Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

High-sensitive measurement of uranium L_III-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials     

Yuhei Yamamoto  Yoshio Takahashi  Yutaka Kanai  Yoshio Watanabe  Tomoya Uruga  Hajime Tanida  Yasuko Terada  Hiroshi Shimizu   《Applied Geochemistry》2008,23(8):2452-2461

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   

In situ strength measurements on natural upper-mantle minerals   总被引：1，自引：0，他引：1  

Junji Yamamoto  Jun-ichi Ando  Hiroyuki Kagi  Toru Inoue  Akihiro Yamada  Daisuke Yamazaki  Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.  相似文献   

Sedimentation of terrigenous red soils in coastal area adjacent to an estuary and coral reefs,the Okkubi River estuary,Okinawa Island,Japan     

Satoshi Yamamoto  Takumi Chiba 《Journal of Oceanography》1994,50(4):423-435

Sedimentation process of fine-grained terrigenous red soils was observed on the seafloor by coral reefs near an estuary using a paired mooring of turbidity meter and sediment trap or a mooring of sediment trap and current meter. Silty clays contained in the bottom calcareous sands were mainly resuspended and trapped in both surface and bottom layer traps, at noncatastrophic normal sedimentation periods. In addition, silty clays were supplied to this mooring site by inflowing river. Turbidity and the flux rate determined by sediment traps show certain relationship accompanied with the coefficient, which is changed by precipitation, current, and other conditions. Resuspension process caused by a typhoon was recorded as both core sequence of sediment trap and time-series data of bottom current. Maximum velocity of 49.5 cm/s was recorded from bottom currents resulting from the passing of attyphoon at the mooring site. A graded sand layer is interbedded in dark-gray, silty clay and considered to be a resuspended sediment resulting from the passing of the typhoon. Flux of the resuspended sediments by the typhoon was estimated from this core sequence and compared to the flux observed at the normal sedimentation.  相似文献   

Concentration and behavior of detrital mineral grains suspended in the water column of the open sea in the western Pacific     

Satoshi Yamamoto 《Journal of Oceanography》1984,40(1):80-89

The pattern of distribution of detrital mineral grains in the water column was investigated at three stations in the western Pacific during July through August of 1979. The sedimentation of detrital mineral grains was also studied using piston cores from two sites adjacent to the three stations. The concentration of suspended detrital mineral grains in the subsurface waters becomes lower with increasing distance from the land, and shows a prominent peak in the intermediate zone of the water column. The sharp increase in water density and viscosity in the pycnocline in the intermediate zone decreases the settling velocity of grains, and may result in the accumulation of falling grains in the intermediate layer. Proportion of detrital mineral grains to organic remains in the sediment was more than two orders of magnitude larger than in the overlying water column, and reasons for this are briefly discussed.  相似文献   

Satellite detection of red tide in Ariake Sound, 1998–2001     

Joji Ishizaka  Yasuhisa Kitaura  Yasuharu Touke  Hiroaki Sasaki  Akihiko Tanaka  Hiroshi Murakami  Toshikazu Suzuki  Kazumi Matsuoka  Hideaki Nakata 《Journal of Oceanography》2006,62(1):37-45

High resolution SeaWiFS data was used to detect red tide events that occurred in the Ariake Sound, Japan, a small embayment known as one of the most productive areas in Japan. SeaWiFS chlorophyll data clearly showed that a large red tide event, which damaged seaweed (Nori) cultures, started early in December 2000 in Isahaya Bay, expanded to the whole sound and persisted to the end of February 2001. The monthly average of SeaWiFS data from May 1998 to December 2001 indicated that the chlorophyll peaks appeared twice a year, in early summer and in fall, after the peaks of rain and river discharge. The SeaWiFS data showed that the red tide event during 2000–2001 winter was part of the fall bloom; however, it started later and continued significantly longer than other years. Satellite ocean color data is useful to detect the red tide; however the algorithms require improvement to accurately estimate chlorophyll in highly turbid water and in red tide areas.  相似文献   

Roles of Continental Shelves and Marginal Seas in the Biogeochemical Cycles of the North Pacific Ocean   总被引：4，自引：0，他引：4  

Chen-Tung Arthur Chen  Andrey Andreev  Kyung-Ryul Kim  Michiyo Yamamoto 《Journal of Oceanography》2004,60(1):17-44

