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1.
Cu-bearing pyroxene, Mg(Cu.56,Mg.44)Si2O6, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3Å3. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu2+ is unusual among the divalent cations with similar ionic sizes. 相似文献
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Toshihiko Yajima Hideo Higuchi Hiroshi Nagasawa 《Contributions to Mineralogy and Petrology》1972,35(3):235-244
The abundances of rare earth elements in 5 each of aphyric volcanic rocks of pigeonitic and hypersthenic rock series from Izu-Hakone region have been determined by neutron activation analysis. Pigeonitic rock series show rare earth patterns with relative depletion of lighter rare earths (low lanthanum type) and large increase in rare earth abundances with differentiation. Hypersthenic rock series show higher lanthanum abundances (high lanthanum type) compared with pigeonitic rock series. The differences in rare earth patterns between two rock series are compatible with the theory of independent magmatic generation of these two series. Variation of rare earth patterns in both series have been examined by a model of magmatic differentiation based on the observed rare earth partition coefficients. 相似文献
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Diffusion coefficients of Co2+ and Ni2+ in synthetic single crystal forsterite along the c-axis were determined in the temperature ranges, 700–1200?°C and 800–1300?°C, respectively. The synthesized forsterite specimens were coated with thin evaporated films of CoO and NiO on the c-surface and annealed for diffusion experiments. The short penetration distance of diffusing ions in forsterite was measured by secondary ion mass spectrometry using the depth profile method. The diffusion coefficients of Co (700–1200?°C) and Ni (800–1300?°C) are given by: and The observed diffusion coefficient values show good linear relationships in Arrhenius plots and the activation energy values obtained agree well with the previous values, although the diffusion coefficient values observed at the high temperature end of the experimental range deviate from the previous values. These results indicate that Co and Ni diffuse in olivine with a single mechanism within the temperature range observed, possibly with an extrinsic in nature as in the case of Mg tracer diffusion observed by Chakraborty et?al. 1994 and of Fe-Mg interdiffusion by Chakraborty. 相似文献
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Hiroshi Nagasawa Douglas P Blanchard Jeffrey W Jacobs Joyce C Brannon John A Philpotts Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600
Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the 26Al-26Mg chronometer. 相似文献
8.
Motoo Ito Hiroshi Nagasawa Hisayoshi Yurimoto 《Meteoritics & planetary science》2006,41(12):1871-1881
Abstract— The measurements of magnesium and potassium isotopic compositions of refractory minerals in Allende calcium‐aluminum‐rich inclusions (CAIs), 7R‐19–1, HN3–1, and EGG3 were taken by secondary ion mass spectrometry (SIMS). The 7R‐19–1 contains 16O‐rich and 16O‐poor melilite grains and define a single isochron corresponding to an initial 26Al/27Al ratio of (6.6 ± 1.3) × 10?5. The Al‐Mg isochron, O isotope measurements and petrography of melilite in 7R‐19–1 indicate that 16O‐poor melilite crystallized within 0.4 Myr after crystallization of 16O‐rich melilite, suggesting that oxygen isotopic composition of the CAI‐forming region changed from 16O‐rich to 16O‐poor within this time interval. The 16O‐poor melilite is highly depleted in K compared to the adjacent 16O‐rich melilite, indicating evaporation during remelting of 7R‐19–1. We determined the isochron for 41Ca‐41K isotopic systematics in EGG3 pyroxene with (4.1 ± 2.0) × 10?9 (2s?) as an initial ratio of 41Ca/40Ca, which is at least two times smaller than the previous result (Sahijipal et al. 2000). The ratio of 41Ca/40Ca in the EGG3 pyroxene grain agrees within error with the value obtained by Hutcheon et al. (1984). No evidence for the presence of 41K excess (decay product of a short‐lived radionuclide 41Ca) was found in 7R‐19–1 and HN3–1. We infer that the CAI had at least an order of magnitude lower than canonical 41Ca/40Ca ratio at the time of the CAI formation. 相似文献
9.
Richard D. Brodeur Joseph P. Fisher Yasuhiro Ueno Kazuya Nagasawa William G. Pearcy 《Journal of Oceanography》2003,59(4):415-434
During the 1980s and 1990s, scientific research cruises were conducted in both the eastern and western boundary regions of
the North Pacific Ocean. The main purpose of these cruises was to examine the abundance and distribution patterns of juvenile
salmon in coastal waters. These studies created one of the most extensive databases ever collected on the species composition
of coastal Transition Zone epipelagic nekton in the North Pacific Ocean. Catch data from two purse seine and two surface trawl
surveys (one each from off northern Japan and eastern Russia and off the West Coast of the U.S.) were examined using multivariate
techniques to analyze the community structure of nektonic cephalopods, elasmobranchs, and teleosts in the coastal zone during
the summer and autumn months. Juvenile salmonids are generally among the most common species caught, but in terms of overall
abundance, other potential competitors with juvenile salmon, such as small squids and clupeoid fishes predominated the catches.
Species diversity and dominance varied among areas and gear types. Distinct assemblages were found in each area, but the two
regions had closely related species occupying similar ecological positions in each habitat.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.
Spatial Variability of Living Coccolithophore Distribution in the Western Subarctic Pacific and Western Bering Sea 总被引：1，自引：0，他引：1
Hiroshi Hattori Makoto Koike Kenichi Tachikawa Hiroaki Saito Kazuya Nagasawa 《Journal of Oceanography》2004,60(2):505-515
Vertical distributions of coccolithophores were observed in the depth range 0–50 m in the western subarctic Pacific and western
Bering Sea in summer, 1997. Thirty-five species of coccolithophores were collected. Overall, Emiliania huxleyi var. huxleyi was the most abundant taxon, accounting for 82.8% of all coccolithophores, although it was less abundant in the western Bering
Sea. Maximum abundance of this species was found in an area south of 41°N and east of 175°E (Transition Zone) reaching >10,000
cells L−1 in the water column. In addition to this species, Coccolithus pelagicus f. pelagicus, which accounted for 4.2% of the assemblage, was representative of the coccolithophore standing crop in the western part
of the subarctic Pacific. Coccolithus pelagicus f. hyalinus was relatively abundant in the Bering Sea, accounting for 2.6% of the assemblage. Coccolithophore standing crops in the top
50 m were high south of 41°N (>241 × 106 cells m−2) and east of 170°E (542 × 106 cells m−2) where temperatures were higher than 12°C and salinities were greater than 34.2. The lowest standing crop was observed in
the Bering Sea and Oyashio areas where temperatures were lower than 6–10°C and salinities were less than 33.0. From the coccolithophore
volumes, the calcite stocks in the Transition, Subarctic, and the Bering Sea regions were estimated to be 73.0, 9.7, and 6.9
mg m−2, respectively, corresponding to calcite fluxes of 3.6, 0.5, and 0.3 mg m−2d−1 using Stoke's Law.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献