Distribution and Trophic Importance of Anthropogenic Nitrogen in Narragansett Bay: An Assessment Using Stable Isotopes     

Autumn Oczkowski  Scott Nixon  Kelly Henry  Peter DiMilla  Michael Pilson  Stephen Granger  Betty Buckley  Carol Thornber  Richard McKinney  Joaquin Chaves 《Estuaries and Coasts》2008,31(1):53-69

Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ¹⁵N) and carbon (δ¹³C). The δ¹⁵N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ¹⁵N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ¹⁵N values in macroalgae there reflected preferential uptake of ¹⁴N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ¹³C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ¹⁵N (13.2 ± 0.54‰ SD) and δ¹³C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ¹⁵N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.  相似文献   

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes     

Zachary Morgan  Yan Liang  Paul Hess 《Geochimica et cosmochimica acta》2006,70(13):3477-3491

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.  相似文献   

Web-Based interrogation of large-scale geophysical data sets from handheld devices     

Zachary A. Garbow  Gordon Erlebacher  David A. Yuen  John M. Boggs  Fabien W. Dubuffet 《Visual Geosciences》2003,8(1):1-20

This paper describes the issues related to using handheld devices to interrogate wirelessly large-scale geophysical data over the Web using a client–server configuration. A modification of our current Web-based data interrogation program addresses specifically the limitations of current handheld devices with wireless access, such as processor speed, screen size and resolution, memory, and network speeds. The system uses a combination of Java, Python, and C in order to run remotely from the handheld device, while incorporating the power and memory capacity of a large workstation server.  相似文献   

Oxygen isotope heterogeneity in chondrules from the Mokoia CV3 carbonaceous chondrite     

Rhian H Jones  Laurie A Leshin  Zachary D Sharp  Alan J Schilk 《Geochimica et cosmochimica acta》2004,68(16):3423-3438

We report a study of the oxygen isotope ratios of chondrules and their constituent mineral grains from the Mokoia, oxidized CV3 chondrite. Bulk oxygen isotope ratios of 23 individual chondrules were determined by laser ablation fluorination, and oxygen isotope ratios of individual grains, mostly olivine, were obtained in situ on polished mounts using secondary ion mass spectrometry (SIMS). Our results can be compared with data obtained previously for the oxidized CV3 chondrite, Allende. Bulk oxygen isotope ratios of Mokoia chondrules form an array on an oxygen three-isotope plot that is subparallel to, and slightly displaced from, the CCAM (carbonaceous chondrite anhydrous minerals) line. The best-fit line for all CV3 chondrite chondrules has a slope of 0.99, and is displaced significantly (by δ¹⁷O ∼ −2.5‰) from the Young and Russell slope-one line for unaltered calcium-aluminum-rich inclusion (CAI) minerals. Oxygen isotope ratios of many bulk CAIs also lie on the CV-chondrule line, which is the most relevant oxygen isotope array for most CV chondrite components. Bulk oxygen isotope ratios of most chondrules in Mokoia have δ¹⁸O values around 0‰, and olivine grains in these chondrules have similar oxygen isotope ratios to their bulk values. In general, it appears that chondrule mesostases have higher δ¹⁸O values than olivines in the same chondrules. Our bulk chondrule data spread to lower δ¹⁸O values than any ferromagnesian chondrules that have been measured previously. Two chondrules with the lowest bulk δ¹⁸O values (−7.5‰ and −11.7‰) contain olivine grains that display an extremely wide range of oxygen isotope ratios, down to δ¹⁷O, δ¹⁸O around -50‰ in one chondrule. In these chondrules, there are no apparent relict grains, and essentially no relationships between olivine compositions, which are homogeneous, and oxygen isotopic compositions of individual grains. Heterogeneity of oxygen isotope ratios within these chondrules may be the result of incorporation of relict grains from objects such as amoeboid olivine aggregates, followed by solid-state chemical diffusion without concomitant oxygen equilibration. Alternatively, oxygen isotope exchange between an ¹⁶O-rich precursor and an ¹⁶O-poor gas may have taken place during chondrule formation, and these chondrules may represent partially equilibrated systems in which isotopic heterogeneities became frozen into the crystallizing olivine grains. If this is the case, we can infer that the earliest nebular solids from which chondrules formed had δ¹⁷O and δ¹⁸O values around -50‰, similar to those observed in refractory inclusions.  相似文献   

Channel adjustments of the lower Trinity River,Texas, downstream of Livingston Dam     

Jonathan D. Phillips  Michael C. Slattery  Zachary A. Musselman 《地球表面变化过程与地形》2005,30(11):1419-1439

