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1.
The estimation of hydrologic transit times in a catchment provides insights into the integrated effects of water storage, mixing dynamics, and runoff generation processes. There has been limited effort to estimate transit times in southern boreal Precambrian Shield landscapes, which are characteristically heterogeneous with surface cover including till, thin soils, bedrock outcrops, and depressional wetland features that play contrasting hydrologic roles. This study presents approximately 3.5 years of precipitation and streamflow water isotope data and estimates mean transit times (MTTs) and the young water fraction (py) across six small catchments in the Muskoka-Haliburton region of south-central Ontario. The main objectives were to define a typical range of MTTs for headwater catchments in this region and to identify landscape variables that best explain differences in MTTs/py using airborne light detection and ranging and digital terrain analysis. Of the transit time distributions, the two parallel linear reservoir and gamma distributions best describe the hydrology of these catchments, particularly because of their ability to capture more extreme changes related to events such as snowmelt. The estimated MTTs, regardless of the modelling approach or distribution used, are positively associated with the percent wetland area and negatively with mean slope in the catchments. In this landscape, low-gradient features such as wetlands increase catchment scale water storage when antecedent conditions are dryer and decrease transit times when there is a moisture surplus, which plausibly explains the increases in MTTs and mean annual runoff from catchments with significant coverage of these landscape features.  相似文献   
2.
A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
3.
Times for accumulation of chemically significant dosages on icy surfaces of Centaur, Kuiper Belt, and Oort Cloud objects from plasma and energetic ions depend on irradiation position within or outside the heliosphere. Principal irradiation components include solar wind plasma ions, pickup ions from solar UV ionization of interstellar neutral gas, energetic ions accelerated by solar and interplanetary shocks, including the putative solar wind termination shock, and galactic cosmic ray ions from the Local Interstellar Medium (LISM). We present model flux spectra derived from spacecraft data and models for eV to GeV protons at 40 AU, a termination shock position at 85 AU, and in the LISM. Times in years to accumulate dosages ~100 eV per molecule are computed from the spectra as functions of sensible surface depth less than one centimeter at unit density.The collisional resurfacing model of Luu and Jewitt is reconsidered in thecontext of depth-dependent dosage rates from plasma, suprathermal,and higher energy protons, and global exposure, by micrometeoroiddust grain impacts, of moderately irradiated red material below athin crust of heavily irradiated neutral material. This material should be more visible on dynamically `cold’ objects in the ~40 AU region.  相似文献   
4.
 Near-surface sediment geoacoustic and physical properties were measured from a variety of unconsolidated carbonate sediments in the Lower Florida Keys. Surficial values of compressional and shear speed correlate with sediment physical properties and near-surface acoustic reflectivity. Highest speeds (shear 125–150 m s-1; compressional 1670–1725 m s-1) are from sandy sediments near Rebecca Shoal and lowest speeds (shear 40–65 m s-1; compressional 1520–1570 m s-1) are found in soft, silty sediments which collect in sediment ponds in the Southeast Channel of the Dry Tortugas. High compressional wave attenuation is attributed to scattering of acoustic waves from heterogeneity caused by accumulation of abundant shell material and other impedance discontinuities rather than high intrinsic attenuation. Compared to siliciclastic sediments, carbonate sediment shear wave speed is high for comparable values of sediment physical properties. Sediment fabric, rather than changes due to the effects of biogeochemical processes, is responsible for these differences.  相似文献   
5.
6.
Remote sensing and surface POC concentration in the South Atlantic   总被引:1,自引:0,他引:1  
Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.  相似文献   
7.
An extensive study of peridotitic sulfide inclusion bearing diamonds and their prospective harzburgitic host rocks from the 53 Ma Panda kimberlite pipe, Ekati Mine, NWT Canada, has been undertaken with the Re–Os system to establish their age and petrogenesis. Diamonds with peridotitic sulfide inclusions have poorly aggregated nitrogen (<30% N as B centers) at N contents of 200–800 ppm which differs from that of chromite and silicate bearing diamonds and indicates residence in the cooler portion of the Slave craton lithospheric mantle. For most of the sulfide inclusions, relatively low Re contents (average 0.457 ppm) and high Os contents (average 339 ppm) lead to extremely low 187Re/188Os, typically << 0.05. An age of 3.52 ± 0.17 Ga (MSWD = 0.46) and a precise initial 187Os/188Os of 0.1093 ± 0.0001 are given by a single regression of 11 inclusions from five diamonds that individually provide coincident internal isochrons. This initial Os isotopic composition is 6% enriched in 187Os over 3.5 Ga chondritic or primitive mantle. Sulfide inclusions with less radiogenic initial Os isotopic compositions reflect isotopic heterogeneity in diamond forming fluids. The harzburgites have even lower initial 187Os/188Os than the sulfide inclusions, some approaching the isotopic composition of 3.5 Ga chondritic mantle. In several cases isotopically distinct sulfides occur in different growth zones of the same diamond. This supports a model where C–O–H–S fluids carrying a radiogenic Os signature were introduced into depleted harzburgite and produced diamonds containing sulfides conforming to the 3.5 Ga isochron. Reaction of this fluid with harzburgite led to diamonds with less radiogenic inclusions while elevating the Os isotope ratios of some harzburgites. Subduction is a viable way of introducing such fluids. This implies a role for subduction in creating early continental nuclei at 3.5 Ga and generating peridotitic diamonds.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   
8.
