Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km2 area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models. 相似文献
Serpentine soils and ultramafic laterites develop over ultramafic bedrock and are important geological materials from environmental, geochemical, and industrial standpoints. They have naturally elevated concentrations of trace metals, such as Ni, Cr, and Co, and also high levels of Fe and Mg. Minerals host these trace metals and influence metal mobility. Ni in particular is an important trace metal in these soils, and the objective of this research was to use microscale (µ) techniques to identify naturally occurring minerals that contain Ni and Ni correlations with other trace metals, such as Fe, Mn, and Cr. Synchrotron based µ-XRF, µ-XRD, and µ-XAS were used. Ni was often located in the octahedral layer of serpentine minerals, such as lizardite, and in other layered phyllosilicate minerals with similar octahedral structure, such as chlorite group minerals including clinochlore and chamosite. Ni was also present in goethite, hematite, magnetite, and ferrihydrite. Goethite was present with lizardite and antigorite on the micrometer scale. Lizardite integrated both Ni and Mn simultaneously in its octahedral layer. Enstatite, pargasite, chamosite, phlogopite, and forsterite incorporated various amounts of Ni and Fe over the micrometer spatial scale. Ni content increased six to seven times within the same 500 µm µ-XRD transect on chamosite and phlogopite. Data are shown down to an 8 µm spatial scale. Ni was not associated with chromite or zincochromite particles. Ni often correlated with Fe and Mn, and generally did not correlate with Cr, Zn, Ca, or K in µ-XRF maps. A split shoulder feature in the µ-XAS data at 8400 eV (3.7 Å?1 in k-space) is highly correlated (94% of averaged LCF results) to Ni located in the octahedral sheet of layered phyllosilicate minerals, such as serpentine and chlorite-group minerals. A comparison of bulk-XAS LCF to averaged µ-XAS LCF results showed good representation of the bulk soil via the µ-XAS technique for two of the three soils. In the locations analyzed by µ-XAS, average Ni speciation was dominated by layered phyllosilicate and serpentine minerals (76%), iron oxides (18%), and manganese oxides (9%). In the locations analyzed by µ-XRD, average Ni speciation was dominated by layered phyllosilicate, serpentine, and ultramafic-related minerals (71%) and iron oxides (17%), illustrating the complementary nature of these two methods.
The Tons Valley, situated in the central-easternmost part of the Himachal Lesser Himalaya, adjoining the Garhwal Himalaya, shows geological features suggestive of a strong pre-Tertiary deformational episode. The Paleoproterozoic Dharagad Group, overlain by the Mesoproterozoic Deoban and Neoproterozoic Simla groups rest as a thrust sheet over the Middle Cambrian Chilar Formation, which occurs as windows and also as tectonic slivers within the thrust sheet designated as the Dharagad Thrust Sheet (DTS). The mineral lineation, inclination of tectonic slivers and overturned beds suggest that the DTS was translated from the NE. The westernmost and southwesternmost leading edges of the DTS are exposed at Subathu and Morni WNW and WSW respectively of the Tons Valley. The position of the leading edges of the DTS vis-à-vis the windows in the Tons Valley suggest a minimum translation of about 50 km for the DTS. The Simla Group at Subathu and the Deoban at Morni, forming parts of the DTS, constitute basement for the Thanetian–Lutetian Subathu Formation of the Himalayan Foreland Basin (HFB). This stratigraphic relationship unambiguously demonstrates that the Simla and the Deoban Groups, forming leading edges of the allochthonous DTS, were already translated and emplaced at Subathu and Morni before the creation of the HFB in which the deposition commenced with the Subathu Formation in Thanetian. It implies that the DTS was translated from the NE to the present position at Subathu and Morni in pre-Thanetian time. There is no direct evidence to constrain the age of the thrusting.In view of regional regression in Late Cambrian, a distinct angular unconformity between the Cambrian and the overlying Ordovician, Early Paleozoic metamorphism and extensive development of Early Paleozoic granites and their rapid exhumation, a Late Cambrian age is suggested for the DTS thrusting. Not only the direction of movement of the DTS is same as that of the Tertiary thrust sheets but also Cambrian folds are co-axial with the Tertiary folds. This strange coincidence shows that similar kinematic field existed during two tectonic events. A ridge, like the present Central Crystalline Axis, was elevated between the Tethyan and Lesser Himalayan basins, which contributed zircons of the Early Cambrian age to both basins. 相似文献