Most marginal seas in the North Pacific are fed by nutrients supported mainly by upwelling and many are undersaturated with respect to atmospheric CO₂ in the surface water mainly as a result of the biological pump and winter cooling. These seas absorb CO₂ at an average rate of 1.1 ± 0.3 mol C m⁻²yr⁻¹ but release N₂/N₂O at an average rate of 0.07 ± 0.03 mol N m⁻²yr⁻¹. Most of primary production, however, is regenerated on the shelves, and only less than 15% is transported to the open oceans as dissolved and particulate organic carbon (POC) with a small amount of POC deposited in the sediments. It is estimated that seawater in the marginal seas in the North Pacific alone may have taken up 1.6 ± 0.3 Gt (10¹⁵ g) of excess carbon, including 0.21 ± 0.05 Gt for the Bering Sea, 0.18 ± 0.08 Gt for the Okhotsk Sea; 0.31 ± 0.05 Gt for the Japan/East Sea; 0.07 ± 0.02 Gt for the East China and Yellow Seas; 0.80 ± 0.15 Gt for the South China Sea; and 0.015 ± 0.005 Gt for the Gulf of California. More importantly, high latitude marginal seas such as the Bering and Okhotsk Seas may act as conveyer belts in exporting 0.1 ± 0.08 Gt C anthropogenic, excess CO₂ into the North Pacific Intermediate Water per year. The upward migration of calcite and aragonite saturation horizons due to the penetration of excess CO₂ may also make the shelf deposits on the Bering and Okhotsk Seas more susceptible to dissolution, which would then neutralize excess CO₂ in the near future. Further, because most nutrients come from upwelling, increased water consumption on land and damming of major rivers may reduce freshwater output and the buoyancy effect on the shelves. As a result, upwelling, nutrient input and biological productivity may all be reduced in the future. As a final note, the Japan/East Sea has started to show responses to global warming. Warmer surface layer has reduced upwelling of nutrient-rich subsurface water, resulting in a decline of spring phytoplankton biomass. Less bottom water formation because of less winter cooling may lead to the disappearance of the bottom water as early as 2040. Or else, an anoxic condition may form as early as 2200 AD. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The chemical composition and nickel,cobalt, copper,zinc and lead contents of Nanao Bay sediments     

Yoshikazu Yamamoto  Yukitaka Tanaka  Shunzo Ueda 《Journal of Oceanography》1977,33(5):242-246

The contents of major and some of the minor elements, nickel, cobalt, copper, zinc and lead were studied on sediments collected from three inlets of Nanao Bay located at eastern side of Noto Peninsula. Little variation was found on the average contents of silicon, iron, titanium, aluminum, manganese, magnesium and potassium among the sediments of West, South and North Bays in Nanao Bay. Whereas significant difference was found on the contents of calcium, chlorine, sulfur and nitrogen among sediments of three bays.As to the minor elements, the average contents of nickel (20±5 ppm), cobalt (5±1 ppm), copper (18±5 ppm) and lead (17±8 ppm) are relatively low but zinc content is high in these sediments comparing with those of coastal deposit around Japan Island. From the results obtained here, it became clear that no environmental contamination of nickel, cobalt, copper and lead, and a little organic pollution were found in Nanao Bay sediments.  相似文献   

Size-Fractionated Primary Production Estimated by a Two-Phytoplankton Community Model Applicable to Ocean Color Remote Sensing   总被引：3，自引：0，他引：3  

Takahiko?KamedaEmail author  Joji?Ishizaka 《Journal of Oceanography》2005,61(4):663-672

In order to estimate primary production from ocean color satellite data using the Vertical Generalized Production Model (VGPM; Behrenfeld and Falkowski, 1997), we propose a two-phytoplankton community model. This model is based on the two assumptions that changes in chlorophyll concentration result from changes of large-sized phytoplankton abundance, and chlorophyll specific productivity of phytoplankton tends to be inversely proportional to phytoplankton size. Based on the analysis of primary production data, P _opt ^B , which was one parameter in the VGPM, was modeled as a function of sea surface temperature and sea surface chlorophyll concentration. The two-phytoplankton community model incorporated into the VGPM gave good estimates in a relatively high productive area. Size-fractionated primary production was estimated by the two-phytoplankton community model, and P _opt ^B of small-sized phytoplankton was 4.5 times that of large-sized phytoplankton. This result fell into the ranges observed during field studies.  相似文献   

Amorphous interstellar grains: Wavelength dependence of far-infrared emission efficiency     

Junji Seki  Tetsuo Yamamoto 《Astrophysics and Space Science》1980,72(1):79-86

It is shown theoretically that the emission efficiency of amorphous grains with radii smaller than 100 Å has a _-1-dependence in the wavelength region longer than 100 , whereas those of crystalline, metallic, and larger amorphous grains are proportional to _-2 in far infrared. Astrophysical implications of the amorphous grains are discussed.  相似文献