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1.
A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites 
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下载免费PDF全文 We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CBb3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high 15N-enrichments (~50‰ ≤ δ15N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between 15N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk 15N/14N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk 15N/14N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust. 相似文献
2.
Sulfur isotope fractionation during growth of sulfate-reducing bacteria on various carbon sources 总被引：1，自引：0，他引：1
Jutta Kleikemper Martin H. Schroth Benjamin Brunner 《Geochimica et cosmochimica acta》2004,68(23):4891-4904
Stable sulfur isotope fractionation during microbial sulfate reduction is a potential tool to estimate sulfate reduction rates at field sites. However, little is known about the influence of the utilized carbon source on the magnitude of sulfur isotope fractionation. To investigate this effect, both a pure culture (strain PRTOL1) and enrichment cultures from a petroleum hydrocarbon (PHC)-contaminated aquifer were used and grown in batch cultures on various carbon sources with an initial sulfate concentration of 1 mmol/L. As sole carbon sources the PHC components naphthalene, 1,3,5-trimethylbenzene, and heating oil (enrichment culture) and the organic acids acetate, pyruvate, benzoate, and 3-phenylpropionate (enrichment culture and PRTOL1) were used. Sulfate reduction rates of all cultures ranged from 6 ± 1 nmol cm−3 d−1 (enrichment culture grown on 1,3,5-trimethylbenzene) to 280 ± 6 nmol cm−3 d−1 (enrichment culture grown on pyruvate). Cell-specific sulfate reduction rates ranged from 1.1 × 10−14 mol cell−1 d−1 (PRTOL1 grown on pyruvate) to 1.5 × 10−13 mol cell−1 d−1 (PRTOL1 grown on acetate). Sulfur isotope enrichment factors (ε) for the enrichment culture ranged from 16.1‰ (3-phenylpropionate) to 34.5‰ (1,3,5-trimethylbenzene) and for PRTOL1 from 30.0‰ (benzoate) to 36.0‰ (pyruvate). Cultures of PRTOL1 always showed higher ε values than the enrichment culture when grown on the same carbon source due to culture-specific properties. Higher ε values were obtained when the enrichment culture was grown on PHC components than on organic acids. No relationship between ε values and cell-specific sulfate reduction rate existed when all data were combined. When comparing the magnitude of ε values determined in this laboratory study with ε values measured at contaminated and uncontaminated field sites, it becomes evident that a multitude of factors influences ε values at field sites and complicates their interpretation. The results of this study help us assess some of the general parameters that govern the magnitude of ε in sulfate-reducing environments. 相似文献
3.
Benjamin Brunner Stefano M. Bernasconi Jutta Kleikemper 《Geochimica et cosmochimica acta》2005,69(20):4773-4785
We present a model of bacterial sulfate reduction that includes equations describing the fractionation relationship between the sulfur and the oxygen isotope composition of residual sulfate (δ34SSO4_residual, δ18OSO4_residual) and the amount of residual sulfate. The model is based exclusively on oxygen isotope exchange between cell-internal sulfur compounds and ambient water as the dominating mechanism controlling oxygen isotope fractionation processes. We show that our model explains δ34SSO4_residual vs. δ18OSO4_residual patterns observed from natural environments and from laboratory experiments, whereas other models, favoring kinetic isotope fractionation processes as dominant process, fail to explain many (but not all) observed δ34SSO4_residual vs. δ18OSO4_residual patterns. Moreover, we show that a “typical” δ34SSO4_residual vs. δ18OSO4_residual slope does not exist. We postulate that measurements of δ34SSO4_residual and δ18OSO4_residual can be used as a tool to determine cell-specific sulfate reduction rates, oxygen isotope exchange rates, and equilibrium oxygen isotope exchange factors. Data from culture experiments are used to determine the range of sulfur isotope fractionation factors in which a simplified set of equations can be used. Numerical examples demonstrate the application of the equations. We postulate that, during denitrification, the oxygen isotope effects in residual nitrate are also the result of oxygen isotope exchange with ambient water. Consequently, the equations for the relationship between δ34SSO4_residual, δ18OSO4_residual, and the amount of residual sulfate could be modified and used to calculate the fractionation-relationship between δ15NNO3_residual, δ18ONO3_residual, and the amount of residual nitrate during denitrification. 相似文献
4.