Recent advances in our understanding of palaeovalleys are largely guided by examples from passive margins, in which accommodation increases down depositional dip. This study tests these models against a dataset from the Pennsylvanian Breathitt Group of the central Appalachian foreland basin, USA. This fluvio‐deltaic succession contains extensive erosionally based fluvio‐estuarine sand bodies that can be tracked over 80 km down depositional dip from a proximal zone of high accommodation close to the orogenic margin to a distal, lower accommodation zone close to the cratonic margin of the basin. The sand bodies are up to 25 m thick, multi‐storey and characterized in their lower parts by strongly amalgamated storeys containing sandy fluvial to estuarine bar accretion elements, and in their middle to upper parts by more fully preserved storeys up to 10 m thick and laterally extensive over 100s of metres. The upper storeys include abandonment channel‐fills of heterolithic marine or marginal marine deposits or muddy to sandy point‐bar elements. Three major regional‐scale architectures include: (i) Tabular sand bodies that everywhere incise open marine prodelta and mouth bar facies and are interpreted as palaeovalleys formed during falling stage and lowstand systems tracts, when eustatic sea‐level fall outpaced tectonic subsidence across the entire study area. (ii) Sand bodies that incise genetically related floodplain lake and/or bay‐fill minor mouth bar deposits up depositional dip and open marine prodelta and mouth bar facies down dip. These stacked distributary channel deposits map down dip into palaeovalleys and formed when up dip subsidence rate resulted in positive, but reduced rate of accommodation creation, while lower tectonic subsidence rate down‐dip resulted in incision. (iii) Sand bodies that incise genetically related floodplain, lake and/or bay‐fill minor mouth bars up dip and pass down‐dip into genetically related unconfined floodplain, prodelta and mouth bar deposits. These sand bodies represent stacked distributary channel fills and channel amalgamation was the product of high rates of lateral migration, typical of the behaviour of channels above their backwater reach. Case (2) sand bodies demonstrate that in rapidly subsiding foreland basins, cross‐shelf palaeovalleys may form down depositional dip from aggradational, distributive fluival strata. Additionally, the genetic relationship between stacked distributary channels and palaeovalleys supports recent models for palaeovalley formation that emphasize diachronous, cut‐and‐fill during falling stage and lowstands of relative sea level. 相似文献
Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment of 29 km2 of land with Ni concentrations exceeding the Canadian Ministry of the Environment’s remedial action level of 200 mg kg−1. Several studies on these soils have shown that making the soils calcareous was effective at reducing chemically extractable Ni, as well as alleviating Ni phytotoxicity symptoms in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic limestone additions resulted in increased uptake of Ni in the Ni hyperaccumulator Alyssum murale ‘Kotodesh’, a plant whose use was proposed as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil type and lime treatments play in altering the speciation of Ni in the Welland loam and Quarry muck soils around the refinery and relate these findings to Ni mobility and bioavailability.Stirred-flow dissolution experiments using pH 4 HNO3 showed that Ni release from the limed Quarry muck and Welland loam soils was reduced (∼0.10%) relative to the unlimed soils (∼2.0%). Electron microprobe analysis (EMPA) identified approximately spherical NiO and Ni metal particles, which are associated with no other metals, and range from 5 to 50 μm in diameter. Synchrotron micro-X-ray absorption fine structure and X-ray fluorescence spectroscopies showed that Ni and Al layered double hydroxide (Ni-Al LDH) phases were present in both the limed and unlimed mineral soils, with a tendency towards more stable (e.g., aged-LDH and phyllosilicate) Ni species in the limed soil, possibly aided by the solubilization of Si with increasing pH. In the muck soils, Ni-organic complexes (namely fulvic acid) dominated the speciation in both limed and unlimed soils.The results reported herein show that both soil type and treatment have a pronounced effect on the speciation of Ni in the soils surrounding the Port Colborne refinery. We provide the first evidence that Ni-Al LDH phases can form in anthropogenically enriched mineral field soils at circumneutral pH, and can lead to a reduction in Ni mobility. In the organic soils Ni is strongly complexed by soil organic matter; a property enhanced with liming. Interestingly, increased accumulation of Ni by A. murale grown in the limed muck and loam soils indicates that the plant may be capable of removing Ni from those fractions typically considered unavailable to most plants. 相似文献
