiro I  Olga P. Smyshlyaev  Ekaterina A. Sokolov  Alexer M. Popov  Tatiana A. Velivetskay  Tamara B. Afanasyeva 《《地质学报》英文版》2007,81(6):1049-1069

Paleoclimatic settings have been reconstructed for the Campanian using original oxygen-isotopic analyses of well-preserved molluskan and foraminifera shells from Russian Far East, Hokkaido, USA, Belgium and some DSDP holes (95, 98, 102, 390A, and 392A) in North Atlantic. Early Early Campanian climatic optimum has been recognized from data on high bottom shelf water paleotemperatures in middle latitudes of both the western circum-Pacific (to 24.2°C) and the eastern circum-Pacific (to 26.4°C) areas and high bottom shallow water paleotemperatures in high latitudes of the Koryak Upland (22.4–25.5°C), which agrees with the data on the Campanian Barykovskaya flora in high latitudes (Golovneva and Herman, 1998) and Jonker flora and its equivalents in middle latitudes. Judging from the data on comparatively high bottom shallow water paleotemperature values in high latitudes, South Alaska (19.4°C) and the Koryak Upland (22.4–25.5°C), we also expect Latest Campanian temperature maximum, which has not been confirmed, however, for low and middle latitudes by neither of isotopic nor paleobotanic data now. Main climatic tendency during the Campanian (with the exception of Latest Campanian) has been learned from isotopic composition of Campanian aragonitic ammonoid shells from the Hokkaido-South Sakhalin (Krilyon) marine basin. In contrary to Huber’s et al. (2002) assumption, we expect warm greenhouse conditions during the most part of the Campanian.  相似文献   

Energy Balance Of A Sparse Coniferous High-Latitude Forest Under Winter Conditions   总被引：1，自引：0，他引：1  

Sven-Erik Gryning  Ekaterina Batchvarova  H. A. R. De Bruin 《Boundary-Layer Meteorology》2001,99(3):465-488

Measurements carried out in Northern Finland on radiation and turbulent fluxes over a sparse, sub-arctic boreal forest with snow covered ground were analysed. The measurements represent late winter conditions characterised by low solar elevation angles. During the experiment (12–24 March 1997) day and night were about equally long. At low solar elevation angles the forest shades most of the snow surface. Therefore an important part of the radiation never reaches the snow surface but is absorbed by the forest. The sensible heat flux above the forest was fairly large, reaching more than 100 W m^-2. The measurements of sensible heat flux within and above the forest revealed that the sensible heat flux from the snow surface is negligible and the sensible heat flux above the forest stems from warming of the trees. A simple model for the surface energy balance of a sparse forest is presented. The model treats the diffuse and direct shortwave (solar) radiation separately. It introduces a factor that accounts for the shading of the ground at low solar elevation angles, and a parameter that deals with the partial transparency of the forest.Input to the model are the direct and diffuse incoming shortwave radiation.Measurements of the global radiation (direct plus diffuse incoming shortwaveradiation) above the forest revealed a considerable attenuation of the globalradiation at low solar elevation. A relation for the atmospheric turbidity asfunction of the solar elevation angle is suggested. The global radiation wassimulated for a three month period. For conditions with a cloud cover of lessthan 7 oktas good agreement between model predictions and measurementswere found. For cloud cover 7 and 8 oktas a considerable spread can beobserved. To apply the proposed energy balance model, the global radiationmust be separated into its diffuse and direct components. We propose a simpleempirical relationship between diffuse shortwave and global radiation asfunction of cloud cover.  相似文献   

On the Nature of the Impactor That Formed the Shackleton Crater on the Moon     

Svetlana G. Pugacheva  Ekaterina A. Feoktistova  Vladislav V. Shevchenko 《Earth, Moon, and Planets》2016,118(1):27-50

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Trace-element study and uranium-lead dating of perovskite from the Afrikanda plutonic complex, Kola Peninsula (Russia) using LA-ICP-MS     

Ekaterina P. Reguir  Alfredo Camacho  Panseok Yang  Anton R. Chakhmouradian  Vadim S. Kamenetsky  Norman M. Halden 《Mineralogy and Petrology》2010,100(3-4):95-103

The U-Pb geochronology of perovskite is a powerful tool in constraining the emplacement age of silica-undersaturated rocks. The trace-element and U-Pb isotopic compositions of perovskite from clinopyroxenite and silicocarbonatite from the Afrikanda plutonic complex (Kola, Russia) were determined by laser-ablation inductively-coupled mass-spectrometry (LA-ICP-MS). In addition, the Sr isotopic composition of perovskite was measured by isotope-dilution mass-spectrometry to better constrain the relations between its host rocks. Perovskite from the two rock types shows a different degree of enrichment in Na, Mg, Mn, Pb, Fe, Al, V, rare-earth elements, Zr, Hf, Th, U and Ta. The perovskite ⁸⁷Sr/⁸⁶Sr values are within analytical uncertainty of one another and fall within the range of mantle values. The ²⁰⁶Pb/²³⁸U ages (corrected for common lead using ²⁰⁷Pb-method) of perovskite from silicocarbonatite statistically yield a single population with a weighted mean of 371?±?8 Ma (2σ; MSWD?=?0.071). This age is indistinguishable, within uncertainty, to the clinopyroxenite weighted mean ²⁰⁶Pb/²³⁸U age of 374?±?10 Ma (2σ; MSWD?=?0.18). Our data are in good agreement with the previous geochronological study of the Afrikanda complex. The observed variations in trace-element composition of perovskite from silicocarbonatite and clinopyroxenite indicate that these rocks are not related by crystal fractionation. The Sr isotopic ratios and the fact that the two rocks are coeval suggest that they were either produced from a single parental melt by liquid immiscibility, or from two separate magmas derived at different degrees of partial melting from an isotopically equilibrated, but modally complex mantle source.  相似文献   

