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1.
黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义。以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征。结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为46.030%、52.815%,介于岩浆成因与热液成因之间,根据矿石特征,黄铁矿以岩浆成因为主,并有少量热液作用参与;将白草矿区黄铁矿δFe-δS特征与金川等典型铜镍硫化物矿床黄铁矿对比,表明白草矿区黄铁矿为典型的岩浆熔离型;由于存在钒钛磁铁矿,Co/Ni值多小于5,说明钒钛磁铁矿与硫化物存在共生关系;岩浆内生成因黄铁矿S/Se值小于15000,白草矿区黄铁矿S/Se值为812~10466,显示白草矿区黄铁矿为岩浆内生成因;Se/Te值随温度降低而升高,显示上述4类矿石黄铁矿结晶顺序为浸染状矿石→致密块状矿石→斑杂状矿石→网脉状矿石;原始地幔标准化主量、微量元素蛛网图显示白草矿区黄铁矿兼具岩浆成因与热液成因。综上所述,攀西地区白草矿区黄铁矿成因主要以岩浆熔离作用为主,并含有少量热液作用。  相似文献   
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In this paper, we investigate a linear regression time series model of possibly outlier-afflicted observations and autocorrelated random deviations. This colored noise is represented by a covariance-stationary autoregressive (AR) process, in which the independent error components follow a scaled (Student’s) t-distribution. This error model allows for the stochastic modeling of multiple outliers and for an adaptive robust maximum likelihood (ML) estimation of the unknown regression and AR coefficients, the scale parameter, and the degree of freedom of the t-distribution. This approach is meant to be an extension of known estimators, which tend to focus only on the regression model, or on the AR error model, or on normally distributed errors. For the purpose of ML estimation, we derive an expectation conditional maximization either algorithm, which leads to an easy-to-implement version of iteratively reweighted least squares. The estimation performance of the algorithm is evaluated via Monte Carlo simulations for a Fourier as well as a spline model in connection with AR colored noise models of different orders and with three different sampling distributions generating the white noise components. We apply the algorithm to a vibration dataset recorded by a high-accuracy, single-axis accelerometer, focusing on the evaluation of the estimated AR colored noise model.  相似文献   
4.
This study provides a systemic analysis to identify the biases in estimated satellite clocks and illustrates their effects in precise point positioning (PPP). First, the precise satellite clock estimation method considering pseudorange and carrier phase hardware delays is derived. Two methods for satellite clock estimation are compared, and their equivalency is discussed. The results show that apart from the well-known constant code hardware biases, the time-variant phase hardware biases are also absorbed by the estimated clocks. Also, the satellite clocks contain biases caused by modeling errors. To analyze the effects of these biases, they are grouped into initial clock biases (ICBs) and time-dependent biases (TDBs). Then, a detailed analysis of the impact of the biases on PPP-based troposphere and coordinate estimates is conducted. The experimental analysis demonstrates that TDBs affect positioning and tropospheric estimates, and their impacts are more significant in the static mode. The ICBs affect coordinate accuracy, zenith total delay mean bias, and its standard deviations only at the millimeter level for kinematic and static PPP, which is negligible. However, the ICBs affect the convergence period for both static and real kinematic PPP, and the magnitude of their impact largely depends on data quality. Note that satellites clocks are generally estimated with the P1/P2 and L1/L2 ionospheric-free combinations, and that hardware-specific parts of ICBs and TDBs cancel if users employ the same type of observables as the clock providers. Otherwise, the effects of biases cannot be ignored, especially for triple-frequency applications. Also, modeling-specific parts of ICBs and TDBs are significant in real-time clocks, which also affect user applications. Our conclusion is applicable for understanding the effects of these biases.  相似文献   
5.
Projections of runoff from global multi-model ensembles provide a valuable basis for the estimation of future hydrological extremes. However, projections suffer from uncertainty that originates from different error sources along the modeling chain. Hydrological impact studies have generally partitioned these error sources into global impact and global climate model (GIM and GCM, respectively) uncertainties, neglecting other sources, including scenarios and internal variability. Using a set of GIMs driven by GCMs under different representative concentration pathways (RCPs), this study aims to partition the uncertainty of future flows coming from GIMs, GCMs, RCPs, and internal variability over the CONterminous United States (CONUS). We focus on annual maximum, median, and minimum runoff, analyzed decadally over the twenty-first century. Results indicate that GCMs and GIMs are responsible for the largest fraction of uncertainty over most of the study area, followed by internal variability and to a smaller extent RCPs. To investigate the influence of the ensemble setup on uncertainty, in addition to the full ensemble, three ensemble configurations are studied using fewer GIMs (excluding least credible GIMs in runoff representation and GIMs accounting for vegetation and CO2 dynamics), and excluding intermediate RCPs. Overall, the use of fewer GIMs has a minor impact on uncertainty for low and medium flows, but a substantial impact for high flows. Regardless of the number of pathways considered, RCPs always play a very small role, suggesting that improvement of GCMs and GIMs and more informed ensemble selections can yield a reduction of projected uncertainties.  相似文献   
6.