Black‐foot abalone, Haliotis iris, were sampled from two populations in warm northern waters, and from two in colder southern waters. Abalone muscle is characterised by high activity of the glycolytic pyruvate reductase enzyme, tauropine dehydrogenase (TDH). Adductor muscle TDH was profiled for thermostability and activity to test the hypothesis that the enzyme may show adaptation in titre or kinetic characteristics reflecting thermal habitat. Temperature dependency of the apparent Michaelis‐Menten constant of TDH for pyruvate (appKmpyr) suggested eurythermal enzyme behaviour below 20°C, and compromised function at the higher temperatures of northern populations occurring in the summer months. Thermostability profiles and enzyme activities suggest TDH expression does not differ significantly among populations (P > 0.05), indicating that this locus shows no compensation for temperature. The optimal temperature for efficient TDH function, estimated from Vmax./appKmpyr, is close to 20°C. The possible thermal constraints on glycolytic metabolism in H. iris are discussed. 相似文献
The Grès de Champsaur turbidite system, deposited in a distal setting in the Alpine Foreland Basin of south‐eastern France, exhibits a repeated upsection alternation in sand body geometry between incised channels and sheet sands. The channels form symmetric lenticular erosional features, of width 900–1000 m (measured between the lateral limits of incision) and depth 65–115 m, and can be traced axially for up to 5 km. In each case, the channel fill is capped by a laterally persistent sandy sheet‐form interval, which lies upon a fine‐grained substrate beyond the channel margins. No intrachannel elements have been traced into the substrate sequence, suggesting that, before infill, the channels acted as open sea‐floor conduits of essentially the same dimensions as the preserved channel deposits. The channels are vertically stacked, although axial erosion juxtaposes younger channel axis deposits against the fill of older channels and their channel‐capping sheet sandstones to produce an apparently well‐connected composite sandstone body geometry. The predominant channel‐fill facies comprises coarse‐grained, amalgamated sandstones, which are commonly parallel‐ or cross‐stratified. Subsidiary facies of finer grained sandstone–mudstone couplets and clast‐bearing muddy debrites are commonly preserved as erosional remnants, suggesting a complex channel history of aggradation and erosion. The repeated cycles of channel incision, infill and transition to sheet sandstone development indicate repetitive incision and healing of the palaeo‐sea floor. A model is proposed that links incision to the development of relatively steep axial gradients (parallel to the mean dispersal direction) and the return to sheet‐form deposition to the re‐establishment of lower axial gradients, with the repetitive switch between incisional channels and sheet sandstones driven by changes in sediment input rate against a background of ongoing sea‐floor tilting. 相似文献
Submarine external levées are constructional features that develop outside slope channel systems, and are a volumetrically significant component of continental margins. However, detailed observations of their process sedimentology and depositional architecture are rare. Extensive exposures of external levées at multiple stratigraphic intervals and well‐constrained palaeogeographic positions in the Fort Brown Formation, Karoo Basin, South Africa, have been calibrated with research boreholes. This integrated data set permits their origin, evolution and anatomy to be considered, including high‐resolution analysis of sedimentary facies distribution and characterization of depositional sub‐environments. An idealized model of the stratigraphic evolution and depositional architecture of external levées is presented, and variations can be attributed to allogenic (for example, sediment supply) and autogenic (for example, channel migration) factors. Initiation of external levée construction is commonly marked by deposition of a basal sand‐rich facies with sedimentary structures indicating rapid deposition from unconfined flows. These deposits are interpreted as frontal lobes. Propagation of the parent channel, and resultant flow confinement, lead to partial erosion of the frontal lobe and development of constructional relief (levées) by flow overspill and flow stripping. Overall fining‐upwards and thinning‐upwards profiles reflect increased flow confinement and/or waning flow magnitude through time. Identification of a hierarchy of levée elements is not possible due to the absence of internal bounding surfaces or sharp facies changes. The down‐slope taper in levée height and increasing channel sinuosity results in increasing numbers of crevasse lobe deposits, and is reflected by the increased occurrences of channel avulsion events down‐dip. External levées from the Fort Brown Formation are silt‐rich; however their stratigraphic evolution and the distribution of many components (such as sediment waves and crevasse lobe) share commonalities with mud‐rich external levées. This unique integrated data set has permitted the first high‐resolution characterization of external submarine levée systems. 相似文献
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