Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)   总被引：1，自引：0，他引：1  

María López  Isabel González  Antonio Romero 《Environmental Geology》2008,54(4):805-818

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.  相似文献   

Usefulness of geological,mineralogical, chemical and chemometric analytical techniques in exploitation and profitability studies of iron mines and their associated elements     

M. Dolores Petit-Dominguez  M. Isabel Rucandio  Almudena Galan-Saulnier  Rosario Garcia-Gimenez 《Journal of Geochemical Exploration》2008

Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   

Avian and mammalian bone taphonomy in southern continental Patagonia: A comparative approach   总被引：1，自引：0，他引：1  

Isabel Cruz   《Quaternary International》2008,180(1):30

In southern Patagonia, the occurrence of large seabird nesting colonies condition the features of the regional bone record, which is characterized by a large amount of bird remains, despite their small body size. Bird and mammal bones have remarkably different taphonomic histories in this region: mammal remains are less damaged by carnivores and resist weathering for long periods, whereas bird bones show a greater initial destruction by carnivore activities and faster deterioration by weathering. A comparison of these results with results from research conducted in several African parks (particularly Amboseli) shows that differences in both records are mainly due to differences in community composition and predator–prey dynamics in both ecosystems. Furthermore, while in both ecosystems bird bones weather more rapidly than mammal bones, destruction by this process is more rapid in Patagonia. Overall, the analysis reinforces the need to generate specific models to understand taphonomic histories of archaeofaunal assemblages from Patagonia.  相似文献   

Projecting land-use change processes in the Sierra Norte of Oaxaca, Mexico     

Leticia Gmez-Mendoza  Ernesto Vega-Pea  M. Isabel Ramírez  Jos Luis Palacio-Prieto  Leopoldo Galicia 《Applied geography (Sevenoaks, England)》2006,26(3-4):276-290

The objective of study was to explore short-term trends of processes that determine land-use change in Sierra Norte of Oaxaca (SNO), Mexico. Land use and land cover changes (LULCC) were estimated in a complex mosaic of vegetation in the SNO from 1980 to 2000, and projected them to 2020 through a Markovian model. SNO is highly vulnerable to climatic change according to a 2050 GCM scenario. However, 3% annual rate of tropical and temperate forest deforestation from agriculture and livestock encroachment, suggest the threat from land-use change is higher than that from climatic change for this study site. Productive land-use strategies are needed to reduce such high deforestation rates for tropical regions. Controlling deforestation would also reduce short-term effects of CO₂ emissions to the atmosphere. Because of the necessity to evaluate anthropogenic ecosystem changes, it is imperative to separate short-term influences such as deforestation, from long-term influences such as climatic change.  相似文献   

Morphology and distribution of fossil soils in the Permo-Pennsylvanian Wichita and Bowie Groups, north-central Texas, USA: implications for western equatorial Pangean palaeoclimate during icehouse–greenhouse transition     

Neil John Tabor  Isabel P. Montañez† 《Sedimentology》2004,51(4):851-884

Analysis of stacked Permo‐Pennsylvanian palaeosols from north‐central Texas documents the influence of palaeolandscape position on pedogenesis in aggradational depositional settings. Palaeosols of the Eastern shelf of the Midland basin exhibit stratigraphic trends in the distribution of soil horizons, structure, rooting density, clay mineralogy and colour that record long‐term changes in soil‐forming conditions driven by both local processes and regional climate. Palaeosols similar to modern histosols, ultisols, vertisols, inceptisols and entisols, all bearing morphological, mineralogical and chemical characteristics consistent with a tropical, humid climate, represent the Late Pennsylvanian suite of palaeosol orders. Palaeosols similar to modern alfisols, vertisols, inceptisols, aridisols and entisols preserve characteristics indicative of a drier and seasonal tropical climate throughout the Lower Permian strata. The changes in palaeosol morphology are interpreted as being a result of an overall climatic trend from relatively humid and tropical, moist conditions characterized by high rainfall in the Late Pennsylvanian to progressively drier, semi‐arid to arid tropical climate characterized by seasonal rainfall in Early Permian time. Based on known Late Palaeozoic palaeogeography and current hypotheses for atmospheric circulation over western equatorial Pangea, the Pennsylvanian palaeosols in this study may be recording a climate that is the result of an orographic control over regional‐scale atmospheric circulation. The trend towards a drier climate interpreted from the Permian palaeosols may be recording the breakdown of this pre‐existing orographic effect and the onset of a monsoonal atmospheric circulation system over this region.  相似文献   

Trace element compositions of submicroscopic inclusions in coated diamond: A tool for understanding diamond petrogenesis     

Emma Tomlinson  Isabel De Schrijver  Adrian P. Jones  Frank Vanhaecke 《Geochimica et cosmochimica acta》2005,69(19):4719-4732

