Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

Erratum:"The Lyman-alpha Solar Telescope(LST)for the ASO-S mission—I.Scientific objectives and overview"(2019,RAA,19,158)     

Hui Li  Bo Chen  Li Feng  Ying Li  Yu Huang  Jing-Wei Li  Lei Lu  Jian-Chao Xue  Bei-Li Ying  Jie Zhao  Yu-Tong Yang  Wei-Qun Gan  Cheng Fang  Ke-Fei Song  Hong Wang  Quan-Feng Guo  Ling-Ping He  Bo Zhu  Cheng Zhu  Lei Deng  Hai-Chao Bao  Cai-Xia Cao  Zhong-Guang Yang 《天文和天体物理学研究(英文版)》2021,(2)

As a result of an error by the authors,in the paper"The Lyman-alpha Solar Telescope(LST)for the ASO-S Mission.I.Scientific Objectives and Overview"by Hui Li et al.(RAA 2019 Vol.19,No.11,158,doi:10.1088/1674C4527/19/11/158),there is an error occurred in Table 2 about the image size of SCI UV in the'Event'mode:the image size 4608×4608 should be replaced by 2048×2048.This correction is indicated in bold face in the following table.  相似文献   

Precise Location of Earthquakes at the Eastern Boundaries of the Sichuan-Yunnan Rhombic Block     

Fu Ying  Hu Bin  Long Feng  Wang Shiyuan 《中国地震研究》2018,32(4):470-481

Based on the seismic station data sets from Sichuan and Yunnan provinces, we employed a multi-step seismic location method (Hypo2000 + Velest + HypoDD) to precisely locate the 7,787 earthquakes that occurred during 2010-2015 along the eastern boundaries of the Sichuan-Yunnan rhombic block, namely from southern Dawu to the Qiaojia segment. The final results show that location precision is greatly advanced and epicenter distribution exhibits good consistency with the linear distribution of the seismic faults. Earthquake distribution is quite intensive at the intersection region in the southern segment of the Xianshuihe fault, the Anninghe fault zone, the Xiaojinhe fault zone and the Daliangshan fault zone to the east. The depth profile of seismicity shows a clear stepwise activity along the active seismic fault zones. The profile crossing the faults of the Xianshuihe, Anninghe, and Daliangshan presents a complex interaction among faults near the multiple faults intersection region, Shimian, where the earthquakes are obviously divided into two groups in depth. Earthquakes are very rare at the depth of 15km-20km, which is consistent with the region of the plastic rheology between 14km-19km calculated by Zhu Ailan et al.,(2005).  相似文献   

The time and frequency standard system for FAST receivers     

朱凯  范瑾  Kun Liang  Wei Tang  Zhi-Sheng Gao  Yan Zhu  Yi Feng  Wei-Wei Zhu  Lei Qian  You-Ling Yue  Jin-You Song  Xiang-Wei Shi  Xing-Yi Wang  Ming-Lei Guo  Hang Zhang  Heng-Qian Gan  Hong-Fei Liu  Cheng-Jin Jin  Peng Jiang 《天文和天体物理学研究(英文版)》2020,(5):148-154

This paper reports on the time and frequency standard system for the Five-hundred meter Aperture Spherical radio Telescope(FAST),including the system design,stability measurements and pulsar timing observations.The stability and drift rate of the frequency standard are calculated using 1-year monitoring data.The UTC-NIM Disciplined Oscillator(NIMDO)system improves the system time accuracy and stability to the level of 5 ns.Pulsar timing observations were carried out for several months.The weighted RMS of timing residuals reaches the level of less than 3.0μs.  相似文献   

昔日“煤海明珠”的成功转型 走进山西大同晋华宫矿国家矿山公园     

胡光晓  程东卫 《地球》2019,(3)

正在大同"世界文化遗产"云冈石窟的南面有一座矿山公园,与云冈石窟隔河相望,她就是山西大同晋华宫矿国家矿山公园。这是一座饱含民族煤炭工业底蕴的文化创意园、一座极具研究价值和观赏价值的地质科考园,悠久的煤炭开采历史元素渗透到公园的景区各个部分。它被国际休闲产业协会授予"国际休闲生态旅游示范区",被国际文化旅游推进会、中国旅游品牌协会、中国生态旅游发展协会评为"中国最具特色生态旅游目的地",被山西省旅游局评为"2014山西百佳旅游休闲产品"。  相似文献   

“雨霁芙蓉曙 春深草树馨” 走进广东韶关芙蓉山国家矿山公园     

胡光晓  熊嘉育  陆宝明 《地球》2019,(4)

正位于广东省韶关市区新民路西南端的芙蓉山,蕴藏着丰富的矿物资源,曾有过辉煌的煤矿和石灰岩矿开采历史,至今山上仍然残存大量采矿遗迹。2005年8月23日,经原国土资源部批准,广东韶关芙蓉山国家矿山公园成为首批国家矿山公园。2009年6月18日开园。这里不仅能够领略芙蓉山秀美的自然风光,还可以学到地学、古生物、矿业等科普知识,是集历史、文化、艺术于一体的科普教育基地,  相似文献   

