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1.
Summary ?A single-crystal X-ray investigation was performed on crystals of P21/c natural pigeonite with varying Ca and Fe* ( = Fe2+ + Mn2+) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal
chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal
free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains
and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae.
The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than
that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated.
The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples.
In particular, it is shown that Ca and Fe* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and
decrease the difference between the M2–O3 distances.
Received October 18, 2001; revised version accepted February 15, 2002 相似文献
2.
At first-order of approximation a sea-state may be considered as an infinite sum of Airy components with angular frequencies ωi and wave-number vectors ki. A second-order analysis shows the co-existence of long waves appearing at the difference frequencies ωi—ωj with wave-number vectors ki—kj. In shallow water they become appreciable in amplitudes and may induce slow-drift motion of moored structures.For small values of ωi—ωj,ki—kj may take all kinds of directions for an angular-spread wave system. Then it may be questioned how the in-line and transverse second-order accelerations compare to those obtained for a mono-directional wave-system.This analysis is carried out here by relating the spectra of the second-order horizontal accelerations to the directional wave-spectrum. Numerical applications are first performed for deep water. They show that at low frequencies, even for very narrowly spread wave systems, the transverse component is larger than the in-line component. In shallow water both components are dratically reduced as compared to the mono-directional case. As a consequence one may question the validity of model-testings or numerical models which take no account of the directionality of the wave-system. 相似文献
3.
Summary The crystal-chemistry of clinopyroxene from a suite of Sunda arc volcanic rocks was investigated by X-ray structure refinement and microprobe analysis. Relationships with clinopyroxene from volcanic rocks of the intraplate environment were highlighted.Sunda clinopyroxenes were distinguished into two groups. The first consists of clinopyroxene from SiO2-saturated rock types and crystal rim from SiO2-undersaturated rock types, the second of crystal core from SiO2-undersaturated rock types. The crystal chemical behaviour of the two groups differs significantly, mainly in the geometrical relationships between M2 and T sites. While in the first group M2-O3 and T-O3 bond lengths shorten and lengthen respectively due to Ca and AlIV increase, in the second group in which M2 site is almost fully coordinated by Ca, -O3 bond lengths are forced to lengthen in spite of low AlIV content, in order to mantain the local charge balance around the O3 oxygens.It is noteworthy that Sunda clinopyroxene shows strong analogies with that from basaltic rocks from the Ethiopian plateau and K-rich lavas from the Roman Province respectively, reflecting similarities between the composition and mineralogical assemblages of the host rocks, although they all came from different tectonic environments. A relationship between intracrystalline Mg-Fe 2+ disorder and the explosive character of the volcanism is demonstrated.
Kristallchemie von Klinopyroxenen aus Gesteinen des Vulkanbogens der Sunda-Inseln
Zusammenfassung Die Kristallchemie von Klinopyroxenen aus einer Serie von vulkanischen Gesteinen des Sunda-Bogens wurde mit Röntgen-Strukturverfeinerungen und Mikrosonden-analysen untersucht. Beziehungen zu Klinopyroxenen vulkanischer Gesteine aus intra-Plattenpositionen werden beleuchtet. Die Sunda-Klinopyroxene wurden in zwei Gruppen eingeteilt. Die erste umfaßt Klinopyroxene SiO2-gesättigter Gesteinstypen und Kristallsäume SiO2-untersättigter Gesteinstypen, die zweite Kristallkerne SiO2-untersättigter Gesteinstypen. Das kristallchemische Verhalten der beiden Gruppen unterscheidet sich beträchtlich, hauptsächlich in den geometrischen Beziehungen zwischen den M2 und T Positionen. Während in der ersten Gruppe die M2-O3 und T-O3 Bindungsldngen durch Zunahme von Ca und AlIV kleiner bzw. größer werden, sind in der zweiten Gruppe die T-O3 Bindungslängen trotz niedrigen AlIV Gehaltes zu einer Vergrößerung gezwungen, damit um die O3 Atome der lokale Ladungsausgleich erhalten bleibt.Es ist bemerkenswert, daß die Sunda-Klinopyroxene große Analogien zu denen aus basaltischen Gesteinen des Abessinischen Plateaus und aus K-reichen Laven sowohl der Römischen Provinz als auch des Westafrikanischen Grabens zeigen. Dies spiegelt Ähnlichkeiten zwischen Zusammensetzung und Mineralbestand der Muttergesteine wider, obwohl sie all aus tektonisch unterschiedlichen Positionen kommen.Eine Beziehung zwischen intrakristalliner Mg-Fe2+ Unordnung und dem explosiven Charakter des Vulkanismus wird aufgezeigt.相似文献
4.