Channel cross‐sectional changes since construction of Livingston Dam and Lake Livingston in 1968 were studied in the lower Trinity River, Texas, to test theoretical models of channel adjustment, and to determine controls on the spatial extent of channel response. High and average flows were not significantly modified by the dam, but sediment transport is greatly reduced. The study is treated as an opportunistic experiment to examine the effects of a reduction in sediment supply when discharge regime is unchanged. Channel scour is evident for about 60 km downstream, and the general phenomena of incision, widening, coarsening of channel sediment and a decrease in channel slope are successfully predicted, in a qualitative sense, by standard models of channel response. However, there is no consistent channel response within this reach, as various qualitatively different combinations of increases, decreases or no change in width, depth, slope and roughness occur. These multiple modes of adjustment are predicted by the unstable hydraulic geometry model. Between about 60 km and the Trinity delta 175 km downstream of the dam, no morphological response to the dam is observed. Rather than a diminution of the dam's effects on fluvial processes, this is due to a fundamental change in controls of the fluvial system. The downstream end of the scour zone corresponds to the upstream extent of channel response to Holocene sea level rise. Beyond 60 km downstream, the Trinity River is characterized by extensive sediment storage and reduced conveyance capacity, so that even after dam construction sediment supply still exceeds transport capacity. The channel bed of much of this reach is near or below sea level, so that sea level rise and backwater effects from the estuary are more important controls on the fluvial system than upstream inputs. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Clustering and visualization of earthquake data in a grid environment     

Dave A.Yuen  Benjamin J. Kadlec  Evan F. Bollig  Witold Dzwinel  Zachary A. Garbow  Cesar R. S. da Silva 《Visual Geosciences》2005,10(1):1-12

We present a web client-server service WEB-IS, which we have developed for remote analysis and visualization of seismic data consisting of both small magnitude events and large earthquakes. We show that the problem-solving environment (PSE) intended for prediction of large magnitude earthquakes can be based on this WEB-IS idea. The clustering schemes, feature generation, feature extraction techniques and rendering algorithms form a computational framework of this environment. On the other hand, easy and fast access both to the seismic data distributed among distant computing resources and to computational and visualization resources can be realized in a GRID framework. We discuss the usefulness of NaradaBrokering (iNtegrated Asynchronous Real-time Adaptive Distributed Architecture) as a middleware, allowing for flexibility and high throughput for remote visualization of geophysical data. The WEB-IS functionality was tested both on synthetic and the actual earthquake catalogs. We consider the application of similar methodology for tsunami alerts.  相似文献   

What is the source of baseflow in agriculturally fragmented catchments? Complex groundwater/surface‐water interactions in three tributary catchments of the Wabash River,Indiana, USA          下载免费PDF全文

Marty D. Frisbee  Zachary P. Meyers  Noah S. Stewart‐Maddox  Marc W. Caffee  Philine Bogeholz  Madison N. Hughes 《水文研究》2017,31(22):4019-4038

Some conceptual models suggest that baseflow in agriculturally fragmented watersheds may contain little, if any, groundwater. This has critical implications for stream quality and ecosystem functioning. Here, we (a) identify the sources and flowpaths contributing to baseflow using ²²²Rn and ⁸⁷Sr/⁸⁶Sr and (b) quantify mean apparent ages of groundwater and baseflow using multiple isotopic tracers (CFC, SF₆, ³⁶Cl, and ³H) in 4 small (0.08 to 0.64 km²) tributary catchments to the Wabash River in Indiana, USA. ²²²Rn activities and ⁸⁷Sr/⁸⁶Sr ratios indicate that baseflow in 3 catchments is sourced primarily from groundwater; baseflow in the fourth is dominated by a source similar to agricultural run‐off. CFC‐12 data indicate that springs in 1 catchment are discharging significant proportions of water that recharged between 1974 (42 ± 2 years) and 1961 (55 ± 2 years). Those same springs have ³⁶Cl/Cl ratios between 1,381.08 ± 29.37 (×10^?15) and 1,530.64 ± 27.65 (×10^?15) indicating that a substantial proportion of the discharge likely recharged between 1975 (41 years) and 1950 (66 years). Groundwater samples collected from streambed mini‐piezometers in a separate catchment have CFC‐12 concentrations indicating that a large proportion of the recharge occurred between 1948 (68 ± 2 years) and 1950 (66 ± 2 years). Repeat sampling conducted in September 2015 after above‐average summer rainfall did not show significant decreases in mean apparent age. The relatively old ages observed in 3 of the catchments can be explained by geological complexities that are likely present in all 4 catchments, but overwhelmed by flow from the shallow phreatic aquifer in the fourth catchment.  相似文献   

A geospatial study of the drought impact on surface water reservoirs: study cases from Texas,USA     

