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Carbonate rocks are important reservoirs for global petroleum exploration.The largest oilfield in the South China Sea,Liuhua 11-1,is distributed in the massive carbonate reef area of the Zhujiang(Pearl)River Mouth Basin.Previous studies showed that one 802.17-m-long core from well Xichen-1 in the South China Sea mainly consisted of white and light gray-white organic reefs.Recently,a Miocene whole core(161.9 m long)of well Xiyong-2,near well Xichen-1,was found to contain six layers of yellowish brown,light yellowish gray,iron black,or light yellowish gray-white organic reefs.Scanning electron microscope images of these layers reveal a typical ferroan dolomite rich in Fe(up to 29%),with the high concentrations of Mn,Cu,W,Zn,Cr,Ni,and Co.Systematic X-ray powder diffraction analysis yields a 1.9–6.1 match in phase ratio with ankerite,5.4–26.9 with dolomite,and zero with calcite,which indicate that the samples can be classified as ferroan dolomite.The iron and heavy metals are inferred to be originated from multiple volcanic eruptions of Gaojianshi Island in the Dongdao Atoll during the middle-late Miocene.These elements were dissolved in seawater,likely as a sol,and carried to Yongxing Island in the Xuande Atoll by sea currents and tides enhanced by prevailing winds,and deposited as a part of the sedimentation process in the study area.The ferroan dolomite has Sr content of (125–285)×10~(-6),which is lower than the accepted Sr boundary value of dolomite.This finding suggests that dolomitization occurred during large-scale global glacial regression in the late Miocene.The isolated Xisha carbonate platform,exposed to air,underwent freshwater leaching and dolomitization induced by mixed water,and caused the extensive Fe-Mg exchange along the organic reef profile to form ankerite and ferroan dolomite.These results may help to understand paleoceanographic environmental changes in the South China Sea during the Miocene. 相似文献
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Coastal seas,located between continents and the open ocean,are an important active carbon pool.The sedimentary total organic carbon(TOC)in these areas is a mixture of terrestrial and marine sources,and can be a powerful proxy for tracing natural processes and human activities.In this study,one fine-grained sediment core(DH5-1) from the inner shelf of the East China Sea was systematically analyzed for TOC and black carbon(BC) contents and TOC stable carbon isotope ratios(d13 C).By combining these data with 210~Pb dating,an improved carbon correction model and a two end-member mixing model,we reconstructed century-scale high-resolution sequences of corrected TOC,terrestrial TOC and marine TOC contents and identified two carbon depletion events in the DH5-1 record.The two events,shown as two minima in the TOC profiles,correspond temporally to 1985-1987 AD and 2003-2006 AD,which exactly matches the water impoundment of the Gezhouba Dam and Three Gorges Dam,respectively.In addition,the variations in TOC contents and δ~(13)C values before,during or after the minima demonstrate a relationship between the depletion events and water