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1.
M.P. Collings J.W. Dever H.J. Fraser M.R.S. McCoustra 《Astrophysics and Space Science》2003,285(3-4):633-659
The interaction of carbon monoxide (CO) with vapour-deposited water(H2O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared
spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption
from amorphous H2Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory
experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption
of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical
environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO
desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as
the water ice crystallises and then desorbs. The astronomical implications of this model are discussed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
2.
3.
Jennifer M. Galloway Christine T. Doherty R. Timothy Patterson Helen M. Roe 《第四纪科学杂志》2009,24(4):322-335
A pollen‐based study from Tiny Lake in the Seymour‐Belize Inlet Complex of central coastal British Columbia, Canada, permits an evaluation of the dynamic response of coastal temperate rainforests to postglacial climate change. Open Pinus parklands grew at the site during the early Lateglacial when the climate was cool and dry, but more humid conditions in the later phases of the Lateglacial permitted mesophytic conifers to colonise the region. Early Holocene conditions were warmer than present and a successional mosaic of Tsuga heterophylla and Alnus occurred at Tiny Lake. Climate cooling and moistening at 8740 ± 70 14C a BP initiated the development of closed, late successional T. heterophylla–Cupressaceae forests, which achieved modern character after 6860 ± 50 14C a BP, when a temperate and very wet climate became established. The onset of early Holocene climate cooling and moistening at Tiny Lake may have preceded change at more southern locations, including within the Seymour‐Belize Inlet Complex, on a meso‐ to synoptic scale. This would suggest that an early Holocene intensification of the Aleutian Low pressure system was an important influence on forest dynamics in the Seymour‐Belize Inlet Complex and that the study region was located near the southern extent of immediate influence of this semi‐permanent air mass. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
4.
Charles H. Nelson Douglas S. Hall Francis C. Fekel Robert E. Fried Richard E. Lines Helen C. Lines 《Astrophysics and Space Science》1991,182(1):1-17
Photometry of HD 155638=V792 Her has been analyzed to determine the elements of this totally eclipsing RS CVn binary. The light variation outside eclipse was found to have a period of 27d.07±0d.07, which is slightly different from the 27d.5384±0d.0045 orbital period. Analysis of the eclipses was achieved by a modification of the Russell-Merrill technique. With the aid of radial velocity measures, absolute elements were obtained for the hot and cool stars, respectively;R
h=2.58R
,R
c=12.28R
,M
h=1.40M
,M
c=1.46M
,i=80o.61 and velocity semi-amplitudesK
c=48.36 km s–1±0.79 km s–1, andK
h=50.50 km s–1±0.33 km s–1. The apparent magnitudes areV
h=9
m
.73 andV
c=8
m
.48. The distance to HD 155638 was estimated to be 310 parsecs. 相似文献
5.
Jos M. Marques Paula M. Carreira Maria Rosrio Carvalho Maria J. Matias Fraser E. Goff Maria J. Basto Rui C. Graa Luís Aires-Barros Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289
This paper reviews the geochemical, isotopic (2H, 18O, 13C, 3H and 14C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO3 type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ2H and δ18O suggest a common meteoric origin and that the Mg–HCO3 type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO3 to Mg–HCO3 waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO2 (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of 14C and 13C values, which is in agreement with the 3H concentrations being below the detection limit. 相似文献
6.
7.
Mark A. Engle Fraser Goff David G. Jewett Gregory J. Reller Joel B. Bauman 《Hydrogeology Journal》2008,16(3):559-573
Boron, chloride, sulfate, δD, δ18O, and 3H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were
used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur
and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-3H tracers (i.e., boron, chloride, sulfate, δD, and δ18O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input
and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters
and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990.
A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric
water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month
period for δD and δ18O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it
leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM
hydrogeologic regime.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Résumé Les concentrations en bore, chlorure, sulfate, δD, δ18O, et 3H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ18O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ18O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.
Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ18O, y 3H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son 3H (por ejemplo, boro, cloruros, sulfatos δD, y δ18O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ18O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.相似文献
8.
Ruminations of a Dyspeptic Ex-Editor* 总被引:1,自引:0,他引:1
John Fraser Hart 《The Professional geographer》1976,28(3):225-232
9.
10.
K. W. Helen Lau Keith E. Louden Sharon Deemer Jeremy Hall John R. Hopper Brian E. Tucholke W. Steven Holbrook Hans Christian Larsen † 《Geophysical Journal International》2006,167(1):157-170
New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins. 相似文献