Eric J.E. Molin Harmen Oppewal Harry J.P. Timmermans 《Journal of Geographical Systems》2002,4(4):343-358
In this paper, two approaches for measuring residential group preferences, based on the method of Hierarchical Information
Integration (HII), are compared. In particular, the hypothesis that group-based preference models estimated from integrated
HII experiments better predict group preferences than part individual-based group models estimated from classical HII experiments
is tested. To that effect, the models' ability to predict group preferences for new residential alternatives is compared in
a study of residential preferences of co-ops. Results indicate that integrated HII group experiments indeed result in better
predictions of residential preferences. 相似文献
5.
镇江市古运河边岸滑坡干扰了城市交通、航运和河道整治工程的正常运行。本文研究了城市边岸的工程环境、滑坡形态、特有的城市地质环境恶化所诱发的边岸破坏机制及其稳定性,它对我同城市水陆交通发展所导致的斜坡地质灾害及其治理有实用价值。 相似文献
6.
利用树轮宽度重建黄河源区1618—2009年5—6月最高气温 总被引：1，自引：0，他引：1
利用采集自青海省雪山乡的祁连圆柏建立树轮宽度标准年表,将标准年表与黄河源区内4个气象站各气象要素作相关分析,结果显示整个源区5—6月最高气温与标准年表相关性最显著,相关系数为-0.65。根据相关分析结果,重建了黄河源区1618—2009年5—6月最高气温距平序列,重建方程经过逐一剔除检验,方差解释量达42.2%,具有一定的可靠性。重建序列在近400年间先后经历了8个较暖时间段和8个较冷时间段,暖期时段有1644—1656、1727—1746、1786—1797、1817—1835、1860—1885、1916—1934、1952—1968和1992—2005年,冷期的时段分别为1632—1643、1657—1696、1747—1764、1798—1816、1836—1859、1898—1915、1935—1951和1969—1991年。对比本次重建序列与杂多、青藏高原东部以及长江源的气温重建序列,发现以上序列在公共时段变化趋势一致,另外,一些文献和历史记载也证实了此次重建的可靠性。 相似文献
7.
8.
M.?Stimpfl J.?GangulyEmail author G.?Molin 《Contributions to Mineralogy and Petrology》2005,150(3):319-334
We determined the forward rate constant (K+) for the Fe2+–Mg order–disorder between the M2 and M1 sites of orthopyroxene (OPx), which is described by the homogeneous reaction Fe2+ (M2) + Mg(M1) ↔ Mg(M2) + Fe2+ (M1), by both ordering and disordering experiments at isothermal condition and also by continuous cooling experiments. The
rate constant was determined as a function of temperature in the range of 550–750°C, oxygen fugacity between quartz–fayalite–iron
and Ni–NiO buffers, and at compositions of 16 and 50 mol% ferrosilite component. The K+ value derived from disordering experiment was found to be larger than that derived from ordering experiment at 550°C, while
at T>580°C, these two values are essentially the same. The fO2 dependence of the rate constant can be described by the relation K+ α (fO2)
n
with n=5.5–6.5, which is compatible with the theoretically expected relation. The Arrhenius relation at the WI buffer condition
is given by
where C
o represents the total number of M2 + M1 sites occupied by Fe2+ and Mg per unit volume of the crystal. The above relation can be used to calculate the cooling rates of natural OPx crystals
around the closure temperature (T
c) of Fe–Mg ordering, which are usually below 300°C for slowly cooled rocks. We determined the Fe–Mg ordering states of several
OPx crystals (∼ Fs50) from the Central Gneissic Complex (Khtada Lake), British Columbia, which yields T
c ∼290°C. Numerical simulation of the change of Fe2+-Mg ordering in OPx as a function of temperature using the above expression of rate constant and a non-linear cooling model
yields quenched values of ordering states that are in agreement with the observed values for cooling rates of 11–17°C/Myr
below 300°C. The inferred cooling rate is in agreement with the available geochronological constraints. 相似文献
9.
The evaluation of the seismic damageability of existing buildings is a primary element in the planning for mitigation of earthquake effects. To this purpose, the use of the vulnerability index has been recently proposed and adopted in various surveys in Italy. The index results from grading the status of various structural and non-structural components exposed to damage in a seismic event. The effectiveness of the vulnerability index as a measure of the health status of buildings is discussed on the basis of regional surveys of vulnerability index versus reported damage, carried out in various Italian areas such as Friuli and the city of Gubbio. Also, investigation of the items most effective in describing damageability among those contributing to the index is performed, in view of formulating a reduced survey procedure. A damage versus vulnerability index database collected in these surveys is presented as well. Finally, a vulnerability index based procedure to evaluate the expected damage in a territory is proposed. 相似文献
10.