Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece     

Rachelle B. Turnier  Yaron Katzir  Kouki Kitajima  Ian J. Orland  Michael J. Spicuzza  John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.  相似文献   

Microscale Simultaneous Measurement of Carbon and Nitrogen Isotopes on Natural Diamond     

Akizumi Ishida  Kouki Kitajima  Ko Hashizume  Michael J. Spicuzza  Alexander Zaitsev  Daniel J. Schulze  John W. Valley 《Geostandards and Geoanalytical Research》2023,47(3):569-578

Simultaneous analysis of carbon and nitrogen isotope ratios by SIMS was applied for the first-time to a natural diamond from the Kelsey Lake kimberlite, State Line Distinct, Colorado (UWD-1). This in situ procedure is faster, reduces sample size for analysis, and measures both isotope ratios from a single ~ 10 μm diameter pit, a critical advantage for zoned diamonds. The carbon isotope ratio (expressed as δ¹³C_VPDB) of the bulk UWD-1 crystal, determined by the conventional combustion method in the present study, is -5.9‰ ± 0.2‰ (VPDB, 2s). Nitrogen mass fraction ([N]) and isotope ratio (expressed as δ¹⁵N_Air) were determined by stepwise combustion and gas-source mass-spectrometry, resulting in 553 ± 64 μg g^-1 and -6.7‰ ± 1.1‰ (Air, 2s), respectively. Secondary ions of ¹²C₂^-, ¹²C¹³C^-, ¹²C¹⁴N^-, and ¹²C¹⁵N^- were simultaneously measured by SIMS using three Faraday cups and one electron multiplier. The spot-to-spot reproducibility of δ¹³C and δ¹⁵N values for the UWD-1 (178 spots on sixteen chips, 10 μm spots), were 0.3‰ and 1.6‰, respectively (2s). While ¹²C¹⁴N^-/¹²C₂^- ratios, which are an indicator for [N], varied up to 12% among these sixteen chips, such variation did not correlate with either δ¹³C or δ¹⁵N values. We propose that UWD-1 is a suitable reference sample for microscale in situ analysis of δ¹³C and δ¹⁵N values in diamond samples.  相似文献   

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China          下载免费PDF全文

S.‐J. Wang  L. Wang  M. Brown  P. M. Piccoli  T. E. Johnson  P. Feng  H. Deng  K. Kitajima  Y. Huang 《Journal of Metamorphic Geology》2017,35(6):601-629

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   

Explosive volcanic eruptions triggered by cosmic rays: Volcano as a bubble chamber     

Toshikazu Ebisuzaki  Hiroko Miyahara  Ryuho Kataoka  Tatsuhiko Sato  Yasuhiro Ishimine 《Gondwana Research》2011,19(4):1054-1061

Volcanoes with silica-rich and highly viscous magma tend to produce violent explosive eruptions that result in disasters in local communities and that strongly affect the global environment. We examined the timing of 11 eruptive events that produced silica-rich magma from four volcanoes in Japan (Mt. Fuji, Mt. Usu, Myojin-sho, and Satsuma-Iwo-jima) over the past 306 years (from AD 1700 to AD 2005). Nine of the 11 events occurred during inactive phases of solar magnetic activity (solar minimum), which is well indexed by the group sunspot number. This strong association between eruption timing and the solar minimum is statistically significant to a confidence level of 96.7%. This relationship is not observed for eruptions from volcanoes with relatively silica-poor magma, such as Izu-Ohshima. It is well known that the cosmic-ray flux is negatively correlated with solar magnetic activity, as the strong magnetic field in the solar wind repels charged particles such as galactic cosmic rays that originate from outside of the solar system. The strong negative correlation observed between the timing of silica-rich eruptions and solar activity can be explained by variations in cosmic-ray flux arising from solar modulation. Because silica-rich magma has relatively high surface tension (~ 0.1 Nm^?1), the homogeneous nucleation rate is so low that such magma exists in a highly supersaturated state without considerable exsolution, even when located relatively close to the surface, within the penetration range of cosmic-ray muons (1–10 GeV). These muons can contribute to nucleation in supersaturated magma, as documented by many authors studying a bubble chamber, via ionization loss. This radiation-induced nucleation can lead to the pre-eruptive exsolution of H₂O in the silica-rich magma. We note the possibility that the 1991 Mt. Pinatubo eruption was triggered by the same mechanism: an increase in cosmic-ray flux triggered by Typhoon Yunya, as a decrease in atmospheric pressure results in an increase in cosmic-ray flux. We also speculate that the snowball Earth event was triggered by successive large-scale volcanic eruptions triggered by increased cosmic-ray flux due to nearby supernova explosions.  相似文献   