impoundment of the dams on the Changjiang River.The TOC reductions may represent synchronous responses of sedimentary TOC and resultant ecological ef fects on the inner shelf of the East China Sea to the water impoundment of the dams.These new TOC records reflect the interaction between natural and anthropogenic processes and,accordingly,provide a deep insight and important references for assessing marine ecological ef fects resulting from water impoundment of largescale dams. 相似文献
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青藏高原新生代形成演化的整合模型——来自火成岩的约束 总被引：28，自引：8，他引：28
深部过程是青藏高原演化的主导因素,其他地质过程都可以看作是对深部过程的响应。因此,一个构造旋回(阶段)的地球动力学事件链可以概括为深部地质过程—幔源岩浆活动—壳源岩浆活动—陆壳增厚—地表隆升—表层剥蚀与沉积,其中幔源岩浆活动的研究成为追索青藏高原演化历史的关键环节。据此,青藏高原演化的关键性时间坐标为80、45、27、17、9和4Ma。青藏高原新生代火成岩具有三种展布形式:与雅鲁藏布缝合带平行的岩浆带、沿深大断裂展布的岩浆带和藏北离散性岩浆分布区,它们分别受控于大陆碰撞、大规模走滑和岩石圈拆沉构造体制,且都受控于印度—亚洲软流圈汇聚过程。据此,文中提出了一个描述青藏高原演化的整合模型:南北向地幔对流汇聚控制了岩石圈块体的相对运动,并最终导致印度—亚洲大陆的碰撞和沿碰撞带的大规模岩浆活动;碰撞之初(白垩纪末期),大陆岩石圈块体的刚性属性有利于应力的远程传递和块体旋转,沿块体边界分布的大型走滑断裂控制了岩浆活动的发生;随着挤压过程的持续进行,岩石圈块体的受热和变形,高原岩石圈的重力不稳定性增加,最终导致拆沉作用和软流圈物质的大规模上涌以及藏北高原的离散性岩浆活动。在高原演化中,岩石圈拆沉作用具有重要意义,许多地质事件的发生都与此有关。同时,软流圈的汇聚还导致软流圈物质的向东挤出,并因此造成青藏高原岩石圈的向东挤出和晚新生代的伸展构造。 相似文献
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青藏东缘马关地幔岩包体的岩石学与矿物学研究 总被引：4，自引：1，他引：4
对青藏东缘新生代马关地区高钾岩系中地幔岩包体的岩石学和矿物化学成分的研究表明:马关地幔岩包体属尖晶石相橄榄岩,岩石类型主要为尖晶石二辉橄榄岩,矿物组合为橄榄石(O l) 斜方辉石(O px) 单斜辉石(Cpx) 尖晶石(Sp l),含极少量金云母和角闪石。橄榄石以贵橄榄石为主,部分为镁橄榄石,其Fo值为89.72~90.47,M g#值为89.75~90.51;斜方辉石的En分子为88.00~89.59,M g#值为90.21~91.16,C r#值为3.31~6.23;单斜辉石主要为透辉石,少量为顽透辉石,成分上表现为高C a(wC aO=18.71%~20.78%)、高A l(wA l2O3=6.00%~7.30%)、高M g#值(89.93~91.57)和低C r#值(5.13~8.74);尖晶石为铬尖晶石,其w(C r2O3)为7.62%~12.88%。矿物化学成分指示:马关尖晶石二辉橄榄岩包体属A型包体,为低度熔融后的大陆地幔橄榄岩。温压估算表明,马关尖晶石相二辉橄榄岩包体的平衡温压分别为900℃~1 150℃和1.29 GPa~2.20 GPa(相当于地下深度45 km~71 km),其上地幔地温曲线与大洋地温曲线一致,显示马关地区岩石圈地幔具有很高的热流值,暗示青藏东缘及邻区于0~16 M a期间有热的软流圈地幔上涌,地幔上涌在构造上的响应即是青藏东缘乃至整个东亚地区区域性岩石圈的东-西向伸展。 相似文献
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元古宙罗迪尼亚(Rodinia)泛大陆的重建研究 总被引：7，自引：0，他引：7
详细评述了罗迪尼亚泛大陆研究的新进展,表明罗迪尼亚泛大陆约存在于１０５～０７０Ｇａ期间,于０７０Ｇａ左右裂解。中国华南陆块在中元古代晚期的罗迪尼亚拼贴期间可能处于澳大利亚克拉通和劳亚（Ｌａｕｒｅｎｔｉａ）陆块之间。在０７０Ｇａ左右的罗迪尼亚泛大陆裂解时,中国华南陆块（包括扬子和江南古陆）从其它陆块上分离出来。华南陆块是连接澳大利亚东南极陆块和劳亚大陆的纽带。全球罗迪尼亚泛大陆的重建研究是自１９９１年以来在大陆增生和板块构造研究中的重大突破。正在执行中的中国科学院重大项目将为进一步修正和完善罗迪尼亚泛大陆假说提供科学佐证。 相似文献
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本文根据熔体聚合模型和正规溶液模型,建立了非平衡条件下,在二组分硅酸盐熔体固结过程中的非平衡非理想界面反应的非线性动力学模型:对上式进行数值模拟表明,当W/RT<-2时,有三重态,并通过建立界面状态(组成)的质量守恒方程,合理地说明了硅酸盐固溶体矿物韵律结构形成的可能机理之一,寻找界面反应三重态是研究固溶体矿物韵律结构的一条相当普遍的途径。 相似文献
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云南前寒武纪基底形成与变质时代及其成矿作用年代学研究 总被引：8，自引：0，他引：8
新的同位素年代学、岩石学与地球化学研究表明云南前寒武纪各岩群普遍由跨越古、中和新元古代不同时代的构造片岩组成。哀牢山群和瑶山群是相连接的同一地层单元 ,主体岩石形成于 130 0～ 16 0 0Ma。昆阳群下亚群泥质碳酸盐沉积岩Pb Pb等时年龄在 170 0～ 16 0 0Ma之间 ,上亚群大营盘组为 12 6 0Ma。苍山群的变拉斑系列形成于岛弧环境 ,其钕模式年龄值在 15 0 0～ 2 0 0 0Ma ,Sm Nd等时年龄近于为 16 5 0Ma ,εNd(t) =+ 7.4。形成于板内环境的碱性系列玄武岩 ,钕模式年龄值在 10 0 0～ 110 0Ma。苴林群变拉斑玄武岩钕模式年龄为 16 0 0～ 170 0Ma ,εNd(t) =+ 6 .6 ;变碱性玄武岩样品为 80 0～ 10 0 0Ma ,可与苍山群相比较。钕模式年龄和Pb同位素填图表明昆阳群与大红山群 ,苴林群与苍山群分别归属于扬子和印支块体的准同时地层。成矿年龄测定表明前寒武纪地层中成矿作用表现为 70 0～ 90 0Ma的改造成矿 ,与大规模从基性到酸性的岩浆活动密切相联系。90 0～ 10 0 0Ma板内环境碱性玄武岩的广泛出现 ,标致着大陆裂解的开始。晋宁期花岗岩活动从早期 (80 0～ 830Ma)的偏中酸性到晚期 (6 80～ 780Ma)的酸性 ,表明构造环境从拉张向挤压环境发展 ,体现了Rodinia超大陆形成、裂解到冈瓦纳大陆形成的过程 相似文献