Luminescence dating of ice‐marginal deposits in northern Germany: evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6) 下载免费PDF全文
下载免费PDF全文 Julia Roskosch Jutta Winsemann Ulrich Polom Christian Brandes Sumiko Tsukamoto Axel Weitkamp Werner A. Bartholomäus Dierk Henningsen Manfred Frechen 《Boreas: An International Journal of Quaternary Research》2015,44(1):103-126
The exact number, extent and chronology of the Middle Pleistocene Elsterian and Saalian glaciations in northern Central Europe are still controversial. This study presents new luminescence data from Middle Pleistocene ice‐marginal deposits in northern Germany, giving evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6). The study area is located in the Leine valley south of the North German Lowlands. The data set includes digital elevation models, high‐resolution shear wave seismic profiles, outcrop and borehole data integrated into a 3D subsurface model to reconstruct the bedrock relief surface. For numerical age determination, we performed luminescence dating on 12 ice‐marginal and two fluvial samples. Luminescence ages of ice‐marginal deposits point to at least two ice advances during MIS 12 and MIS 10 with ages ranging from 461±34 to 421±25 ka and from 376±27 to 337±21 ka. The bedrock relief model and different generations of striations indicate that the older ice advance came from the north and the younger one from the northeast. During rapid ice‐margin retreat, subglacial overdeepenings were filled with glaciolacustrine deposits, partly rich in re‐worked Tertiary lignite and amber. During MIS 8 and MIS 6, the study area may have been affected by two ice advances. Luminescence ages of glaciolacustrine delta deposits point to a deposition during MIS 8 or early MIS 6, and late MIS 6 (250±20 to 161±10 ka). The maximum extent of both the Elsterian (MIS 12 and MIS 10) and Saalian glaciations (MIS 8? and MIS 6) approximately reached the same position in the Leine valley and was probably controlled by the formation of deep proglacial lakes in front of the ice sheets, preventing a further southward advance. 相似文献
5.
Flow dynamics,sedimentation and erosion of glacial lake outburst floods along the Middle Pleistocene Scandinavian Ice Sheet (northern central Europe) 下载免费PDF全文
下载免费PDF全文 Jutta Winsemann Petteri Alho Leena Laamanen Nils Goseberg Jörg Lang Josef Klostermann 《Boreas: An International Journal of Quaternary Research》2016,45(2):260-283
During the Middle Pleistocene late Saalian glaciation of northern central Europe numerous pro‐glacial lakes formed along the southwestern margin of the Scandinavian Ice Sheet. Little is known about the drainage history of these lakes, the pathways of glacial lake outburst floods and their impacts on erosion, sedimentation and landscape evolution. This study investigated the impact of the late Saalian Weser and Münsterland Lake (Germany) outburst floods. In particular, we reconstructed the routing and flow dynamics of the lake outburst flood and analysed the flood related sediments. We employed one‐dimensional hydraulic modelling to calculate glacial lake outburst flood hydrographs. We modelled the flow pathway and local flow conditions along the pathway based on the boundary conditions of two different hydrographs and two different ice‐margin positions. The modelling results were compared with geomorphological and sedimentological field data in order to estimate the magnitude and impact of the flood on erosion and sedimentation. Two major lake drainage events are reconstructed for the study area, during which approximately 90–50 km3 of water was released. Modelling results indicate that the lake outburst floods created a high‐energy flood wave with a height of 35–50 m in confined valley areas that rapidly spread out into the Lower Rhine Embayment eventually flowing into the North Sea basin. The sedimentary record of the outburst floods comprises poorly sorted coarse‐grained gravel bars, long‐wavelength bedforms and sandy bedforms deposited by supercritical and subcritical flows. Some parts of the sandy flood deposits are rich in reworked mammoth bones or mammoth and horse teeth, pointing to reworking of older fluvial sediments, hydraulic concentration and subsequent re‐sedimentation of vertebrate remains. These deposits are preserved in sheltered areas or at high elevations, well above the influence of postglacial fluvial erosion. The flood‐related erosional features include up to 80‐m‐deep scour pools, alluvial channels and streamlined hills. 相似文献
6.
S. Grassmann B. Cramer G. Delisle T. Hantschel J. Messner J. Winsemann 《Marine and Petroleum Geology》2010
During the past two million years low surface temperatures as well as episodically advancing ice sheets from Scandinavia acted on the subsurface pT-regime of northern Germany. Their likely effects on the petroleum system of Schleswig-Holstein were investigated. For the entire Quaternary mean annual ground temperature (MAGT) was reconstructed at a resolution of 1000 years by calibrating oxygen isotope records from ODP-site 659 to the climate of northern Germany of the past 120 kyr. The resulting MAGT trend served as input to an ice sheet model and a permafrost model along a 2D section crossing the petroleum bearing south-western part of Schleswig-Holstein. Here advances and retreats of the Scandinavian ice sheet during Saalian and Elsterian glaciation Stages were reconstructed. Maximum ice thicknesses of up to 1700 m and up to 20 periods of regional permafrost in northern Germany were reconstructed for the past 1.25 million years. Based on a basal heat flow of 50 mW/m2 permafrost thicknesses exceeded 100 m during most of these periods, temporarily extending down to depths of more than 300 m. Favourable surface temperatures and long durations of cold periods provided favourable conditions for onshore gas hydrate stability zones at Mittelplate. Implementing these glacial dynamics into 2D basin modelling (PetroMod, IES, Aachen, Germany) of the Mittelplate oil field reveals five phases of gas hydrate stability at depths down to 750 m. The latest of these events occurred during the Weichselian about 20 kyr ago. The effect of the ice sheets on pore pressure in the subsurface strongly depends on the hydraulic boundary conditions at the ice base (e.g. frozen vs. temperate ice sheet base). Excess pore pressure in the reservoir of more than 10 MPa during ice overriding is possible and probable. The calculated temperature effect of the Pleistocene cooling on the Mittelplate reservoir is in the range of 3–7 °C. Even today temperature in the reservoir is still lowered by about 4 °C in comparison to pre-Pleistocene times. Despite the fact that a significant influence of glacial effects on petroleum generation can be ruled out at Mittelplate, we state that pT-effects in reservoirs related to glacial processes in formerly glaciated areas have been underestimated in the past. 相似文献
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Jutta ZIPFEL Bradley L. JOLLIFF Ralf GELLERT Kenneth E. HERKENHOFF Rudolf RIEDER Robert ANDERSON James F. BELL III Johannes BRÜCKNER Joy A. CRISP Philip R. CHRISTENSEN Benton C. CLARK Paulo A.
