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In the context of geological carbon sequestration (GCS), carbon dioxide (CO2) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH4). In this multicomponent multiphase displacement process, CO2 competes with CH4 in terms of dissolution, and CH4 tends to exsolve from the aqueous into a gaseous phase. Because CH4 has a lower viscosity than injected CO2, CH4 is swept up into a ‘bank’ of CH4‐rich gas ahead of the CO2 displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO2 front. On the other hand, the emergence of gaseous CH4 is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO2 if the cap rock is compromised. Open fractures or faults and wells could result in CH4 contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH4‐CO2 mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH4‐rich (up to 90 mol%) gas as a consequence of CO2 injection, with important implications for the risk assessment of future GCS projects.  相似文献   
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Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.  相似文献   
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Intergranular coesite is extremely rare in, and bears crucial information on the formation and preservation of, ultrahigh‐pressure (UHP) rocks. Here, we report the first occurrence of intergranular coesite in a metasedimentary rock, which occurs in the Ganjialing area in the Dabie Shan, east‐central China, and contains abundant coesite inclusions in both garnet and dolomite. We investigated the content of structural water in these minerals with Fourier transform infrared spectroscopy. Our new results undermine the ubiquity of the “pressure‐vessel” model and highlight the role of reaction kinetics in preserving coesite due to the availability of water in UHP rocks.  相似文献   
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The paper refers to fictitious resonant orbits of planet type that surround both components of a binary system. In case of 16 studied examples a suitable choice of the starting values leads to a process of libration of special angular arguments and to an evolution with an at least temporary stay of the planet in the resonant orbit. The ratio of the periods of revolution of the binary and a planet is equal to 1:5. Eight orbits depend on the ratio 1:5 of the masses of the binary components, but two other ratios appear as well. The basis of this study is the planar, elliptic or circular restricted problem of three bodies, but remarks at the end of the text refer to a four-body problem.  相似文献   
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Large‐scale simulations of flow in deformable porous media require efficient iterative methods for solving the involved systems of linear algebraic equations. Construction of efficient iterative methods is particularly challenging in problems with large jumps in material properties, which is often the case in geological applications, such as basin evolution at regional scales. The success of iterative methods for this type of problems depends strongly on finding effective preconditioners. This paper investigates how the block‐structured matrix system arising from single‐phase flow in elastic porous media should be preconditioned, in particular for highly discontinuous permeability and significant jumps in elastic properties. The most promising preconditioner combines algebraic multigrid with a Schur complement‐based exact block decomposition. The paper compares numerous block preconditioners with the aim of providing guidelines on how to formulate efficient preconditioners. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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Boundary-Layer Meteorology - We explore the potential of a new method for the estimation of profiles of turbulence statistics in the stable boundary layer (SBL). By applying gradient-based scaling...  相似文献   
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The use of fish in environmental monitoring has become increasingly important in recent years as anthropogenic substances, many of which function as prooxidants, are accumulating in aquatic environments. We have measured a battery of antioxidant defenses as a measure of oxidative status, as well as protein carbonylation as a measure of oxidative damage, in corkwing wrasse (Symphodus melops) captured near a disused copper mine, where water and sediment are contaminated with heavy metals, and an aluminum smelter, a site contaminated with PAHs. Results were compared to two different reference sites. Fish at the heavy metal site had lower glucose-6-phosphate dehydrogenase activity and elevated protein carbonyls (1.8 times) compared to fish from the reference site. At the PAH site, EROD was increased 2-fold, while total glutathione and methemoglobin reductase concentration, were decreased. No differences were seen in protein carbonyl levels at the PAH site. Measures of both antioxidant defenses and oxidative damage should be used when assessing effects of xenobiotics on oxidative stress in fish species.  相似文献   
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