Chromium solubility in MgSiO3 ilmenite at high pressure     

Luca Bindi  Ekaterina A. Sirotkina  Andrey V. Bobrov  Tetsuo Irifune 《Physics and Chemistry of Minerals》2014,41(7):519-526

The crystal structure and chemical composition of crystals of (Mg_1?x Cr _x )(Si_1?x Cr _x )O₃ ilmenite (with x = 0.015, 0.023 and 0.038) synthesized in the model system Mg₃Cr₂Si₃O₁₂–Mg₄Si₄O₁₂ at 18–19 GPa and 1,600 °C have been investigated. Chromium was found as substitute for both Mg at the octahedral X site and Si at the octahedral Y site, according to the reaction Mg²⁺ + Si⁴⁺ = 2Cr³⁺. Such substitutions cause a shortening of the <X–O> and a lengthening of the <Y–O> distances with respect to the values typically observed for pure MgSiO₃ ilmenite and eskolaite Cr₂O₃. Although no high Cr contents are considered in the pyrolite model, Cr-bearing ilmenite may be the host for chromium in the Earth’s transition zone. The successful synthesis of ilmenite with high Cr contents and its structural characterization are of key importance because the study of its thermodynamic constants combined with the data on phase relations in the lower-mantle systems can help in the understanding of the seismic velocity and density profiles of the transition zone and the constraining composition and mineralogy of pyrolite in this area of the Earth.  相似文献   

X-ray single-crystal and Raman study of knorringite,Mg3(Cr1.58Mg0.21Si0.21)Si3O12, synthesized at 16 GPa and 1,600 °C     

Elena A. Bykova  Andrey V. Bobrov  Ekaterina A. Sirotkina  Luca Bindi  Sergey V. Ovsyannikov  Leonid S. Dubrovinsky  Yuriy A. Litvin 《Physics and Chemistry of Minerals》2014,41(4):267-272

The crystal structure of a knorringite-type compound, Mg₃(Cr_1.58Mg_0.21Si_0.21)Si₃O₁₂, synthesized in a multi-anvil press at P = 16 GPa and T = 1,600 °C, was refined from single-crystal X-ray diffraction data up to R = 2.36 % for 314 independent reflections. Garnet was found to be cubic and have space group Ia $\overline{3}$ d, with the unit cell parameters a = 11.5718 (1) Å, V = 1,549.54 (2) Å³. The knorringite crystal studied contains 21 mol% of majorite end-member. The structural characterization of knorringitic garnet is important because the study of its thermodynamic constants provides new constraints on thermobarometry of peridotitic garnet assemblages of the lowermost upper mantle. The Raman spectra of synthetic knorringite have been obtained for the first time.  相似文献   

Satellite-based analysis of the spatial patterns of fire- and storm-related forest disturbances in the Ural region,Russia     

Shikhov  Andrey N.  Perminova  Ekaterina S.  Perminov  Sergey I. 《Natural Hazards》2019,97(1):283-308

Natural Hazards - Large-scale wildfires and windstorms are the most important disturbance agents for the Russian boreal forests. The paper presents an assessment of fire-related and wind-induced...  相似文献   

Chemical and biological features of the saline Lake Krasnovishnevoye (Baraba,Russia) in comparison with Lake Malinovoe (Kulunda,Russia): a reconnaissance study     

Komova  Anastasia  Melnikova  Anna  Namsaraev  Zorigto  Romanov  Roman  Strakhovenko  Vera  Ovdina  Ekaterina  Ermolaeva  Nadezhda 《中国海洋湖沼学报》2018,36(6):1993-2001

The Baraba and Kulunda steppes are located in southwestern Siberia in an area with an arid continental climate. This paper presents results of the first study of the hypersaline Lake Krasnovishnevoye(Baraba steppe, TDS(total dissolved solids)=297 g/L, pH 7.88). The major chemical, mineralogical and biological features of the lake were studied and compared to those of Lake Malinovoe, a typical saline neutral lake of Kulunda steppe(TDS=396 g/L, pH 7.63). The phytoplankton composition and the culturable diversity of anoxygenic phototrophic bacteria from Lake Krasnovishnevoye correspond to the ones in the Kulunda lakes. Nevertheless, the peculiarities of water composition and regime of Lake Krasnovishnevoye reduce the biodiversity to prokaryotes and unicellular algae.  相似文献