The relationship between molluscan shell growth rate and skeletal δ18O and δ13C was investigated in a detailed field study for the scallop, Pecten maximus. Seasonal variation in shell growth rate was found to be a governing factor influencing shell δ18O and δ13C. At low shell growth rates, shell δ18O were more positive (of the order +0.4‰) and δ13C more negative (up to −2‰) as compared with predicted values for precipitation of inorganic calcite in isotopic equilibrium with seawater. The deviations in δ18O were hypothesized as reflecting possible differences in solution carbonate chemistry at the site of mineralization in the extrapallial fluid as compared with that of the external seawater medium. The deviations in shell δ13C were consistent with incorporation of isotopically depleted respiratory 13C (i.e., a metabolic effect). A trend toward more depleted shell δ18O and δ13C values occurred at higher shell growth rates, with negative δ18O values as compared with predicted equilibrium at shell growth rates above 0.13 mm per day. These simultaneous negative deviations in skeletal δ18O and δ13C were interpreted as resulting from a kinetic effect. The implications for environmental reconstruction from molluscan isotopic records are discussed in light of a model of isotopic behavior based on the findings of the study.  相似文献   
9.
Remobilization of sandstones can dramatically reconfigure original depositional geometries and results in very unusually shaped sandstones, which resemble little, if any, of the original geometry. A number of deformational sandstone bodies, dykes and volcanoes from the upper part of the Carboniferous Ross Formation are described, which offer the opportunity to examine a suite of field-scale reconfigured sandstones. These structures are located in close proximity to the Ross Slide, which outcrops along a 2-km section on the northern coast of the Loop Head Peninsula, County Clare, Ireland. Dome- and ridge-shaped deformational sandstone bodies, dykes and volcanoes are interpreted to be the product of remobilization of a turbiditic sandstone. Liquification and remobilization were triggered by translation, cessation and loading of the underlying turbiditic sandstone by the Ross Slide. Deformational sand body, dyke and volcano development occurred in an asynchronous fashion with deformational sand bodies formed during slump translation. Sand dykes and volcanoes developed after the cessation of slump movement. During slump translation, the minimum principal stress (σ3) was orientated vertically and the slump behaved in a `ductile' manner. After slump arrest, the minimum principal stress was oriented horizontally, and the unit regained shear strength to behave in a `brittle' manner. The relative change in rheological states with changing applied shear stress is indicative of thixotropic-like behaviour within the slump mass. Ridge-shaped deformational sand bodies are aligned parallel to slump folds, and their morphology is inferred to be controlled by compressional slump deformation associated with heterogeneous cessation of slump movement that was initiated by frontal arrest of the translating mass.  相似文献   
10.
Marine mussels, Perna viridis, were transplanted from a reference site to various polluted sites around Hong Kong. After 30 d of exposure, antioxidative responses in the gills and hepatopancreas and tissue concentrations of chlorinated hydrocarbons [polychlorinated biphenyls (PCBs) and chlorinated pesticides (CPs)] were determined for individual mussels. Glutathione S transferase (GST) and glutathione (GSH) were positively correlated with tissue PCB concentrations. Only one of the enzymatic antioxidants, glutathione peroxidase (GPx), showed significant response to tissue PCB. No significant correlation was found between tissue concentrations of chlorinated hydrocarbons and other enzymatic antioxidants (superoxide dismutase (SOD), catalase (CAT), glutathione reductase (GR) and NADPH DT-diaphorase (DT-d). Oxidative stress, measured as thiobarbituric acid reactive substances, was correlated with chlorinated pesticide concentrations in tissues. This study demonstrated a correlation between GST/GSH and chlorinated hydrocarbons. The apparent lack of correlation between trace organic pollutants and some of the enzymatic antioxidants may be due to the inhibitory effects caused by these chemicals. The above results suggest that more investigations are needed before these enzymes can be used as biomarkers.  相似文献   
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