De SOUZA Jr. Gerlind DREIBUS Claude
D’USTON Thanasis ECONOMOU Steven P. GOREVAN Brian C. HAHN Göstar KLINGELHÖFER Timothy J. McCOY Harry Y. McSWEEN Jr. Douglas W. MING Richard V. MORRIS Daniel S. RODIONOV Steven W. SQUYRES Heinrich WÄNKE Shawn P. WRIGHT Michael B. WYATT Albert S. YEN 《Meteoritics & planetary science》2011,46(1):1-20
Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars. 相似文献
9.
The principle of common but differentiated responsibilities and respective capabilities (CBDRC) captures the idea that it is the common responsibility of states to protect and restore the environment but that the levels and forms of states’ individual responsibilities may be differentiated according to their own national circumstances. This principle has shaped the evolution of the climate regime and has played an important role in promoting compromise and agreement. It is argued that some twenty years after the adoption of the United Nations Framework Convention on Climate Change (UNFCCC), the principle of CBDRC remains as relevant as ever. The practice of Parties under the regime and, most recently, the concerted efforts to shape and flesh out the meaning of the principle, underscore the central role that it plays. At the same time, the binary understanding of CBDRC in the Kyoto Protocol is being replaced with a more nuanced, multifaceted understanding. The evolving interpretation of CBDRC is considered, and its continued relevance as the nucleus of a global burden-sharing regime for addressing climate change is demonstrated. Policy relevance The development of a common understanding of the principle of CBDRC is essential for the burden sharing and responsibilities under a future climate agreement. The CBDRC principle captures the idea that it is the common responsibility of states to protect and restore the environment, but that the levels and forms of states’ individual responsibilities may be differentiated according to their own national circumstances. This article informs the international climate change negotiations by considering the development of the principle of CBDRC under the UNFCCC over time. It is concluded that, although there has been a significant shift in how the principle is understood, it remains crucial to the integrity and stability of the climate regime. 相似文献
10.
Janine Meinsen Jutta Winsemann Julia Roskosch Christian Brandes Manfred Frechen Stefan Dultz Jürgen Böttcher 《Boreas: An International Journal of Quaternary Research》2014,43(1):42-66
The Late Pleistocene was characterized by rapid climate oscillations with alternation of warm and cold periods that lasted up to several thousand years. Although much work has been carried out on the palaeoclimate reconstruction, a direct correlation of ice‐core, marine and terrestrial records is still difficult. Here we present new data from late Middle Pleniglacial to Lateglacial alluvial‐fan and aeolian sand‐sheet deposits in northwestern Germany. Records of Late Pleniglacial alluvial fans in central Europe are very rare, and OSL dating is used to determine the timing of fan aggradation. In contrast to fluvial systems that commonly show a delay between climate change and incision/aggradation, the small alluvial‐fan systems of the Senne area responded rapidly to climatic changes and therefore act as important terrestrial climate archives for this time span. The onset of alluvial‐fan deposition correlates with the climate change from warm to cold at the end of MIS 3 (29.3±3.2 ka). Strong fan progradation started at 24.4±2.8 ka and may be related to a period of higher humidity. The vertical stacking pattern of sedimentary facies and channel styles indicate a subsequrent overall decrease in water and sediment supply, with less sustained discharges and more sporadic runoffs from the catchment area, corresponding to an increasing aridity in central Europe during the Late Pleniglacial. Major phases of channel incision and fan aggradation may have been controlled by millennial‐scale Dansgaard–Oeschger cycles. The incision of channel systems is attributed to unstable climate phases at cold–warm (dry–wet) or warm–cold (wet–dry) transitions. The alluvial‐fan deposits are bounded by an erosion surface and are overlain by aeolian sand‐sheets that were periodically affected by flash‐floods. This unconformity might be correlated with the Beuningen Gravel Bed, which is an important marker horizon in deposits of the Late Pleniglacial resulting from deflation under polar desert conditions. The deposition of aeolian sand‐sheet systems (19.6±2.1 to 13.1±1.5 ka) indicates a rapid increase in aridity at the end of the Late Pleniglacial. Intercalated flash‐floods deposits and palaeosols (Finow type) point to temporarily wet conditions during the Lateglacial. The formation of an ephemeral channel network probably marks the warm‐cold transition from the Allerød to the Younger Dryas. 相似文献