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1.
A four-year record from an inverted echo sounder deployed near Palmyra Island at 6°N in the central Pacific Ocean is compared with a simultaneous record of subsurface pressure from this island lagoon. A factor m, converting round-trip acoustic travel time to surface dynamic height relative to a deep pressure level, was estimated from the ratio of the spectra of the two records in the energetic synoptic oscillation band. Year-to-year variation in m was not statistically significant. For the overall record, m was found to be -70±8 dynamic m/s, where the error bounds represent a 90% confidence interval. This is consistent with first-baroclinic-mode excitation  相似文献   
2.
This paper examines the oceanic response off Baja California, Mexico, to the 1997–1998 El Niño and the transition to La Niña conditions. The data presented were gathered during seven cruises over a grid based on the CalCOFI station plan, from lines 100–130, out to station 80. T–S diagrams with data obtained during the peak phase of El Niño, demonstrate that warmer and saltier (spicier) than normal conditions prevailed in the upper 600 m over this region. Temperature and salinity anomalies calculated for CalCOFI line 120 revealed waters near the coast at 50 m depth to be up to 8.7 °C warmer and S=0.8 saltier than the climatology during October 1997. These large anomalies persisted through January 1998, with some slight diminution in the magnitudes near the surface. This study suggests that anomalously warm and salty waters were fed from a source of spicy water to the southwest, identified as Subtropical Surface Water (StSW), and that low-salinity Tropical surface waters (TSW) were blocked to the southeast in the vicinity of the tip of the Peninsula. Subsurface waters associated with the California undercurrent (CU), fed from the Eastern Tropical Pacific (ETP), were also warmer and saltier than normal, and indicate a significant expansion in volume of the CU, presumably a result of intensification of poleward flow at depth. We postulate that the well defined near-surface and deep poleward flows in the study area reflect anomalous large-scale cyclonic circulation affecting the flow in the southeastern region of the North Pacific subtropical gyre east of 125°W. Following the El Niño event, warm and salty upper waters retreated to latitudes south of Punta Eugenia. With the return to normal and cooler conditions, equatorward flow over the sampling grid predominated with an increased meandering and mesoscale activity. Transition to La Niña conditions would have been associated with re-establishment of normal anticyclonic flow in the southeastern quadrant of the Pacific subtropical gyre.  相似文献   
3.
We measured the spatial variation of aluminium concentrations and computed its species distribution before and during mixing of acid mine drainage containing waters with near neutral receiving waters. Acid mine drainage was collected from the Loquitz Creek, Thuringia, Germany, and Garvey Creek, Westland, New Zealand, which drain slate mine workings and coal mine workings, resp. The acidneutralizing capacity (ANC) of the receiving streams and the mixing with waters having low Al-concentrations cause a decrease of aluminium concentrations below the confluence. Depending on volumes and ANCs involved, the content of free Al and sulphate bound Al decreases after mixing in favour of organic and hydroxide bound Al. In addition, below the junction of the Loquitz Creek and the Aue Creek with its high ANC, we observe the precipitation of aluminium hydroxides and Al hydroxysulphates.
Zusammenfassung Wir haben die räumliche Änderung der Aluminiumkonzentrationen vor und nach der Mischung von Flußwasser, versauert durch Bergwerksabwässer, mit nahezu neutralem Wasser der Vorfluter gemessen und haben dazu die Speziesverteilung berechnet. Saure Bergwerksabwässer sickern aus Halden eines Schiefertagebaus in Thüringen in die Loquitz ebenso wie aus Halden eines Kohletagebaus in den Garvey Creek, Westland, Neuseeland. Die Säuren-Neutralisierungskapazität der Vorfluter und die Mischung mit Al-armem Wasser bewirken eine Abnahme der Aluminiumkonzentrationen nach dem Zusammenfluß. In Abhängigkeit von beteiligten Abflüssen und Säuren-Neutralisierungskapazitäten nimmt der Gehalt an freiem Aluminium und sulfatgebundenem Aluminium nach der Mischung zugunsten von organisch- und hydroxy-gebundenem Aluminium ab. Ferner beobachten wir unterhalb des Zusammenflusses von Loquitz und Aue, der eine hohe Säuren-Neutralisierungskapazität eigen ist, eine Ausfällung von Aluminiumhydroxyden und Aluminiumhydroxysulfaten.