张威涛  任利剑  运迎霞 《地理科学》2020,40(11):1899-1908
关注滨海城市竖向避难场所的选址可靠性问题,首先深化确立“竖向避难场所”概念;然后构建竖向避难场所选址可靠性评价模型,综合自然地理要素和建成环境要素,从与灾害直接作用相关的选址暴露性、与应急交通相关的选址敏感性、与应急服务相关的选址适应性3个维度展开,搭建3级评价指标体系;再以天津滨海新区为例、聚焦滨海城市潮洪灾害和人口安全矛盾的集核——临港城区展开实证研究,借助ArcGIS分类与可视化发现:高低可靠性选址之间具有明显的空间分异,可以分解为灾害暴露性的“近岸高?远岸低”分异、交通敏感性的“外围高?中心低”分异、服务适应性的“中心与沿河高?外围低”兼“近港高?远港低”分异。同时发现:商业设施用地选址价值较高,在高可靠性选址中占比第一;中小学和社会福利设施用地选址价值最高,在高可靠性选址中占比第二;文化科研和娱乐康体设施用地在高可靠性选址中占比最小。针对临港城区实证研究结果,提出滨海城市竖向避难场所选址及可靠性提升对策。  相似文献   
7.
王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345
为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明:1)多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO2等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2)利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3)δ 18O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程(主要是呼吸作用过程);而对比水库水体和大气降水的d-excess(d值)发现,水库水体的d值(8.21‰)显著偏低于当地大气降水的d值(9.64‰),说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   
8.
摘要:目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性,属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高,α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高,且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸,并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示,α螺旋和β片层围成了蛋白酶的催化腔,EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体,且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性,并有助于其催化功能的发挥,为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   
9.
ABSTRACT

Pedestrian networks play an important role in various applications, such as pedestrian navigation services and mobility modeling. This paper presents a novel method to extract pedestrian networks from crowdsourced tracking data based on a two-layer framework. This framework includes a walking pattern classification layer and a pedestrian network generation layer. In the first layer, we propose a multi-scale fractal dimension (MFD) algorithm in order to recognize the two different types of walking patterns: walking with a clear destination (WCD) or walking without a clear destination (WOCD). In the second layer, we generate the pedestrian network by combining the pedestrian regions and pedestrian paths. The pedestrian regions are extracted based on a modified connected component analysis (CCA) algorithm from the WOCD traces. We generate the pedestrian paths using a kernel density estimation (KDE)-based point clustering algorithm from the WCD traces. The pedestrian network generation results using two actual crowdsourced datasets show that the proposed method has good performance in both geometrical correctness and topological correctness.  相似文献   
10.
Recently measured high gamma ray values in the Yanchang Formation of the Upper Triassic in the Ordos Basin have added an interesting and controversial twist to the study of the formation’s uranium enrichment and genesis. High uranium and thorium contents in the tuffaceous layer cause high gamma ray values in the Yanchang Formation. Petrographic studies, major elements, rare earth elements (REEs), and trace elements have been systematically analyzed to determine the composition, geochemical environment, and diagenetic processes of the layer. The observed color of the tuffaceous layer in the study area varies from yellow to yellowish brown. The tuff consists of matrix supported with sub-rounded to sub-angular lithic fragments. These lithic fragments probably derived from pre-existing rocks and incorporated into the tuffaceous layer during volcanic eruption. Quartz, plagioclase, and biotite were observed in well to poorly sorted form, in addition to framboidal pyrite and organic laminae. Measured ratios of SiO2/Al2O3 ranged from 3.277 to 6.105 with an average of 3.738. The ratio of TiO2/Al2O3 varied from 0.037 to 0.201 with an average of 0.061, indicating that the sediments of the tuffaceous layer originated from an intermediate magma. REE distribution patterns show sharp negative Eu anomalies, indicating a reducing environment, which is suitable for uranium deposition. A reducing environment was confirmed by black shale in the base of the Yanchang Formation. Such black shale has high organic matter content that can take kerogene from mudstone and provide a reducing environment for uranium enrichment in the tuffaceous layer. Moreover, negative Eu anomalies and the REE patterns indicate a subduction-related volcanic arc environment as the magma source of the tuffaceous layers. High values of Rb, Ba, and Sr might be the result of fluid phase activities; low values of Hf and Eu indicate the involvement of crustal material during diagenesis of the tuff. Discrimination diagrams (Th/Yb vs Ta/Yb, Th/Hf vs Ta/Hf) suggest an active continental margin as the tectonic setting of source volcanoes. Plots of Nb versus Y, Rb versus Y + Nb, TiO2 versus Zr, and Th/Yb versus Nb/Yb of the tuffaceous content point to calc-alkaline continental arc-related magmatism. We concluded that uranium enrichment in the tuffaceous layer was supported by oxidation–reduction.  相似文献   
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