Trace element compositions of submicroscopic inclusions in both the core and the coat of five coated diamonds from the Democratic Republic of Congo (DRC, formerly Zaire) have been analyzed by Laser Ablation Inductively Coupled Mass Plasma Spectrometry (LA-ICP-MS). Both the diamond core and coat inclusions show a general 2-4-fold enrichment in incompatible elements relative to major elements. This level of enrichment is unlikely to be explained by the entrapment of silicate mantle minerals (olivine, garnet, clinopyroxene, phlogopite) alone and thus submicroscopic fluid or glass inclusions are inferred in both the diamond coat and in the gem quality diamond core. The diamond core fluids have elevated High Field Strength Element (Ti, Ta, Zr, Nb) concentrations and are enriched in U relative to inclusions in the diamond coats and relative to chondrite. The core fluids are also moderately enriched in LILE (Ba, Sr, K). Therefore, we suggest that the diamond cores contain inclusions of silicate melt. However, the Ni content and Ni/Fe ratio of the trapped fluid are very high for a silicate melt in equilibrium with mantle minerals; high Ni and Co concentrations in the diamond cores are attributed to the presence of a sulfide phase coexisting with silicate melt in the diamond core inclusions. Inclusions in the diamond coat are enriched in LILE (U, Ba, Sr, K) and La over the diamond core fluids and to chondrite. The coats have incompatible element ratios similar to natural carbonatite (coat fluid: Na/Ba ≈0.66, La/Ta≈130). The coat fluid is also moderately enriched in HFSE (Ta, Nb, Zr) when normalized to chondritic Al. LILE and La enrichment is related to the presence of a carbonatitic fluid in the diamond coat inclusions, which is mixed with a HFSE-rich hydrous silicate fluid similar to that in the core. The composition of the coat fluid is consistent with a genetic link to group 1 kimberlite.  相似文献   

A Road to Conflict: Stakeholder’s and Social Network Analysis of the Media Portrayals of a Social-Environmental Conflict in Bolivia     

Victoria Reyes-García  Oriol Andrés-Conejero  Álvaro Fernández-Llamazares  Isabel Díaz-Reviriego  José-Luis Molina 《社会与自然资源》2019,32(4):452-472

Society’s understanding of a conflict is mediated by information provided in mass media, for which researchers stress the importance of analyzing media portrays of stakeholders in a conflict. We analyze information from the Bolivian press regarding the construction of a road crossing the Isiboro-Sécure Indigenous Territory and National Park (TIPNIS). Using stakeholder’s and social network analyses, we explore stakeholder’s positions and alliances as represented in the media and contrast it with previous scholarly work. We found that some actors cited as central in scholar analyses of the conflict are largely absent in the media (e.g., private investors, conservationist sector) and that the media tend to present stakeholders as having more homogeneous positions than the academic literature does while also neglecting some important alliances in their account. The media also suggests that Indigenous communities are forging stronger alliances with urban sectors and civil society, alliances not stressed by researchers.  相似文献   

Palaeoceanographic changes in the North Atlantic during the Mid‐Pleistocene Transition (MIS 31–19) as inferred from planktonic foraminiferal and calcium carbonate records     

Iván Hernández‐Almeida  Francisco Javier Sierro  José‐Abel Flores  Isabel Cacho  Gabriel Michael Filippelli 《Boreas: An International Journal of Quaternary Research》2013,42(1):140-159

Marine sediments from the Integrated Ocean Drilling Project (IODP) Site U1314 (56.36°N, 27.88°W), in the subpolar North Atlantic, were studied for their planktonic foraminifera, calcium carbonate content, and Neogloboqudrina pachyderma sinistral (sin.) δ¹³C records in order to reconstruct surface and intermediate conditions in this region during the Mid‐Pleistocene Transition (MPT). Variations in the palaeoceanography and regional dynamics of the Arctic Front were estimated by comparing CaCO₃ content, planktonic foraminiferal species abundances, carbon isotopes and ice‐rafted debris (IRD) data from Site U1314 with published data from other North Atlantic sites. Site U1314 exhibited high abundances of the polar planktonic foraminifera N. pachyderma sin. and low CaCO₃ content until Marine Isotope Stage (MIS) 26, indicating a relatively southeastward position of the Arctic Front (AF) and penetration of colder and low‐salinity surface arctic water‐masses. Changing conditions after MIS 25, with oscillations in the position of the AF, caused an increase in the northward export of the warmer North Atlantic Current (NAC), indicated by greater abundances of non‐polar planktonic foraminifera and higher CaCO₃. The N. pachyderma sin. δ¹³C data indicate good ventilation of the upper part of the intermediate water layer in the eastern North Atlantic during both glacial and interglacial stages, except during Terminations 24/23, 22/21 and 20/1. In addition, for N. pachyderma (sin.) we distinguished two morphotypes: non‐encrusted and heavily encrusted test. Results indicate that increases in the encrusted morphotype and lower planktonic foraminiferal diversity are related to the intensification of glacial conditions (lower sea‐surface temperatures, sea‐ice formation) during MIS 22 and 20.  相似文献   

Growth and feeding patterns of European anchovy (Engraulis encrasicolus) early life stages in the Aegean Sea (NE Mediterranean)     

Ignacio A. Catalán  Arild Folkvord  Isabel Palomera  Gemma Quílez-Badía  Fotini Kallianoti  Anastasios Tselepides  Argyris Kallianotis 《Estuarine, Coastal and Shelf Science》2010

  相似文献   

Nutrient dynamics in Mediterranean temporary streams: A case study in Pardiela catchment (Degebe River, Portugal)   总被引：1，自引：0，他引：1  

Ana Isabel Lilleb  Manuela Morais  Pedro Guilherme  Rita Fonseca  Antnio Serafim  Ramiro Neves 《Limnologica》2007,37(4):337-348

Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L⁻¹, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L⁻¹, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH₄-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO₄-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.  相似文献