In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

A new method for specular and diffuse pseudorange multipath error extraction using wavelet analysis     

Giovanni?Pugliano  Umberto?RobustelliEmail authorView author&#;s OrcID profile  Fabio?Rossi  Raffaele?Santamaria 《GPS Solutions》2016,20(3):499-508

Multipath remains one of the major challenges in Global Navigation Satellite System (GNSS) positioning because it is considered the dominant source of ranging errors, which can be classified into specular and diffuse types. We present a new method using wavelets to extract the pseudorange multipath in the time domain and breaking it down into the two components. The main idea is an analysis-reconstruction approach based on application of both continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The proposed procedure involves the use of L1 code-minus-carrier (CMC) observable where higher-frequency terms are isolated as residuals. CMC residuals are analyzed by applying the CWT, and we propose the scalogram as a technique for discerning time–frequency variations of the multipath signal. Unlike Fourier transform, the potential of the CWT scalogram for examining the non-stationary and multifrequency nature of the multipath is confirmed as it simultaneously allows fine detection and time localization of the most representative frequencies of the signal. This interpretation of the CWT scalogram is relevant when choosing the levels of reconstruction with DWT, allowing accurate time domain extraction of both the specular and diffuse multipath. The performance and robustness of the method and its boundary applicability are assessed. The experiment was carried out using a receiver of Campania GNSS Network. The results are given in which specular multipath error is achieved using DWT level 7 approximation component and diffuse multipath error is achieved using DWT level 6 denoised detail component.  相似文献   

Sodium beacon tip–tilt determination with Rayleigh-aided auxiliary telescope technique     

S. Esposito  A. Riccardi  & R. Ragazzoni 《Monthly notices of the Royal Astronomical Society》1998,294(3):489-493

The usefulness of tracking the Rayleigh portion of a mesospheric sodium laser guide star as reference for absolute tip–tilt recovery in the frame of the auxiliary telescopes technique is shown. This approach leads to the reduction of the ground occupation needed to attain a given sky coverage by more than one order of magnitude. Speed, tracking precision, and the number of auxiliary telescopes are also reduced, making this new approach a more attractive one. The use of a low-altitude Rayleigh spot reinforces the fundamental limitations affecting this and other techniques, thus degrading significantly the quality of the recovered tip–tilt. However, it is shown that, provided adequate care is taken in the collection and treatment of data, an interesting tilt signal can still be retrieved.  相似文献   

Reconnaissance geochronology of basement rocks from the Amazonas and Maranhão Basins in Brazil     

Adam Kovach  Harold W. Fairbairn  Patrick M. Hurley  Miguel A.S. Basei  Umberto G. Cordani 《Precambrian Research》1976,3(5):471-480

Rb/Sr whole rock as well as K/Ar whole rock and mineral age determinations have been carried out on drill core samples obtained from the crystalline basement underlying the Amazonas and Maranhão Basins in Brazil. The data confirm the existence of an ancient basement under the Upper and Middle Amazonas Basin. The primary age of the granitic rocks is estimated at about 1560 Ma which correlates with recent age data obtained on granitic rocks on both sides of the Amazonas syneclise. In some areas the K/Ar ages show a decrease probably due to the effect of the Nickerie thermal episode described previously in the Guayana Shield.In the basement of the interconnected Lower Amazonas and Maranhão Basins Late Precambrian (Caririan) metamorphism and igneous activity seems to have been pervasive. The data allow the continuation of the Brazilian age province known in northeastern Brazil under the Maranhão Basin, linking this province to the Brasilia-Paraguay orogenic belt of similar age.  相似文献   

Considerazioni chimiche e chimico-fisiche sui gas vulcanici e magmatici     

Prof. Umberto Sborgi 《Bulletin of Volcanology》1939,5(1):109-131

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Contribution of SHRIMP U–Pb zircon geochronology to unravelling the evolution of Brazilian Neoproterozoic fold belts     