Résumé Nous avons mesuré la variation spatiale de la teneur en Al et calculé la distribution de ses différentes formes dans deux cours d'eau différents, qui reçoivent des eaux acides venant de mines situées sur leur cours. Ces mesures ont été faites d'une part sur le cours du Loquitz (Thuringe-Allemagne) qui reçoit des aux acides venant d'une mine d'ardoise et d'autre part sur le cours du Garvey (Westland - Nouvelle Zélande) qui reçoit les eaux d'une mine de charbon. Pour chaque cours d'eau, les mesures ont été faites en amont de la source d'apport, puis en aval, c'est-à-dire après le mélange avec les eaux acides. La capacité de neutralisation des acides (ANC) des eaux des cours d'eau récepteurs et la basse teneur en Al des eaux d'apport provoquent une diminution de la teneur en Al après le mélange. Dans une mesure liée aux volumes en jeu et à l'ANC, la teneur en Al libre et en Al lié au sulfate diminue près le mélange au profit de l'Al lié soit à des substances organiques, soit à des hydroxydes. De plus, en aval du confluent du Loquitz et de l'Aue, rivière à ANC élevé, nous observons la précipitation d'hydroxydes d'Al et d'hydroxisulfates d'Al.

, , - , . , , Garvey Creek, Westland, . , , , , , , , , , . , , , .
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4.
5.
Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low 176Lu/177Hf and 147Sm/144Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.  相似文献   
6.
Melting experiments of calcite were performed on the join CaCO3‐H2O at a pressure of 1000 bars. The system evolves to the ternary CaO‐H2O‐CO2 system during melting experiments. Our experiments show that partial melting of calcite begins at a low temperature, below 650 °C. Such a low partial melting temperature for carbonates revives the debate about the presence of carbonate melts in the upper crust. More specifically, the conditions for carbonate partial melting are present in carbonate host rocks undergoing contact metamorphism at high temperatures in the presence of water‐rich fluid. The presence of carbonate melts influences physical parameters such as viscosity and permeability in contact aureoles, and, furthermore, decarbonation reactions release massive amounts of CO2.  相似文献   
7.
In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ18O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ18O = ~15‰) to the rim (δ18O = ~11‰) suggests that the 18O/16O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the 18O/16O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ18O value of the garnet rim, together with the previously reported low δ18O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ18O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   
8.
Forests cover 29% of the continents. Their importance for mankind is not only due to wood production but also by their manyfold influences on the biosphere. The properties of forest stands influence climate, water balance, air constituents and the dynamic of atmosphere. The welfare functions of forests can be observed in the global as well as in the local or microscale. Anthropogenic measures, as deforestation and air pollution, endanger the forests and by that one of the main pillars of nature on earth.  相似文献   
9.
High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore, the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical PTt histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle.  相似文献   
10.
Shallow-water limestones of presumed Late Cretaceous and Eocene age, interbedded with basaltic lavas, were described by earlier authors from São Nicolau in the northwestern part of the Cabo Verde archipelago. If confirmed, these ages would imply late Mesozoic shallow-marine and subaerial volcanic activity in the Cabo Verde archipelago, and document a geological history very different from that known so far from other Cabo Verde Islands, from which no subaerial volcanic activity before the mid-Cenozoic is known. Our re-investigation of the foraminiferal fauna indicates a Late Miocene age for the presumed Late Cretaceous and Eocene limestones. The hypothesis of a long-lived hot spot, active by the Early Cretaceous, and of a major island-building stage in the Cabo Verde Islands during this period, is therefore not supported by the present bio- or chronostratigraphic data.  相似文献   
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