Effect of ocean acidification on coastal phytoplankton composition and accompanying organic nitrogen production     

Takeo Hama  Shoko Kawashima  Koichi Shimotori  Yuhi Satoh  Yuko Omori  Shigeki Wada  Taiki Adachi  Shun Hasegawa  Takashi Midorikawa  Masao Ishii  Shu Saito  Daisuke Sasano  Hiroko Endo  Tsuyoshi Nakayama  Isao Inouye 《Journal of Oceanography》2012,68(1):183-194

The effect of ocean acidification, caused by the increase in pCO₂ in seawater, on phytoplankton population and on related organic nitrogen production was experimentally examined by use of a natural coastal microbial population. pCO₂ and pH were controlled by aeration with air in which pCO₂ was at the current level (control), for which ambient air was used, and with air in which pCO₂ was ??800?? and ??1200?? ppm, in 500-L culture vessels. The experiment was continued for 15?days after addition of the inorganic nutrients such as nitrate, phosphate, and silicate. During most of the experimental period, a minor increase in phytoplankton biomass was noted, probably because of low irradiance, an increase in phytoplankton biomass was observed at the end of the experiment. Flow cytometric and microscopic observations revealed that this increase was because of Chrysochromulina sp. (Haptophyceae). The growth of Chrysochromulina sp. was most obvious in the control vessel, and tended to be obscured by increasing pCO₂ (decrease in pH), indicating the possibility that ocean acidification inhibits the growth of specific phytoplankton groups, for example Chrysochromulina sp. Production of particulate organic nitrogen (PON), determined by the ¹⁵N tracer method, also diminished under acidified conditions compared with that at the current level.  相似文献   

Dynamical response to supernova-induced gas removal in spiral galaxies with dark matter halo     

Hiroko Koyama  Masahiro Nagashima  Takayuki Kakehata  Yuzuru Yoshii 《Monthly notices of the Royal Astronomical Society》2008,389(1):237-249

We investigate the dynamical response, in terms of disc size and rotation velocity, to mass loss by supernovae in the evolution of spiral galaxies. A thin baryonic disc having the Kuzmin density profile embedded in a spherical dark matter halo having a density profile proposed by Navarro, Frenk & White is considered. For the purpose of comparison, we also consider the homogeneous and   r ⁻¹  profiles for dark matter in a truncated spherical halo. Assuming for simplicity that the dark matter distribution is not affected by mass-loss from discs and the change of baryonic disc matter distribution is homologous, we evaluate the effects of dynamical response in the resulting discs. We found that the dynamical response only for an adiabatic approximation of mass-loss can simultaneously account for the rotation velocity and disc size as observed particularly in dwarf spiral galaxies, thus reproducing the Tully–Fisher relation and the size versus magnitude relation over the full range of magnitude. Furthermore, we found that the mean specific angular momentum in discs after the mass-loss becomes larger than that before the mass-loss, suggesting that the mass-loss would most likely occur from the central disc region where the specific angular momentum is low.  相似文献   

Possible link between multi-decadal climate cycles and periodic reversals of solar magnetic field polarity     

Hiroko Miyahara  Yusuke Yokoyama  Kimiaki Masuda 《Earth and Planetary Science Letters》2008,272(1-2):290-295

