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1.
One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.  相似文献   
2.
The effect of nonlinearities, such as wave-breaking and vertical asymmetry associated with sea waves, on the distribution of wave amplitudes is explored. Semiclosed theoretical expressions are derived to describe the distributions of breaking-limited crest and trough amplitudes for Stokes-type nonlinear sea waves. These are compared with the conventional Rayleigh distribution appropriate to linear wave amplitudes. The construction of nonlinear wave envelopes with the fast Fourier transform technique is described. The technique can be utilized to enlarge the data base in empirical analyses of field records which typically contain limited information on amplitude characteristics. The theoretical distributions and the proposed data enlargement technique are demonstrated with the analysis of a nonlinear wave record.  相似文献   
3.
The statistical distribution of the crest-to-trough heights of narrowband nonlinear sea waves is derived in a semi-closed form. A quantitative comparison of the resulting density and exceedance probability distributions with those of the linear theory is given. It is shown that the nonlinearity of waves, even with steepnesses typical of extreme sea states, has an insignificant influence on the distribution of crest-to-trough heights.  相似文献   
4.
Statistics of nonlinear wave crests and groups   总被引:1,自引:0,他引:1  
M. Aziz Tayfun   《Ocean Engineering》2006,33(11-12):1589-1622
Groups of large nonlinear waves with sharper higher crests can pose hazards to ships, induce harbor resonance and cause wave-overtopping of fixed and floating structures. Past interest in wave groups has mostly been focused on the statistics and modeling of linear wave groups. Studies on nonlinear wave groups are surprisingly few, and address deep water waves only. Here, statistics of nonlinear wave crests and wave-crest groups in deep and transitional water depths are considered, using an appropriate second-order representation for crest heights and the continuous wave-envelope approach. In particular, theoretical expressions describing the statistics of nonlinear wave crests and their groups are posed in the form of a simple second-order transformation of well-known results on linear waves. Predictions from the transformation so posed compare well with nonlinear wave data gathered in the North Sea, and demonstrate that nonlinearities do affect the statistics of large wave crests and their groups significantly.  相似文献   
5.
The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture, gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite, which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O18 content ranges from 1.45 to 8.38% PDB and the C13 content ranges from −1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted conditions were provided by the development of beach barriers.  相似文献   
6.
The determination of the optimal type and placement of a nonconventional well in a heterogeneous reservoir represents a challenging optimization problem. This determination is significantly more complicated if uncertainty in the reservoir geology is included in the optimization. In this study, a genetic algorithm is applied to optimize the deployment of nonconventional wells. Geological uncertainty is accounted for by optimizing over multiple reservoir models (realizations) subject to a prescribed risk attitude. To reduce the excessive computational requirements of the base method, a new statistical proxy (which provides fast estimates of the objective function) based on cluster analysis is introduced into the optimization process. This proxy provides an estimate of the cumulative distribution function (CDF) of the scenario performance, which enables the quantification of proxy uncertainty. Knowledge of the proxy-based performance estimate in conjunction with the proxy CDF enables the systematic selection of the most appropriate scenarios for full simulation. Application of the overall method for the optimization of monobore and dual-lateral well placement demonstrates the performance of the hybrid optimization procedure. Specifically, it is shown that by simulating only 10% or 20% of the scenarios (as determined by application of the proxy), optimization results very close to those achieved by simulating all cases are obtained.  相似文献   
7.
The impact of Southern Oscillation on thecyclogenesis over the Bay of Bengal duringthe summer monsoon has been investigated.The analysis of correlation coefficients(CCs) between the frequency of monsoondepressions and the Southern OscillationIndex (SOI) reveals that more depressionsform during July and August of El Niñoyears. Due to this, the seasonal frequencyof monsoon depressions remains little higherduring El Niño epochs even though thecorrelations for June and September are notsignificant. The CCs for July and August aresignificant at the 99% level.The El Niño-Southern Oscillation (ENSO)is known to affect Indian MonsoonRainfall (IMR) adversely. The enhancedcyclogenesis over the Bay of Bengal duringJuly and August is an impact of ENSO whichneeds to be examined closely. Increasedcyclogenesis over the Bay of Bengal may bereducing the deficiency in IMR duringEl Niño years by producing more rainfallover the eastern parts of India duringJuly and August. Thus there is a considerablespatial variation in the impact of ENSOon the monsoon rainfall over India and El Niñoneed not necessarily imply a monsoonfailure everywhere in India.The area of formation of monsoon depressionsshifts eastward during El Niño years.Warmer sea surface temperature (SST) anomaliesprevail over northwest and adjoiningwestcentral Bay of Bengal during premonsoon andmonsoon seasons of El Niño years.May minus March SOI can provide useful predictionsof monsoon depression frequencyduring July and August.  相似文献   
8.
