首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   606篇
  免费   55篇
  国内免费   13篇
测绘学   21篇
大气科学   100篇
地球物理   151篇
地质学   195篇
海洋学   47篇
天文学   94篇
综合类   1篇
自然地理   65篇
  2022年   5篇
  2021年   22篇
  2020年   19篇
  2019年   16篇
  2018年   20篇
  2017年   25篇
  2016年   54篇
  2015年   31篇
  2014年   30篇
  2013年   46篇
  2012年   52篇
  2011年   38篇
  2010年   42篇
  2009年   51篇
  2008年   33篇
  2007年   30篇
  2006年   34篇
  2005年   26篇
  2004年   19篇
  2003年   14篇
  2002年   6篇
  2001年   13篇
  2000年   12篇
  1999年   7篇
  1998年   7篇
  1997年   6篇
  1996年   3篇
  1994年   2篇
  1993年   2篇
  1989年   1篇
  1987年   1篇
  1986年   1篇
  1985年   1篇
  1984年   2篇
  1980年   1篇
  1973年   1篇
  1971年   1篇
排序方式: 共有674条查询结果,搜索用时 31 毫秒
1.
Wildfire significantly alters the hydrologic properties of a burned area, leading to increases in overland flow, erosion, and the potential for runoff-generated debris flows. The initiation of debris flows in recently burned areas is well characterized by rainfall intensity-duration (ID) thresholds. However, there is currently a paucity of data quantifying the rainfall intensities required to trigger post-wildfire debris flows, which limits our understanding of how and why rainfall ID thresholds vary in different climatic and geologic settings. In this study, we monitored debris-flow activity following the Pinal Fire in central Arizona, which differs from both a climatic and hydrogeomorphic perspective from other regions in the western United States where ID thresholds for post-wildfire debris flows are well established, namely the Transverse Ranges of southern California. Since the peak rainfall intensity within a rainstorm may exceed the rainfall intensity required to trigger a debris flow, the development of robust rainfall ID thresholds requires knowledge of the timing of debris flows within rainstorms. Existing post-wildfire debris-flow studies in Arizona only constrain the peak rainfall intensity within debris-flow-producing storms, which may far exceed the intensity that actually triggered the observed debris flow. In this study, we used pressure transducers within five burned drainage basins to constrain the timing of debris flows within rainstorms. Rainfall ID thresholds derived here from triggering rainfall intensities are, on average, 22 mm h−1 lower than ID thresholds derived under the assumption that the triggering intensity is equal to the maximum rainfall intensity recorded during a rainstorm. We then use a hydrologic model to demonstrate that the magnitude of the 15-min rainfall ID threshold at the Pinal Fire site is associated with the rainfall intensity required to exceed a recently proposed dimensionless discharge threshold for debris-flow initiation. Model results further suggest that previously observed differences in regional ID thresholds between Arizona and the San Gabriel Mountains of southern California may be attributed, in large part, to differences in the hydraulic properties of burned soils. © 2019 John Wiley & Sons, Ltd.  相似文献   
2.
The time it takes water to travel through a catchment, from when it enters as rain and snow to when it leaves as streamflow, may influence stream water quality and catchment sensitivity to environmental change. Most studies that estimate travel times do so for only a few, often rain-dominated, catchments in a region and use relatively short data records (<10 years). A better understanding of how catchment travel times vary across a landscape may help diagnose inter-catchment differences in water quality and response to environmental change. We used comprehensive and long-term observations from the Turkey Lakes Watershed Study in central Ontario to estimate water travel times for 12 snowmelt-dominated headwater catchments, three of which were impacted by forest harvesting. Chloride, a commonly used water tracer, was measured in streams, rain, snowfall and as dry atmospheric deposition over a 31 year period. These data were used with a lumped convolution integral approach to estimate mean water travel times. We explored relationships between travel times and catchment characteristics such as catchment area, slope angle, flowpath length, runoff ratio and wetland coverage, as well as the impact of harvesting. Travel time estimates were then used to compare differences in stream water quality between catchments. Our results show that mean travel times can be variable for small geographic areas and are related to catchment characteristics, in particular flowpath length and wetland cover. In addition, forest harvesting appeared to decrease mean travel times. Estimated mean travel times had complex relationships with water quality patterns. Results suggest that biogeochemical processes, particularly those present in wetlands, may have a greater influence on water quality than catchment travel times.  相似文献   
3.
