The supergene origin of ruthenian hexaferrum in Ni‐laterites          下载免费PDF全文

Thomas Aiglsperger  Joaquín A. Proenza  Salvador Galí  Jordi Rius  Francisco Longo  Cristina Domènech 《地学学报》2017,29(2):106-116

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.  相似文献   

Can we learn from the past? Four hundred years of changes in adaptation to floods and droughts. Measuring the vulnerability in two Hispanic cities   总被引：2，自引：0，他引：2  

Salvador Gil-Guirado  José-Antonio Espín-Sánchez  María Del Rosario Prieto 《Climatic change》2016,139(2):183-200

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Bioerosion and encrustation rates in recent mollusk death assemblages on a supratidal siliciclastic setting,Playa Norte,Veracruz State,Mexico     

Catalina Gómez-Espinosa  F. Raúl Gío-Argáez  Ester A. Farinati  Salvador Aliotta  Sergio Adrian Salgado-Souto 《Arabian Journal of Geosciences》2018,11(8):188

This study presents both qualitative and quantitative data regarding marine mollusk (gastropods and bivalves) shell bioerosion and encrustation based on death assemblages obtained from a recent supratidal environment in Playa Norte, Veracruz State. The objectives of this study were to assess the nature of bioerosion and encrustation processes and to investigate the role of these taphonomic features contributing to the deterioration of natural shell accumulations within a tropical siliciclastic tidal environment. The assemblage comprises 31 species: 13 gastropods and 18 bivalves. The bioerosion and encrustation degrees were low to moderate for both types. The most abundant traces were predatory gastropod structures (Oichnus paraboloides and O. simplex), whereas sponge borings (Entobia isp.), polychaete dwellings (Caulostrepsis taeniola), and echinoid raspings (Gnatichnus isp.) were less frequent. The encrusting organisms include polychaete serpulids, bryozoans, and rare foraminifers (Homotrema rubrum). Because of the low bioerosion and encrustation degrees occurring in this area, accumulation is expected to predominate over biotic destruction. As deposition conditions (richly fossiliferous carbonate sandstone beds) were similar to those prevailing in the Tuxpan Formation during the Miocene (Langhian), it is suggested that this study provides an equivalent reference to interpret mollusk fossil assemblages located in this site.  相似文献   

Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)   总被引：1，自引：0，他引：1  

M. Angeles García Del Cura  Jose P. Calvo  Salvador Ordóñez  Blair F. Jones  & Juan C. Cañaveras 《Sedimentology》2001,48(4):897-915

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.  相似文献   

Analyzing ice dynamics using Sentinel-1 data at the Solheimajoküll Glacier,Iceland     

Diego Gómez  Pablo Salvador  Julia Sanz  Mikhail Urbazaev  José Luis Casanova 《地理信息系统科学与遥感》2020,57(6):813-829

ABSTRACT

The climate in southern Iceland has warmed over the last 70 years, resulting in accelerated glacier dynamics at the Solheimajoküll glacier. In this study, we compare glacier terminus locations from 1973 to 2018, to changes in climate across the study area, and we derive ice-surface velocities (2015–2018) from satellite remote-sensing imagery (Sentinel-1) using the offset-tracking method. There have been two regional temperature trends in the study period: cooling (1973–1979) and warming (1980–2018). Our results indicate a time lag of about 20 years between the onset of glacier retreat (?53 m/year since 2000) and the inception of the warming period. Seasonally, the velocity time series suggest acceleration during the summer melt season since 2016, whereas glacier velocities during accumulation months were constant. The highest velocities were observed at high elevations where the ice-surface slope is the steepest. We tested several scenarios to assess the hydrological time response to glacier accelerations, with the highest correlations being found between one and 30 days after the velocity estimates. Monthly correlation analyses indicated inter-annual and intra-annual variability in the glacier dynamics. Additionally, we investigate the linkage between glacier velocities and meltwater outflow parameters as they provide useful information about internal processes in the glacier. Velocity estimates positively correlate with water level and negatively correlate with water conductivity between April and August. There is also a disruption in the correlation trend between water conductivity and ice velocity in June, potentially due to a seasonal release of geothermal water.  相似文献   

