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Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).  相似文献   
2.
The relationship between particulate organic carbon (POC) concentrations measured in modern sediment and fluxes of exported POC to the sediment surface needs to be understood in order to use POC content as a proxy of paleo-environmental conditions. The objective of our study was to compare POC concentrations, POC mineralization rates calculated from O2 consumption and POC burial rates. Benthic O2 distributions were determined in 58 fine-grained sediment cores collected at different periods at 14 stations in the southeastern part of the Bay of Biscay with depths ranging from 140 to 2800 m. Depth-dependent volume-specific oxygen consumption rates were used to assess rates of aerobic oxidation of organic matter (OM), assuming that O2 consumption solely was related to heterotrophic activity at the sediment–water interface. Heterogeneity of benthic O2 fluxes denoted changes in time and space of fresh organic material sedimentation. The most labile fraction of exported POC engendered a steep decrease in concentration in the upper 5 mm of vertical O2 profiles. The rupture in the gradient of O2 microprofile may be related to the bioturbation-induced mixing depth of fast-decaying carbon. Average diffusive O2 fluxes showed that this fast-decaying OM flux was much higher than buried POC, although diffusive O2 fluxes underestimated the total sediment oxygen demand, and thus the fast-decaying OM flux to the sediment surface. Sedimentary POC burial was calculated from sediment mass accumulation rate and the organic carbon content measured at the top of the sediment. The proportion of buried POC relative to total exported POC ranged at the most between 50% and 10%, depending on station location. Therefore, for a narrow geographic area like the Bay of Biscay, burial efficiency of POC was variable. A fraction of buried POC consisted of slow-decaying OM that was mineralized within the upper decimetres of sediment through oxic and anoxic processes. This fraction was deduced from the decrease with depth in POC concentration. At sites located below 500 m water depth, where the fast-decaying carbon did not reach the anoxic sediment, the slow-decaying pool may control the O2 penetration depth. Only refractory organic material was fossilized in sedimentary records at locations where labile OM did not reach the anoxic portion of the sediment.  相似文献   
3.
Hydrographic structure of the water column, dissolved nutrient concentrations and the distribution of suspended particulate matter were recorded from CDT measurements and Niskin bottles sampling on the continental slope of the Bay of Biscay and on the axis of Capbreton canyon. Ascorbate extraction was applied here for the first time on marine suspended particles to determine the content of reactive Fe- and Mn-oxides, and P associated with Fe-oxides. Hydrographic structure of the south-eastern part of the Bay of Biscay did not change during the last three decades. Particulate organic carbon (POC) contents dropped strongly with depth, showing that organic matter mineralization was efficient in the water column. Organic matter mineralized in the water column had a Redfield N:P ratio. POC percent of particles collected at depth were higher during a bloom period, suggesting that some new organic matter reached the bottom. Contents of Fe and Mn extracted with the ascorbate leaching solution showed that suspended particles originated from the Gironde estuary, one of the major sources of particles in the Bay of Biscay. Intermediate and deeper nepheloid layers occurred in the Capbreton canyon. Particles of nepheloid layers were enriched in Mn- and Fe-oxides because they originated from resuspension of surface sediment.  相似文献   
4.
This study reports the results of a field experiment using benthic mesocosms that examined dose-dependent effects of mussel biodeposition on the benthic environment. Mesocosms were placed in the natural sea bottom and subjected to one of eight levels of biodeposition (from 0 to 1400 mussels m?2). Most analyses indicated non-linear (i.e., threshold) effects. Sediment characteristics changed significantly between 200 and 400 mussels m?2 as did multivariate community structure. Community structure effects were characterised by changes in abundances of species that are very sensitive or tolerant to organic loading. The multivariate AZTI Marine Biotic Index (M-AMBI) indicated that the benthic status changed from High to Good in all mesocosms receiving biodeposits. Sediments acted as a sink for oxygen (O2), but results suggest O2 sediment demand was not sensitive enough to evaluate organic loading impacts. Results from this and improved experiments can be used to determine the environmental carrying capacity of sites for bivalve culture.  相似文献   
5.
The offshore branch of the East African Rift System (EARS) has developed during Late Cenozoic time along the eastern Africa continental margin. While Neogene–Pleistocene extensional tectonic deformation has been evidenced along the northern segment of the Davie Ridge, the spatial extent of deformation further south remains poorly documented. Based on recent and various oceanographic datasets (bathymetric surveys, dredge samples and seismic profiles), our study highlights active normal faulting, modern east–west extensional tectonic deformation and Late Cenozoic alkaline volcanism at the Sakalaves Seamounts (18°S, Davie Ridge) that seem tightly linked to the offshore EARS development. In parallel, rift‐related tectonic subsidence appears responsible for the drowning of the Sakalaves Miocene shallow‐water carbonate platform. Our findings bring new insights regarding the development of the EARS offshore branch and support recent kinematic models proposing the existence of a plate boundary across the Mozambique Channel.  相似文献   
6.