Reservoir sizing is one of the most important aspects of water resources engineering as the storage in a reservoir must be sufficient to supply water during extended droughts. Typically, observed streamflow is used to stochastically generate multiple realizations of streamflow to estimate the required storage based on the Sequent Peak Algorithm (SQP). The main limitation in this approach is that the parameters of the stochastic model are purely derived from the observed record (limited to less than 80 years of data) which does not have information related to prehistoric droughts. Further, reservoir sizing is typically estimated to meet future increase in water demand, and there is no guarantee that future streamflow over the planning period will be representative of past streamflow records. In this context, reconstructed streamflow records, usually estimated based on tree ring chronologies, provide better estimates of prehistoric droughts, and future streamflow records over the planning period could be obtained from general circulation models (GCMs) which provide 30 year near-term climate change projections. In this study, we developed paleo streamflow records and future streamflow records for 30 years are obtained by forcing the projected precipitation and temperature from the GCMs over a lumped watershed model. We propose combining observed, reconstructed and projected streamflows to generate synthetic streamflow records using a Bayesian framework that provides the posterior distribution of reservoir storage estimates. The performance of the Bayesian framework is compared to a traditional stochastic streamflow generation approach. Findings based on the split-sample validation show that the Bayesian approach yielded generated streamflow traces more representative of future streamflow conditions than the traditional stochastic approach thereby, reducing uncertainty on storage estimates corresponding to higher reliabilities. Potential strategies for improving future streamflow projections and its utility in reservoir sizing and capacity expansion projects are also discussed.  相似文献   
4.
Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.  相似文献   
5.
Rivera  Jason D. 《Natural Hazards》2020,104(2):1331-1343
Natural Hazards - Individual household emergency planning is the most fundamental and can be the least expensive way to prepare for natural disasters. However, despite government and nonprofit...  相似文献   
6.
Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ2H and δ18O of soil water isotope ratios.  相似文献   
7.
There is a need for research that advances understanding of flow alterations in contemporary watersheds where natural and anthropogenic interactions can confound mitigation efforts. Event-based flow frequency, timing, magnitude, and rate of change were quantified at five-site nested gauging sites in a representative mixed-land-use watershed of the central USA. Statistically independent storms were paired by site (n = 111 × 5 sites) to test for significant differences in event-based rainfall and flow response variables (n = 17) between gauging sites. Increased frequency of small peak flow events (i.e., 64 more events less than 4.0 m3 s?1) was observed at the rural–urban interface of the watershed. Differences in flow response were apparent during drier periods when small rainfall events resulted in increased flow response at urban sites in the lower reaches. Relationships between rainfall and peak flow were stronger with decreased pasture/crop land use and increased urban land use by approximately 20%. Event-based total rainfall explained 40–68% of the variance in peak flow (p < 0.001). Coefficients of determination (r2) were negatively correlated with pasture/crop land use (r2 = 0.92; p = 0.007; n = 5) and positively correlated with urban land use (r2 = 0.90; p = 0.008; n = 5). Significant differences in flow metrics were observed between rural and urban sites (p < 0.05; n = 111) that were not explained by differences in rainfall variables and drainage area. An urban influence on flow timing was observed using median time lag to peak centroid and time of maximum precipitation to peak flow. Results highlight the need to establish manageable flow targets in rapidly urbanizing mixed-land-use watersheds.  相似文献   
8.
