Muscovite dehydration melting: Reaction mechanisms,microstructures, and implications for anatexis     

Brendan Dyck  David J. Waters  Marc R. St-Onge  Mike P. Searle 《Journal of Metamorphic Geology》2020,38(1):29-52

Dehydration melting of muscovite in metasedimentary sequences is the initially dominant mechanism of granitic melt generation in orogenic hinterlands. In dry (vapour-absent) crust, muscovite reacts with quartz to produce K-feldspar, sillimanite, and monzogranitic melt. When water vapour is present in excess, sillimanite and melt are the primary products of muscovite breakdown, and any K-feldspar produced is due to melt crystallization. Here we document the reaction mechanisms that control nucleation and growth of K-feldspar, sillimanite, and silicate melt in the metamorphic core of the Himalaya, and outline the microstructural criteria used to distinguish peritectic K-feldspar from K-feldspar grains formed during melt crystallization. We have characterized four stages of microstructural evolution in selected psammitic and pelitic samples from the Langtang and Everest regions: (a) K-feldspar nucleates epitaxially on plagioclase while intergrowths of fibrolitic sillimanite and the remaining hydrous melt components replace muscovite. (b) In quartzofeldspathic domains, K-feldspar replaces plagioclase by K⁺–Na⁺ cation exchange, while melt and intergrowths of sillimanite+quartz form in the aluminous domains. (c) At 7–8 vol.% melt generation, the system evolves from a closed to open system and all phases coarsen by up to two orders of magnitude, resulting in large K-feldspar porphyroblasts. (d) Preferential crystallization of residual melt on K-feldspar porphyroblasts and coarsened quartz forms an augen gneiss texture with a monzogranitic-tonalitic matrix that contains intergrowths of sillimanite+tourmaline+muscovite+apatite. Initial poikiloblasts of peritectic K-feldspar trap fine-grained inclusions of quartz and biotite by replacement growth of matrix plagioclase. During subsequent coarsening, peritectic K-feldspar grains overgrow and trap fabric-aligned biotite, resulting in a core to rim coarsening of inclusion size. These microstructural criteria enable a mass balance of peritectic K-feldspar and sillimanite to constrain the amount of free H₂O present during muscovite dehydration. The resulting modal proportion of K-feldspar in the Himalayan metamorphic core requires vapour-absent conditions during muscovite dehydration melting and leucogranite formation, indicating that the generation of large volumes of granitic melts in orogenic belts is not necessarily contingent on an external source of fluids.  相似文献   

A geochronological and petrological study of anatectic paragneiss and associated granite dykes from the Day Nui Con Voi metamorphic core complex,North Vietnam: constraints on the timing of metamorphism within the Red River shear zone     

R. M. Palin  M. P. Searle  D. J. Waters  R. R. Parrish  N. M. W. Roberts  M. S. A. Horstwood  M.‐W. Yeh  S.‐L. Chung  T. T. Anh 《Journal of Metamorphic Geology》2013,31(4):359-387

The Red River shear zone (RRSZ) is a major left‐lateral strike‐slip shear zone, containing a ductilely deformed metamorphic core bounded by brittle strike‐slip and normal faults, which stretches for >1000 km from Tibet through Yunnan and North Vietnam to the South China Sea. The RRSZ exposes four high‐grade metamorphic core complexes along its length. Various lithologies from the southernmost core complex, the Day Nui Con Voi (DNCV), North Vietnam, provide new constraints on the tectonic and metamorphic evolution of this region prior to and following the initial India–Asia collision. Analysis of a weakly deformed anatectic paragneiss using P–T pseudosections constructed in the MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNCKFMASHTO) system provides prograde, peak and retrograde metamorphic conditions, and in situ U–Th–Pb geochronology of metamorphic monazite yields texturally controlled age constraints. Tertiary metamorphism and deformation, overprinting earlier Triassic metamorphism associated with the Indosinian orogeny and possible Cretaceous metamorphism, are characterized by peak metamorphic conditions of ~805 °C and ~8.5 kbar between c. 38 and 34 Ma. Exhumation occurred along a steep retrograde P–T path with final melt crystallizing at the solidus at ≥~5.5 kbar at ~790 °C. Further exhumation at ~640–700 °C and ~4–5 kbar at c. 31 Ma occurred at subsolidus conditions. U–Pb geochronological analysis of monazite from a strongly deformed pre‐kinematic granite dyke from the flank of the DNCV provides further evidence for exhumation at this time. Magmatic grains suggest initial emplacement at 66.0 ± 1.0 Ma prior to the India–Asia collision, whereas grains with metamorphic characteristics indicate later growth at 30.6 ± 0.4 Ma. Monazite grains from a cross‐cutting post‐kinematic dyke within the core of the DNCV antiform provide a minimum age constraint of 25.2 ± 1.4 Ma for the termination of fabric development. A separate and significant episode of monazite growth at c. 83–69 Ma is suggested to be the result of fluid‐assisted recrystallization following the emplacement of magmatic units.  相似文献   

The stratigraphical signature of the Anthropocene in England and its wider context     

Jan Zalasiewicz  Colin Waters  Mark Williams  David C. Aldridge  Ian P. Wilkinson 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(3):482-491