Miguel Angelo Stipp Basei  Benjamim Bley Brito Neves  Oswaldo Siga Junior  Marly Babinski  Marcio Martins Pimentel  Colombo Celso Gaeta Tassinari  Maria Helena Bezerra Hollanda  Allen Nutman  Umberto Giuseppe Cordani 《Precambrian Research》2010

The South-American continent is constituted of three major geologic–geotectonic entities: the homonym platform (consolidated at the end of the Cambrian), the Andean chain (essentially Meso-Cenozoic) and the Patagonian terrains, affected by tectonism and magmatism through almost all of the Phanerozoic. The platform is constituted by a series of cratonic nuclei (pre-Tonian, fragments of the Rodinia fission) surrounded by a complex fabric of Neoproterozoic structural provinces.  相似文献   

Sr and Nd isotopic geochemistry of the early ultramafic–mafic rocks of the Mako bimodal volcanic belt of the Kedougou–Kenieba inlier (Senegal)     

Papa Malick Ngom  Umberto G. Cordani  Wilson Teixeira  Valdecir de Assis Janasi 《Arabian Journal of Geosciences》2010,3(1):49-57

The Mako bimodal volcanic belt of the Kédougou–Kéniéba inlier is composed of volcanic basalts and peridotites interbedded by quartzites and limestones intruded by different generations of granitoïds. The early volcanic episode of the belt is constituted of submarine basalts with peridotite similar to those of the oceanic abyssal plains. It is intruded by the Badon Kakadian TTG?granitic batholite dated around 2200 Ma. The second volcanic phase is constituted of basaltic, andesitic, and felsitic flows exhibit structures of aerial volcanic rocks. It is intruded by granites dated between 2160 and 2070 Ma. The general pattern of trace element variation of submarine volcanic rocks is consistent with those of basalts from oceanic plateaus which are the modern equivalent of the Archean greenstones belts. The Nd and Sr isotopic systematics typical of juvenile material indicates that the source of these igneous rocks is derived from a depleted mantle source. These results are consistent with the idea of a major accretion within the West African Craton occurring at about 2.1 Ga and corresponding to an important process of mantle–oceanic lithosphere differentiation.  相似文献   

Measuring persistence in time series of temperature anomalies     

Umberto Triacca  Antonello Pasini  Alessandro Attanasio 《Theoretical and Applied Climatology》2014,118(3):491-495

Studies on persistence are important for the clarification of statistical properties of the analyzed time series and for understanding the dynamics of the systems which create these series. In climatology, the analysis of the autocorrelation function has been the main tool to investigate the persistence of a time series. In this paper, we propose to use a more sophisticated econometric instrument. Using this tool, we obtain an estimate of the persistence in global land and ocean and hemispheric temperature time series.  相似文献   

The marine Jurassic of Argentina： a biostratigraphic framework     

Alberto C. Riccardi 《《幕》》2008,31(3):326-335

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Quantitative morphometric analysis of lakes using GIS: rectangularity R,ellipticity E,orientation O,and the rectangularity vs. ellipticity index,REi     

Umberto Lombardo 《制图学和地理信息科学》2013,40(4):340-347

Quantitative measures of polygon shapes and orientation are important elements of geospatial analysis. These kinds of measures are particularly valuable in the case of lakes, where shape and orientation patterns can help identifying the geomorphological agents behind lake formation and evolution. However, the lack of built-in tools in commercial geographic information system (GIS) software packages designed for this kind of analysis has meant that many researchers often must rely on tools and workarounds that are not always accurate. Here, an easy-to-use method to measure rectangularity R, ellipticity E, and orientation O is developed. In addition, a new rectangularity vs. ellipticity index, REi, is defined. Following a step-by-step process, it is shown how these measures and index can be easily calculated using a combination of GIS built-in functions. The identification of shapes and estimation of orientations performed by this method is applied to the case study of the geometric and oriented lakes of the Llanos de Moxos, in the Bolivian Amazon, where shape and orientation have been the two most important elements studied to infer possible formation mechanisms. It is shown that, thanks to these new indexes, shape and orientation patterns are unveiled, which would have been hard to identify otherwise.  相似文献