ABSTRACT The Alkyonides half‐graben is separated from the Gerania Range to the south by active faults whose offshore traces are mapped in detail. The East Alkyonides and Psatha Faults have well‐defined, Holocene‐active tip zones and cannot be extrapolated from the onshore Skinos Fault into a single continuous surface trace. During the late Quaternary, catchments draining the step‐faulted range front have supplied sediment to alluvial fans along a subsiding marine ramp margin in the hangingwall of the Skinos Fault, to shelf ledge fans on the uplifting footwall to the East Alkyonides Fault and to the Alepochori submarine fan in the hangingwall of the latter. During late Pleistocene lowstand times (c. 70–12 ka), sediment was deposited in Lake Corinth as fan deltas on the subsiding Skinos shelf ramp which acted as a sediment trap for the adjacent 360 m deep submarine basin plain. At the same time, the uplifting eastern shelf ledge was exposed, eroded and bypassed in favour of deposition on the Alepochori submarine fan. During Holocene times, the Skinos bajada was first the site of stability and soil formation, and then of substantial deposition before modern marine erosion cut a prominent cliffline. The uplifting eastern shelf ledge has developed substantial Holocene fan lobe depositional sequences as sediment‐laden underflows have traversed it via outlet channels. We estimate mean Holocene displacement rates towards the tip of the Psatha Fault in the range 0.7–0.8 mm year?1. Raised Holocene coastal notches indicate that this may be further partitioned into about 0.2 mm year?1 of footwall uplift and hence 0.5–0.6 mm year?1 of hangingwall subsidence. Holocene displacement rates towards the tip of the active East Alkyonides Fault are in the range 0.2–0.3 mm year?1. Any uplift of the West Alkyonides Fault footwall is not keeping pace with subsidence of the Skinos Fault hangingwall, as revealed by lowstand shelf fan deltas which show internal clinoforms indicative of aggradational deposition in response to relative base‐level rise due to active hangingwall subsidence along the Skinos Fault. Total subsidence here during the last 58 kyr lowstand interval of Lake Corinth was some 20 m, indicating a reduced net displacement rate compared to estimates of late Holocene (< 2000 bp ) activity from onshore palaeoseismology. This discrepancy may be due to the competition between uplift on the West Alkyonides Fault and subsidence on the onshore Skinos Fault, or may reflect unsteady rates of Skinos Fault displacement over tens of thousands of years.  相似文献   
9.
Tariq A. Khan   《Limnologica》2003,33(4):327-339
Major biological parameters of four permanent (Lake Colac, Modewarre, Bolac and Tooliorook), shallow and slightly saline lakes in the volcanic plains of western Victoria, Australia recorded bi-monthly between November 1999–September 2001 are described. Chlorophyll a concentration ranged from 3–29 μg l−1 with peaks in autumn. Phytoplankton taxa recorded were diverse, with Chlorophyta and Bacillariophyta being common. Cyanobacterial blooms were recorded mostly in summer. Zooplankton abundance in the lakes ranged from 12–368 individuals per litre. Rotifera dominated Lake Bolac, Copepoda dominated Lake Modewarre and they co-dominated Lake Colac and Tooliorook. Zooplankton interactions with phytoplankton suggest that simple predator-prey relationships cannot fully explain the trends exhibited and that a more complex model was acting to regulate algal biomass. A decline in the abundance of zooplankton in summer in Lake Modewarre was attributed to predation by high number of exotic larval carp at that time of the year. A total of 25 benthic macroinvertebrate taxa were recorded from Lake Colac, 30 from Modewarre, 22 from Bolac and 35 from Tooliorook. Twenty-one of the 45 taxa identified occurred in at least three lakes. Nine of the 12 taxa that occurred in only one lake were from Lake Tooliorook. Simpson's diversity index was low in Lake Bolac when compared to other three lakes. Lake Modewarre had more benthic individuals (3246 Ind m−2) than other three lakes (range 624–1397 Ind m−2). The combined contribution of Ostracoda, Amphipoda and Gastropoda dominated the benthos in all the lakes throughout the study period. Macroinvertebrate taxa richness was higher in the present study lakes than recorded from the lakes in the region. Frequency of sampling and number of sampling sites seemed more important in determining species richness than the size and shallowness of the lakes.  相似文献   
10.
Indirect nitrous oxide (N2O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N2O emissions from soils. In this study, dissolved N2O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N2O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N2O emissions to the atmosphere. Soil texture was found to significantly influence field drain N2O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L?1) being greater than drains in sandy loam soils (4.0 μg N L?1). Soil texture also impacted upon the relationships between field drain N2O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO3) and nitrite (NO2) concentrations), highlighting possible differences in N2O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N2O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N2O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N2O concentrations, whereas higher N2O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N2O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.  相似文献   
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