The Anthropocene deposits of England, here regarded as those formed after ～1950 CE, are now extensive, take various forms, and may be characterized and recognized by a number of stratigraphic signals, such as artificial radionuclides, pesticide residues, microplastics, enhanced fly ash levels, concrete fragments and a novel variety of ‘technofossils’ and neobiotic species. They include the uppermost parts of both ‘natural’ deposits such as the sediment layers formed in lakes and estuaries, and more directly human-made or human-influenced ones such as landfill deposits and the ‘artificial ground’ beneath urban areas and around major constructions. ‘Negative deposits’ include the worked areas of quarries and regions such as the English Fenland, where thick peat deposits have ablated to leave a strongly modified underlying landscape, and extend beneath into the subterranean realm as mine workings, metro systems and boreholes. The production of these is still rapidly increasing and evolving in character, while the early signs of global change, such as warming, sea level rise, and modifications to biotic assemblages, are beginning to further modify the emerging geology of this new phase of Earth history.  相似文献   

Contrasting perspectives on barriers to adaptation in Australian climate change policy     

Elissa Waters  Jon Barnett  Aedan Puleston 《Climatic change》2014,124(4):691-702

Barriers to adaptation have emerged as key concerns in climate change theory and practice, however there remains little consensus about which barriers are the most significant to different groups and how competing concerns may be addressed. We investigate the significance of different barriers to adaptation for governments, the private sector, and civil society in Australia through a systematic analysis of submissions to the Australian Productivity Commission’s inquiry into barriers to adaptation. Our results show that respondents prioritise barriers differently according to their respective sectors, and that there are competing concerns about which barriers should be addressed first. Nevertheless, some barriers are more persistent in the submissions than others, with governance and policy seen by most groups as being the major impediments to adaptation. We explain the implications of our analysis for adaptation politics and policy.  相似文献   

The 69-μm forsterite band as a dust temperature indicator     

J. E.Bowey  M. J.Barlow  F. J.Molster  A. M.Hofmeister  C.Lee  C.Tucker  T.Lim  P. A. R.Ade  L. B. F. M.Waters 《Monthly notices of the Royal Astronomical Society》2002,331(1):L1-L6

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PDRS and Shocks in S106 IR and CEP a East     

M.E. Van Den Ancker  P.R. Wesselius  A.G.G.M. Tielens  L.B.F.M. Waters 《Astrophysics and Space Science》1997,255(1-2):69-75

We present SWS grating scans of pure H2 rotational lines, as well as several infrared fine-structure lines for two embedded Young Stellar Objects, S106 IR and Cep A East. Excitation temperatures and masses were derived from the low-lying pure rotational levels of H2 and are 490 and 740 K and 0.04 and 0.007 M⊙ for S106 and Cep A, respectively. The observations were compared to theoretical models for PDRs and dissociative and non-dissociative shocks. The infrared spectrum of S106 IR is dominated by PDR emission while that of Cep A East has a large shock component. We suggest that the difference between these two objects could reflect an evolutionary trend. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Infrared Observations of High-Mass X-Ray Binaries     

L. Kaper  N.R. Trams  P. Barr  J.Th. Van Loon  L.B.F.M. Waters 《Astrophysics and Space Science》1997,255(1-2):199-204

We present the first results of our ISO program on High-Mass X-ray Binaries (HMXBs). Infrared photometry, obtained at different aspect angles of the systems, is used to investigate the massive star's disrupted stellar wind and the accretion flow towards the compact X-ray source. Scenarios for massive binary evolution predict that HMXBs receive a large kick velocity during the supernova explosion of the compact star's progenitor. One might, therefore, expect to observe wind bow shocks around these systems such as observed around many OB-runaway stars. Such a wind bow shock has recently been discovered around the system Vela X-1. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Ionized Outflows of Hot Stars     

F. Najarro  R.-P. Kudritzki  D.J. Hillier  H.J.G.L.M. Lamers  R.H.M. Voors  P.W. Morris  L.B.F.M. Waters 《Astrophysics and Space Science》1997,255(1-2):137-144

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Circumstellar Silicate Mineralogy     

A.G.G.M. Tielens  L.B.F.M. Waters  F.J. Molster  K. Justtanont 《Astrophysics and Space Science》1997,255(1-2):415-426

This paper reviews spectra obtained with the SWS on board of ISO of dust shells around O-rich objects. These spectra reveal the presence of many new emission features between 10 and 45 μm. These bands are generally much narrower than the well-known 10 and 20 μm silicates features. The strength of these features relative to the underlying broad continuum varies from source to source (≅ 5-50%). The 10 μm region shows evidence for the presence of Al2O3 grains. At longer wavelength, the spectra are dominated by features due to crystalline olivine and pyroxene. The exact peak position of these features shows that the emitting grains consist of the Mg-rich end-members of these minerals with an Fe-content of < 10%. The underlying continuum is attributed to amorphous silicate grains. These observations of aluminum-rich and magnesium-rich compounds compare well with the thermodynamic condensation sequence of minerals expected for O-rich outflows. The observations also imply that freeze out (ie., kinetics) of this condensation sequence at different temperatures is an important characteristic of dust formation in these objects. It is suggested that the absence of Fe-rich silicates is a natural consequence of the low temperature at which gaseous Fe reacts with Mg-rich silicates in these outflows, resulting in amorphous grains with little characterizing spectral detail. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Obscured AGB Stars in the LMC     

Jacco Th. Van Loon  Albert A. Zijlstra  Patricia A. Whitelock  M.A.T. Groenewegen  Cecile Loup  Peter Te Lintel Hekkert  Norman R. Trams  L.B.F.M. Waters 《Astrophysics and Space Science》1997,255(1-2):403-404

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