Sequestration of organic carbon (OC) in environmental systems is critical to mitigating climate change. Organo-mineral associations, especially those with iron (Fe) oxides, drive the chemistry of OC sequestration and stability in soils. Short-range-ordered Fe oxides, such as ferrihydrite, demonstrate a high affinity for OC in binary systems. Calcium commonly co-associates with OC and Fe oxides in soils, though the bonding mechanism (e.g., cation bridging) and implications of the co-association for OC sequestration remain unresolved. We explored the effect of calcium (Ca2+) on the sorption of dissolved OC to 2-line ferrihydrite. Sorption experiments were conducted between leaf litter-extractable OC and ferrihydrite at pH 4 to 9 with different initial C/Fe molar ratios and Ca2+ concentrations. The extent of OC sorption to ferrihydrite in the presence of Ca2+ increased across all tested pH values, especially at pH ≥ 7. Sorbed OC concentration at pH 9 increased from 8.72 ± 0.16 to 13.3 ± 0.20 mmol OC g?1 ferrihydrite between treatments of no added Ca2+ and 30 mM Ca2+ addition. Batch experiments were paired with spectroscopic studies to probe the speciation of sorbed OC and elucidate the sorption mechanism. ATR-FTIR spectroscopy analysis revealed that carboxylic functional moieties were the primary sorbed OC species that were preferentially bound to ferrihydrite and suggested an increase in Fe-carboxylate ligand exchange in the presence of Ca at pH 9. Results from batch to spectroscopic experiments provide significant evidence for the enhancement of dissolved OC sequestration to 2-line ferrihydrite and suggest the formation of Fe–Ca-OC ternary complexes. Findings of this research will inform modeling of environmental C cycling and have the potential to influence strategies for managing land to minimize OM stabilization.  相似文献   
9.
Minerals constitute a primary ecosystem control on organic C decomposition in soils, and therefore on greenhouse gas fluxes to the atmosphere. Secondary minerals, in particular, Fe and Al (oxyhydr)oxides—collectively referred to as “oxides” hereafter—are prominent protectors of organic C against microbial decomposition through sorption and complexation reactions. However, the impacts of Mn oxides on organic C retention and lability in soils are poorly understood. Here we show that hydrous Mn oxide (HMO), a poorly crystalline δ-MnO2, has a greater maximum sorption capacity for dissolved organic matter (DOM) derived from a deciduous forest composite Oi, Oe, and Oa horizon leachate (“O horizon leachate” hereafter) than does goethite under acidic (pH 5) conditions. Nonetheless, goethite has a stronger sorption capacity for DOM at low initial C:(Mn or Fe) molar ratios compared to HMO, probably due to ligand exchange with carboxylate groups as revealed by attenuated total reflectance-Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy and scanning transmission X-ray microscopy–near-edge X-ray absorption fine structure spectroscopy coupled with Mn mass balance calculations reveal that DOM sorption onto HMO induces partial Mn reductive dissolution and Mn reduction of the residual HMO. X-ray photoelectron spectroscopy further shows increasing Mn(II) concentrations are correlated with increasing oxidized C (C=O) content (r = 0.78, P < 0.0006) on the DOM–HMO complexes. We posit that DOM is the more probable reductant of HMO, as Mn(II)-induced HMO dissolution does not alter the Mn speciation of the residual HMO at pH 5. At a lower C loading (2 × 102 μg C m?2), DOM desorption—assessed by 0.1 M NaH2PO4 extraction—is lower for HMO than for goethite, whereas the extent of desorption is the same at a higher C loading (4 × 102 μg C m?2). No significant differences are observed in the impacts of HMO and goethite on the biodegradability of the DOM remaining in solution after DOM sorption reaches steady state. Overall, HMO shows a relatively strong capacity to sorb DOM and resist phosphate-induced desorption, but DOM–HMO complexes may be more vulnerable to reductive dissolution than DOM–goethite complexes.  相似文献   
10.
X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号