青藏高原不同土地覆盖类型下积雪面积判别算法优化北大核心CSCD     

谢佩瑶韩超欧阳志棋王晓艳 《冰川冻土》2023,(3):1168-1179

MODIS V006版本数据仅提供了归一化积雪指数(NDSI),而用户往往关心的是直观的积雪分类,包括积雪范围或积雪覆盖率。美国国家冰雪数据中心推荐全球积雪范围最佳的NDSI阈值为0.4,但是青藏高原地形复杂多样,积雪斑块化特征明显,单一阈值并不能精确地判识不同下垫面上的积雪。青藏高原被称为地球的第三极,是中国三大稳定积雪区之一,蕴藏了大量的淡水资源。随着全球气候变暖,青藏高原地区积雪融化时间提前,冰川融水增加,影响河流水量,造成洪涝灾害,进而影响人类正常生产生活,因此通过确定不同下垫面阈值,改善传统阈值的积雪高估低估现象,提高积雪识别精度,进而更准确地探究青藏高原积雪状况,显得尤为迫切。本文以青藏高原为研究对象,首先生成MODIS逐日无云NDSI序列并进行验证;其次对应站点雪深数据与NDSI序列,证实在下垫面为林地和非林地的区域,去云NDSI序列与站点雪深均有良好的对应关系,确定不同下垫面最优阈值范围;最后在最优阈值范围内通过混淆矩阵确定最优阈值。计算得出,林地NDSI=0.03时,总体精度最高为94.02%,在该NDSI之下,高估误差OE和低估误差UE分别为1.21%和4.60%;非林地NDSI=0.26时,总体精度OA最高为94.27%,在该NDSI之下,高估误差OE和低估误差UE分别为0.51%和5.03%。因此选取优化后林地阈值为NDSI=0.03,非林地阈值为NDSI=0.26。为避免地面常规观测资料尺度上的局限性,本文采用高精度的Landsat 8 OLI卫星数据识别结果,作为“真值”对优化后阈值的判别结果进行“像元—像元”级别的验证。在定量验证中,优化后NDSI阈值对MOD10A1 V006积雪判别结果的总体精度OA为84.21%,高估误差OE为5.33%,低估误差UE为10.46%;传统阈值对MOD10A1 V006积雪判别结果的总体精度OA为82.86%,高估误差OE为1.48%,低估误差UE为15.66%。可以看出在定量验证中,优化后阈值的积雪判别精度更高。同时在定性验证中,积雪大面积集中的区域,新的阈值与传统阈值提取效果均相对较好;积雪相对分散破碎的区域,优化后阈值能提取出大量积雪,传统阈值则不能。这表明考虑不同土地覆盖类型下的NDSI阈值优化可以有效地提高青藏高原积雪判别精度,为NDSI在积雪识别中的应用提供有力的支撑,有助于更准确地了解该地区积雪分布状况。  相似文献   

Fracture Characteristics and Heat Accumulation of Jixianian Carbonate Reservoirs in the Rongcheng Geothermal Field, Xiong’an New Area     

WANG Yingjin  MA Feng  XIE Heping  WANG Guiling  WANG Zhihe 《《地质学报》英文版》2021,95(6):1902-1914

Geothermal energy plays an important role in urban construction of the Xiong’an New Area. Geothermal reservoir fracture distribution of the Mesoproterozoic Jixianian Wumishan Formation (Fm.) carbonate reservoir in the Rongcheng geothermal field are evaluated based on FMI log from Wells D19 and D21. The results show carbonate reservoir fracture density of Well D19 is 15.2/100 m, greater than that of Well D21 with a value of 9.2/100 m. Reservoir porosity and permeability of Well D19 are better than that of Well D21, and the water saturation is bimodally distributed. The movable fluid volume ratio (BVM) of Well D19 is 2% to 8% with some zones exceeding 20%, while the value of Well D21 is less than 4%. Therefore, reservoir fractures in Well D19 are more conducive to fluid flow. Reservoir fractures have a similar occurrence to normal faults, indicating that the tensile stress field controlled the formation of such fractures. Developed reservoir fractures provide a good channel for groundwater convection. The circulation of regional groundwater and the heat exchange between water and rock and the multiple heat accumulation patterns form a stable and high potential heat reservoir in the Rongcheng geothermal field.  相似文献   

Recent advances in monsoon studies in China   总被引：8，自引：0，他引：8  

XUE Feng  ZENG Qingcun  HUANG Ronghui  LI Chongyin  LU Riyu  ZHOU Tianjun 《大气科学进展》2015,32(2):206-229

This review provides a synopsis of the major progress that has been made in monsoon studies in China and to further bridge the gap between the Chinese and international meteorological community. It consists of seven major sections. After the introduction, the second section begins with the global monsoon systems and their seasonal variation, based on some new methods proposed in recent years. Besides, some major intraseasonal features of East Asian monsoon, including the onset of South China Sea summer monsoon are discussed. In the third section, we review the interactions between ENSO and the East Asian monsoon, focusing in particular on the results of Chinese meteorologists that indicate the influence of ENSO on the East Asian summer monsoon(EASM) is obviously different from that on the tropical monsoon. Besides the tropical Pacific,other ocean basins, such as the Indian Ocean and the Atlantic Ocean, are also important to the East Asian monsoon, and this topic is discussed in the fourth section. In the fifth section, we address the role of land surface processes in East Asian monsoon. For example, we describe work that has shown more snow cover in spring on the Tibetan Plateau is followed by a weakened EASM and more summer rainfall in the Yangtze River valleys. The sixth section focuses on the influence of atmospheric circulation in the Southern Hemisphere(SH) on EASM, demonstrating how the signal from the SH is likely to provide new clues for the seasonal forecasting of summer rainfall in China. Finally, in the seventh section, we concentrate on the interdecadal variations of EASM. In particular, we look at a significant interdecadal variation that occurred at the end of the 1970 s, and how our understanding of this feature could affect forecasting ability.  相似文献   

Expression Analysis of the Insulin-Like Growth Factors Ⅰ and Ⅱ During Embryonic and Early Larval Development of Turbot(Scophthalmus maximus)     

WEN Haishen  QI Qian  HU Jian  SI Yufeng  HE Feng  LI Jifang 《中国海洋大学学报(英文版)》2015,(2):309-316

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