The linkage between multi-decadal climate variability and activity of the sun has been long debated based upon observational evidence from a large number of instrumental and proxy records. It is difficult to evaluate the exact role of each of solar parameters on climate change since instrumentally measured solar related parameters such as Total Solar irradiance (TSI), Ultra Violet (UV), solar wind and Galactic Cosmic Rays (GCRs) fluxes are more or less synchronized and only extend back for several decades. Here we report tree-ring carbon-14 based record of 11-year/22-year solar cycles during the Maunder Minimum (17th century) and the early Medieval Maximum Period (9–10th century) to reconstruct the state of the sun and the flux of incoming GCRs. The result strongly indicates that the influence of solar cycles on climate is persistent beyond the period after instrumental observations were initiated. We find that the actual lengths of solar cycles vary depending on the status of long-term solar activity, and that periodicity of the surface air temperatures are also changing synchronously. Temperature variations over the 22-year cycles seem, in general, to be more significant than those associated with the 11-year cycles and in particular around the grand solar minima such as the Maunder Minimum (1645–1715 AD). The polarity dependence of cooling events found in this study suggests that the GCRs can not be excluded from the possible drivers of decadal to multi-decadal climate change.  相似文献   

A search for millimeter wave spectral lines from comet Sugano-Saigusa-Fujikawa (1983e)     

Tetsuo Hasegawa  Masatoshi Ohishi  Masaki Morimoto  Hiroko Suzuki  Norio Kaifu 《Icarus》1984,60(1):211-214

The search for radio spectral lines from Comet Sugano-Saigusa-Fujikawa (1983e) was conducted using the 45-m telescope of Nobeyama Radio Observatory. The frequency ranges of 44.0–46.0 and 47.5–49.5 GHz were surveyed down to $\text{ΔT}{}_{\mathrm{<mtext>A</mtext>}}{}^1\text{(}\text{rms}\text{) = 20–30}\text{mK}$, with a beam size of ～35 arc sec. Upper limits have been established for spectral lines of atomic hydrogen, CS, OCS, SO₂, H₂CO, CH₃OH, HCCCCCN, HCOOCH₃, CH₃OCH₃, and CH₃CH₂CN. The J = 5?4 line from HCCCN in the vibrational ground state possibly has been detected but not confirmed. The suggested total amount of HCCCN in the coma is consistent with the possible picture that HCCCN is the main parent molecule of CN.  相似文献   

Flash heating of calcium‐aluminum‐rich inclusions     

Hiroko Nagahara 《Meteoritics & planetary science》2001,36(8):1011-1012

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Interdiffusion of Mg–Fe in olivine at 1,400–1,600 °C and 1 atm total pressure     

Shogo Tachibana  Shinnosuke Tamada  Haruka Kawasaki  Kazuhito Ozawa  Hiroko Nagahara 《Physics and Chemistry of Minerals》2013,40(6):511-519

The interdiffusion coefficient of Mg–Fe in olivine (D _Mg–Fe) was obtained at 1,400–1,600 °C at the atmospheric pressure with the oxygen fugacity of 10^?3.5–10^?2 Pa using a diffusion couple technique. The D _Mg–Fe shows the anisotropy (largest along the [001] direction and smallest along the [100] direction), and its activation energy (280–320 kJ/mol) is ~80–120 kJ/mol higher than that estimated at lower temperatures. The D _Mg–Fe at temperatures of >1,400 °C can be explained by the cation-vacancy chemistry determined both by the Fe³⁺/Fe²⁺ equilibrium and by the intrinsic point defect formation with the formation enthalpy of 220–270 kJ/mol depending on the thermodynamical model for the Fe³⁺/Fe²⁺ equilibrium in olivine. The formation enthalpy of 220–270 kJ/mol for the point defect (cation vacancy) in olivine is consistent with that estimated from the Mg self-diffusion in Fe-free forsterite. The increase in the activation energy of D _Mg–Fe at >1,400 °C is thus interpreted as the result of the transition of diffusion mechanism from the transition metal extrinsic domain to the intrinsic domain at the atmospheric pressure.  相似文献