Zachary Asbury 《地理信息系统科学与遥感》2019,56(6):894-910

Satellite images have been used historically to measure and monitor fluctuations in the surface water reservoirs. This study integrates remote sensing and Geographic Information System (GIS) technologies to investigate the impact of drought on 10 selected surface water reservoirs in San Angelo and Dallas, Texas. Oscillations in summer and winter months throughout the 2005–2016 period were assessed using multispectral images from Landsat-5, ?7, and ?8, and changes in the reservoirs were characterized and correlated against local climate data of each reservoir. For quantitative comparisons of the time-series measurements, a robust density slicing approach was employed to classify the range of values of the raster cells in the near-infrared band of Landsat images for each lake into three desired classes (deep water, shallow water, and dry area) based on the natural breaks inherent in the dataset. Statistical analysis shows that the overall accuracy of the classification is about 94%, which demonstrates the efficiency of the density slicer to accurately estimate surface water area changes from an individual Landsat band. Shrinkage in the surface water area over the study period reveals the concrete impact that the drought along with other factors have on the 10 selected lakes. The San Angelo lakes located in west central Texas experienced a nearly consistent pattern of change during most of the study period; whereas the Dallas lakes in northeast Texas followed the oscillating pattern of drought and correlated closely to the local conditions. Shockingly, the extreme drought caused complete vanishing of several lakes, and consequently Texas had to remove them from its recreational plans. Our new findings can certainly help with the water resource management in Texas and our study approach can be adapted for monitoring lake oscillations in other areas across the world. This geospatial study demonstrates the societal benefits from incorporating remote sensing and GIS in investigating geo-environmental problems associated with severe climate changes.  相似文献   

Testing block subdivision algorithms on block designs     

Natalie Wiseman  Zachary Patterson 《Journal of Geographical Systems》2016,18(1):17-43

Integrated land use–transportation models predict future transportation demand taking into account how households and firms arrange themselves partly as a function of the transportation system. Recent integrated models require parcels as inputs and produce household and employment predictions at the parcel scale. Block subdivision algorithms automatically generate parcel patterns within blocks. Evaluating block subdivision algorithms is done by way of generating parcels and comparing them to those in a parcel database. Three block subdivision algorithms are evaluated on how closely they reproduce parcels of different block types found in a parcel database from Montreal, Canada. While the authors who developed each of the algorithms have evaluated them, they have used their own metrics and block types to evaluate their own algorithms. This makes it difficult to compare their strengths and weaknesses. The contribution of this paper is in resolving this difficulty with the aim of finding a better algorithm suited to subdividing each block type. The proposed hypothesis is that given the different approaches that block subdivision algorithms take, it’s likely that different algorithms are better adapted to subdividing different block types. To test this, a standardized block type classification is used that consists of mutually exclusive and comprehensive categories. A statistical method is used for finding a better algorithm and the probability it will perform well for a given block type. Results suggest the oriented bounding box algorithm performs better for warped non-uniform sites, as well as gridiron and fragmented uniform sites. It also produces more similar parcel areas and widths. The Generalized Parcel Divider 1 algorithm performs better for gridiron non-uniform sites. The Straight Skeleton algorithm performs better for loop and lollipop networks as well as fragmented non-uniform and warped uniform sites. It also produces more similar parcel shapes and patterns.  相似文献   

<Emphasis Type="Italic">Deepwater Horizon</Emphasis> Oil Spill Impacts on Salt Marsh Fiddler Crabs (<Emphasis Type="Italic">Uca</Emphasis> spp.)     

Scott Zengel  Steven C. Pennings  Brian Silliman  Clay Montague  Jennifer Weaver  Donald R. Deis  Michelle O. Krasnec  Nicolle Rutherford  Zachary Nixon 《Estuaries and Coasts》2016,39(4):1154-1163

The Deepwater Horizon oil spill was the largest marine oil spill in US waters to date and one of the largest worldwide. Impacts of this spill on salt marsh vegetation have been well documented, although impacts on marsh macroinvertebrates have received less attention. To examine impacts of the oil spill on an important marsh invertebrate and ecosystem engineer, we conducted a meta-analysis on fiddler crabs (Uca spp.) using published sources and newly available Natural Resources Damage Assessment (NRDA) and Gulf of Mexico Research Initiative (GoMRI) data. Fiddler crabs influence marsh ecosystem structure and function through their burrowing and feeding activities and are key prey for a number of marsh and estuarine predators. We tested the hypothesis that the spill affected fiddler crab burrow density (crab abundance), burrow diameter (crab size), and crab species composition. Averaged across multiple studies, sites, and years, our synthesis revealed a negative effect of oiling on all three metrics. Burrow densities were reduced by 39 % in oiled sites, with impacts and incomplete recovery observed over 2010–2014. Burrow diameters were reduced from 2010 to 2011, but appeared to have recovered by 2012. Fiddler crab species composition was altered through at least 2013 and only returned to reference conditions where marsh vegetation recovered, via restoration planting in one case. Given the spatial and temporal extent of data analyzed, this synthesis provides compelling evidence that the Deepwater Horizon spill suppressed populations of fiddler crabs in oiled marshes, likely affecting other ecosystem attributes, including marsh productivity, marsh soil characteristics, and associated predators.  相似文献