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1.
Aleksandra Šajnović Ksenija Stojanović Branimir Jovančićević Olga Cvetković 《Chemie der Erde / Geochemistry》2008,68(4):395-411
In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C25 are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C25 content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C17 content compared to n-C27, and phytane compared to n-C18. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C26 (hypersaline depositional environment), or isoprenoid C25 and n-alkane C22 for high alkalinity environment.This study showed that Sq/n-C26 ratio can be used to assess the quality of organic substance in immature lacustrine sediments. 相似文献
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Sokrat Amataj Todor Anovski Ralf Benischke Romeo Eftimi Laurence L. Gourcy Liliana Kola Ioannis Leontiadis Eftim Micevski Alqiviadis Stamos Jovan Zoto 《Environmental Geology》2007,51(5):749-753
Prespa Lake and Ohrid Lake constitute a hydraulic system shared between Albania, FYR of Macedonia and Greece. Karst rocks
separate both lakes. The elevation of Prespa Lake is about 150 m higher than that of Ohrid Lake. Considering these facts,
Cvijić formulated in 1906 the hypothesis that Prespa Lake recharges the St. Naum and Tushemisht springs at Ohrid lakeside.
Environmental isotopes demonstrated that Prespa Lake recharges about 37–42 and 52–54% of water emerging in St. Naum, and Tushemisht
springs, respectively. An artificial tracer experiment carried out in 2002 physically demonstrated the underground connection
between both lakes. This experiment confirmed the supposed underground connection and brought important information about
the groundwater velocity, transit time, and karst water conduits development. 相似文献
3.
Milan Stojković Jasna Plavšić Stevan Prohaska Dragutin Pavlović Jovan Despotović 《水文科学杂志》2020,65(3):387-400
ABSTRACTClimate change projections of precipitation and temperature suggest that Serbia could be one of the most affected regions in southeastern Europe. To prepare adaptation measures, the impact of climate changes on water resources needs to be assessed. Pilot research is carried out for the Lim River basin, in southeastern Europe, to predict monthly flows under different climate scenarios. For estimation of future water availability, an alternative approach of developing a deterministic-stochastic time series model is chosen. The proposed two-stage time series model consists of several components: trend, long-term periodicity, seasonality and the stochastic component. The latter is based on a transfer function model with two input variables, precipitation and temperature, as climatic drivers. The Nash-Sutcliffe model efficiency for the observed period 1950–2012 is 0.829. The model is applied for the long-term hydrological prediction under the representative concentration pathway (RCP) emissions scenarios for the future time frame 2013–2070. 相似文献
4.
A. Sajnović K. Stojanović G. S. Pevneva A. K. Golovko B. Jovančičević 《Geochemistry International》2010,48(7):678-694
This paper reports an investigation of 60 samples of lacustrine sedimentary rocks of Neogene age lying at depths of 0–400
m in the Valjevo-Mionica Basin, Serbia. The goal of the study was to determine the origin and type of primary organic matter
(OM), the degree of thermal alteration, the generation potential of OM from the rocks of this basin, and conditions in the
sedimentation environment during the formation of the rocks. The potential of OM of the rocks was estimated on the basis of
the thermolysis of a representative sample after its preliminary debituminization. 相似文献
5.
Nenad Grba Aleksandra Šajnović Ksenija Stojanović Vladimir Simić Branimir Jovančićević Goran Roglić Vladisav Erić 《Chemie der Erde / Geochemistry》2014
Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined. 相似文献
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This study presents a review of recently recorded instability phenomena on the flysch slopes of Istria, Croatia. The northeastern part of the Istrian Peninsula, the so-called Gray Istria, is built of Paleogene flysch deposits, where instability phenomena are frequent and where a large number of landslides, with significant consequences, have been recorded over the past 35 years. Based on field investigations conducted for the purpose of remedial study design, a database of these landslides was created. An investigation of the documented landslides and their elements found some common features that enabled general conclusions about the conditions and causes of landslide occurrence. In total, 19 documented landslides have been analyzed as individual phenomena, and from the results of these analyses, general conclusions were drawn about sliding conditions and the main triggering factors. Geological conditions and processes on slopes where landslides occurred are shown in detail, and geotechnical properties have been systematically represented. The sliding conditions and dimensions of four recent landslide occurrences, specifically by type, have been described in detail and analyzed. 相似文献
9.
A. Šajnović K. Stojanović V. Simić G. S. Pevneva A. K. Golovko B. Jovančiećević 《Geochemistry International》2011,49(10):1022-1034
Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica
basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks,
determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect
of Pt4+ and Ru3+ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis
products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis
under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II
and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than
sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment.
The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free
sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high
generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield
of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases.
The Pt4+ and Ru3+ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen
type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a
temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics
in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects
the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during
the thermolysis of immature kerogen, regardless of its type. The effect of the Pt4+ and Ru3+ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to
thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM. 相似文献
10.
Flow energy and channel adjustments in rills developed in loamy sand and sandy loam soils 总被引：1，自引：0，他引：1
The storms usually associated with rill development in nature are seldom prolonged, so development is often interrupted by interstorm disturbances, e.g. weathering or tillage. In laboratory simulated rainfall experiments, active rill development can be prolonged, and under these conditions typically passes through a period of intense incision, channel extension and bifurcation before reaching quasi‐stable conditions in which little form change occurs. This paper presents laboratory experiments with coarse textured soils under simulated rainfall which show how channel adjustment processes contribute to the evolution of quasi‐stability. Newly incised rills were stabilized for detailed study of links between rill configuration and flow energy. On a loamy sand, adjustment towards equilibrium occurred due to channel widening and meandering, whereas on a sandy loam, mobile knickpoints and chutes, pulsations in flow width and flow depth and changes in stream power and sediment discharge occurred as the channel adjusted towards equilibrium. The tendency of rill systems towards quasi‐stability is shown by changes in stream power values which show short‐lived minima. Differences in energy dissipation in stabilized rills indicate that minimization of energy dissipation was reached locally between knickpoints and at the downstream ends of rills. In the absence of energy gradients in knickpoints and chutes, stabilized rill sections tended toward equilibrium by establishing uniform energy expenditure. The study confirmed that energy dissipation increased with flow aspect ratio. In stabilized rills, flow acceleration reduced energy dissipation on the loamy sand but not on the sandy loam. On both soils flow deceleration tended to increase energy dissipation. Understanding how rill systems evolve towards stability is essential in order to predict how interruptions between storms may affect long‐term rill dynamics. This is essential if event‐based physical models are to become effective in predicting sediment transport on rilled hillslopes under changing weather and climatic conditions. Copyright © 2008 John Wiley and Sons, Ltd. 相似文献