Comparison of polycyclic aromatic hydrocarbon distributions and sedimentary organic matter characteristics in contaminated, coastal sediments from Pensacola Bay, Florida     

Simpson MJ  Chefetz B  Deshmukh AP  Hatcher PG 《Marine environmental research》2005,59(2):139-163

In this study, we examined the distribution of polycyclic aromatic hydrocarbons (PAHs) in a contaminated coastal area and the characteristics of the natural organic matter in tandem. We present a detailed study of PAH concentration, distribution, and organic matter characteristics of three core samples from Pensacola Bay, Florida. Solid-state 13C Nuclear Magnetic Resonance (NMR), pyrolysis gas chromatography coupled with mass spectrometry (GC-MS), and tetramethyl ammonium hydroxide (TMAH) thermochemolysis GC-MS were applied to obtain structural details about the sedimentary organic matter. Elemental compositions (carbon and nitrogen) and estimates of black carbon contents are also reported. These coastal sediments were found to contain more PAHs in the upper 15 cm layers than in the bottom 15-25 cm samples. The samples that contained the most PAHs also contained the least amount of aromatic carbon and contained a significant amount of paraffinic carbon. Lignin-derived pyrolysis and TMAH thermochemolysis products were abundant and generally higher in all of the samples in comparison to those reported for modern coastal sediments, indicating a large flux of terrestrial carbon. The black carbon contents were found to range from 4.3% to 6.8%, which are significantly lower than other reports of black carbon in sediments, which represent as much as 65% of the total organic carbon content. The low black carbon content suggests that this type of refractory carbon may not be as responsible for regulating PAH distribution as indicated by other researchers.  相似文献   

Hypsometric analysis of Shakkar river catchment through geographical information system   总被引：2，自引：0，他引：2  

Sarita Gajbhiye  S. K. Mishra  Ashish Pandey 《Journal of the Geological Society of India》2014,84(2):192-196

Hypsometric analysis of watershed (area-elevation analysis) has generally been used to reveal the stages of geomorphic development (stabilized, mature and young). The geologic stages of development and proneness of the watersheds for erosion are quantified by hypsometric integral. The estimation of hypsometric integral is carried out from the graphical plot of the measured contour elevation and encompassed area by using empirical formulae. In this study, efforts were made to estimate the hypsometric integral values of Shakkar river watershed which is a tributary of Narmada river located in Madhya Pradesh. The watershed was delineated into eight sub-watersheds and hypsometric analysis was carried out for all of them using digital contour maps, which was generated using Arc/Info GIS. The hypsometric integral values for all the sub-watersheds of Shakkar river ranges between 0.47 and 0.51. In the study area, only mature stage of erosion cycle is identified.  相似文献   

Correcting lateral boundary biases in regional climate modelling: the effect of the relaxation zone     

Rocheta  Eytan  Evans  Jason P.  Sharma  Ashish 《Climate Dynamics》2020,55(9-10):2511-2521

Climate Dynamics - Regional climate models (RCM) are an important tool for simulating atmospheric information at finer resolutions often of greater relevance to local scale climate change impact...  相似文献   

The Global Paleomonsoon as seen through speleothem records from Asia and the Americas   总被引：3，自引：0，他引：3  

Hai Cheng  Ashish Sinha  Xianfeng Wang  Francisco W. Cruz  R. Lawrence Edwards 《Climate Dynamics》2012,39(5):1045-1062