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico   总被引：1，自引：0，他引：1  

Huerta-Diaz MA  Delgadillo-Hinojosa F  Hernández-Ayón M  Segovia-Zavala JA  García-Esquivel Z  López-Zárate H  Siqueiros-Valencia A  Galindo-Bect S 《Marine environmental research》2008,66(3):345-358

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.  相似文献   

Labour and residential accessibility: a Bayesian analysis based on Poisson gravity models with spatial effects   总被引：1，自引：1，他引：0  

M. P. Alonso  M. A. Beamonte  P. Gargallo  M. J. Salvador 《Journal of Geographical Systems》2014,16(4):409-439

In this study, we measure jointly the labour and the residential accessibility of a basic spatial unit using a Bayesian Poisson gravity model with spatial effects. The accessibility measures are broken down into two components: the attractiveness component, which is related to its socio-economic and demographic characteristics, and the impedance component, which reflects the ease of communication within and between basic spatial units. For illustration purposes, the methodology is applied to a data set containing information about commuters from the Spanish region of Aragón. We identify the areas with better labour and residential accessibility, and we also analyse the attractiveness and the impedance components of a set of chosen localities which allows us to better understand their mobility patterns.  相似文献   

MSC certification in Argentina: Stakeholders’ perceptions and lessons learned     

Mónica Pérez-Ramírez  Salvador Lluch-Cota  Mario Lasta 《Marine Policy》2012

Marine Stewardship Council (MSC) certification is a market-based incentive program recognizing well-managed fisheries. Currently, four Argentine fisheries are involved in the MSC program. Using in-depth, semi-structured interviews with fishery stakeholders, the study surveys their perceptions regarding MSC certification. MSC certification is positively perceived because stakeholders focus on knowledge of the process. Most respondents consider certification as encouraging effective fishery stakeholders’ participation: access to information, increased communication, and reaching consensus. Market/political/social realities will prove whether a more intense participation of Argentine fisheries in the certification initiative is useful. Because some markets in the EU and USA are demanding MSC certified products, there is a need to work towards a governance structure that helps link certification with policy market outcomes to ensure exportation of Argentine fish. MSC certification may suggest improved management of participatory bottom-up planning. This bottom-up approach provides an opportunity to establish feedback mechanisms and organizational changes.  相似文献   

Shaking‐table tests of flat‐bottom circular silos containing grain‐like material          下载免费PDF全文

Stefano Silvestri  Salvador Ivorra  Laura Di Chiacchio  Tomaso Trombetti  Dora Foti  Giada Gasparini  Luca Pieraccini  Matt Dietz  Colin Taylor 《地震工程与结构动力学》2016,45(1):69-89

According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Uvaichnites riojana: A new crane-like bird ichnotaxon from the lower Miocene of La Rioja (Ebro Basin,Spain)     

Ignacio Díaz-Martínez  José María Hernández  Salvador García Fernández  Xabier Murelaga  Félix Pérez-Lorente 《Proceedings of the Geologists' Association. Geologists' Association》2012,123(3):464-470

A new bird ichnotaxon found in Cenicero (La Rioja, Ebro Basin, Spain) is described here. The footprints are preserved in sandstone beds in a central-distal alluvial fringe with a mud-dominated floodplain, located in the transition unit between the Nájera and Haro formations. This level is positioned between the Y and Z local Agenian biozones (lower Miocene). The footprints were preliminarily studied in another work and considered as an indeterminate ichnotaxon. Uvaichnites riojana ichnogen. nov. and ichnosp. nov. is a tridactyl footprint characterized by a prominent central pad, very large to enormous sized, with unjointed toes at the proximal end. These features differ from Aquatilavipes, Aviadactyla, Avipeda, Ludicharadripodiscus, Fuscinapeda, and Ornithotarnocia of the Avipedidae morphofamily. U. riojana is considered to be similar to common crane (Grus grus) footprints in the Gruidae family. There are a few references about this family in the Iberian Peninsula and Balearic Islands and this find could confirm the presence of Gruidae since at least the lower Miocene.  相似文献