Clay minerals and clayey soils have been extensively researched over the last century leading to a rich and still evolving corpus of knowledge on clay chemistry, microstructure and macroscopic behaviour. Clay has the ability, under certain conditions, to spontaneously repair its cracks. However, despite ample evidence, clay self-repair remains understudied and under-theorised. For example, the majority of experimental studies discussing clay self-repair infer its existence from changes to macroscopic properties assumed to be caused by self-repair, and only a small number of studies have attempted to observe self-repair directly. This paper reviews the literature on clay self-repair. First, it situates clay self-repair within the broader context of self-repairing material. Next, autogenous self-repair of clay, under wet-dry cycles, freeze–thaw cycles and deep-ground consolidation, is presented focusing on evidence, driving mechanisms and key variables of influence. Next, theories of clay self-repair proposed in the literature are discussed, highlighting their scope and limitations, as well as the extent to which they have been validated by experimental observations. Key gaps in current knowledge of clay self-repair are highlighted and ways in which they can be addressed in future research are proposed. Finally, a nomenclature distinguishing between different kinds of clay self-repair is proposed based on eight different attributes.

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7.
The Messinian Salinity Crisis is well known to have resulted from a significant drop of the Mediterranean sea level. Considering both onshore and offshore observations, the subsequent reflooding is generally thought to have been very sudden. We present here offshore seismic evidence from the Gulf of Lions and re‐visited onshore data from Italy and Turkey that lead to a new concept of a two‐step reflooding of the Mediterranean Basin after the Messinian Salinity Crisis. The refilling was first moderate and relatively slow accompanied by transgressive ravinement, and later on very rapid, preserving the subaerial Messinian Erosional Surface. The amplitude of these two successive rises of sea level has been estimated at ≤500 m for the first rise and 600–900 m for the second rise. Evaporites from the central Mediterranean basins appear to have been deposited principally at the beginning of the first step of reflooding. After the second step, which preceeded the Zanclean Global Stratotype Section and Point, successive connections with the Paratethyan Dacic Basin, then the Adriatic foredeep, and finally the Euxinian Basin occurred, as a consequence of the continued global rise in sea level. A complex morphology with sills and sub‐basins led to diachronous events such as the so‐called ‘Lago Mare’.This study helps to distinguish events that were synchronous over the entire Mediterranean realm, such as the two‐step reflooding, from those that were more local and diachronous. In addition, the shoreline that marks the transition between these two steps of reflooding in the Provence Basin provides a remarkable palaeogeographical marker for subsidence studies.  相似文献   
8.
Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations, Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles, but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant. This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized. The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV) species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate. The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides or sediment traps. The method has also been validated with data collected in other marine sedimentary environments. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
9.
Biogeochemical processes induced by the deposition of gravity layer in marine sediment were studied in a 295-day experiment. Combining voltammetric microelectrode measurements and conventional analytical techniques, the concentrations of C, O2, N-species, Mn and Fe have been determined in porewaters and sediments of experimental units. Dynamics of the major diagenetic species following the sudden sediment deposition of few cm-thick layer was explained by alternative diagenetic pathways whose relative importance in marine sediments is still a matter of debate. Time-series results indicated that the diffusion of O2 from overlying waters to sediments was efficient after the deposition event: anoxic conditions prevailed during the sedimentation. After a few days, a permanent oxic horizon was formed in the top few millimetres. At the same time, the oxidation of Mn2+ and then Fe2+, which diffused from anoxic sediments, contributed to the surficial enrichment of fresh Mn(III/IV)- and Fe(III)-oxides. Vertical diffusive fluxes and mass balance calculations indicated that a steady-state model described the dynamic of Mn despite the transitory nature of the system. This model was not adequate to describe Fe dynamics because of the multiple sources and phases of Fe2+. No significant transfer of Mn and Fe was observed between the underlying sediment and the new deposit: Mn- and Fe-oxides buried at the original interface acted as an oxidative barrier to reduced species that diffused from below. Nitrification processes led to the formation of a NO3−/NO2− rich horizon at the new oxic horizon. Over the experiment period, NO3− concentrations were also measured in the anoxic sediment suggesting anaerobic nitrate production.  相似文献   
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