The regional monsoons of the world have long been viewed as seasonal atmospheric circulation reversal—analogous to a thermally-driven land-sea breeze on a continental scale. This conventional view of monsoons is now being integrated at a global scale and accordingly, a new paradigm has emerged which considers regional monsoons to be manifestations of global-scale seasonal changes in response to overturning of atmospheric circulation in the tropics and subtropics, and henceforth, interactive components of a singular Global Monsoon (GM) system. The paleoclimate community, however, tends to view ‘paleomonsoon’ (PM), largely in terms of regional circulation phenomena. In the past decade, many high-quality speleothem oxygen isotope (δ¹⁸O) records have been established from the Asian Monsoon and the South American Monsoon regions that primarily reflect changes in the integrated intensities of monsoons on orbital-to-decadal timescales. With the emergence of these high-resolution and absolute-dated records from both sides of the Equator, it is now possible to test a concept of the ‘Global-Paleo-Monsoon’ (GPM) on a wide-range of timescales. Here we present a comprehensive synthesis of globally-distributed speleothem δ¹⁸O records and highlight three aspects of the GPM that are comparable to the modern GM: (1) the GPM intensity swings on different timescales; (2) their global extent; and (3) an anti-phased inter-hemispheric relationship between the Asian and South American monsoon systems on a wide range of timescales.  相似文献   

Seasonal extreme rainfall over Indian monsoon region: a moisture budget analysis to distinguish the role of ENSO and non-ENSO forcing     

Dhakate  Ashish R.  Pillai  Prasanth A. 《Theoretical and Applied Climatology》2022,148(3-4):1603-1613

Theoretical and Applied Climatology - Indian summer monsoon rainfall (ISMR) variability of ± 10% of its long-term mean leads to flood and drought, affecting the life and economic...  相似文献   

Application of semi‐distributed hydrological model for basin level water balance of the Ken basin of Central India          下载免费PDF全文

P. S. Murty  Ashish Pandey  Shakti Suryavanshi 《水文研究》2014,28(13):4119-4129

In the present study, a semi‐distributed hydrological model soil and water assessment tool (SWAT) has been employed for the Ken basin of Central India to predict the water balance. The entire basin was divided into ten sub basins comprising 107 hydrological response units on the basis of unique slope, soil and land cover classes using SWAT model. Sensitivity analysis of SWAT model was performed to examine the critical input variables of the study area. For Ken basin, curve number, available water capacity, soil depth, soil evaporation compensation factor and threshold depth of water in the shallow aquifer (GWQ_MN) were found to be the most sensitive parameters. Yearly and monthly calibration (1985–1996) and validation (1997–2009) were performed using the observed discharge data of the Banda site in the Ken basin. Performance evaluation of the model was carried out using coefficient of determination, Nash–Sutcliffe efficiency, root mean square error‐observations standard deviation ratio, percent bias and index of agreement criterion. It was found that SWAT model can be successfully applied for hydrological evaluation of the Ken basin, India. The water balance analysis was carried out to evaluate water balance of the Ken basin for 25 years (1985–2009). The water balance exhibited that the average annual rainfall in the Ken basin is about 1132 mm. In this, about 23% flows out as surface run‐off, 4% as groundwater flow and about 73% as evapotranspiration. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Multi-criteria evaluation of CMIP5 GCMs for climate change impact analysis   总被引：1，自引：0，他引：1  

Ali?AhmadalipourEmail author  Arun?Rana  Hamid?Moradkhani  Ashish?Sharma 《Theoretical and Applied Climatology》2017,128(1-2):71-87

Climate change is expected to have severe impacts on global hydrological cycle along with food-water-energy nexus. Currently, there are many climate models used in predicting important climatic variables. Though there have been advances in the field, there are still many problems to be resolved related to reliability, uncertainty, and computing needs, among many others. In the present work, we have analyzed performance of 20 different global climate models (GCMs) from Climate Model Intercomparison Project Phase 5 (CMIP5) dataset over the Columbia River Basin (CRB) in the Pacific Northwest USA. We demonstrate a statistical multicriteria approach, using univariate and multivariate techniques, for selecting suitable GCMs to be used for climate change impact analysis in the region. Univariate methods includes mean, standard deviation, coefficient of variation, relative change (variability), Mann-Kendall test, and Kolmogorov-Smirnov test (KS-test); whereas multivariate methods used were principal component analysis (PCA), singular value decomposition (SVD), canonical correlation analysis (CCA), and cluster analysis. The analysis is performed on raw GCM data, i.e., before bias correction, for precipitation and temperature climatic variables for all the 20 models to capture the reliability and nature of the particular model at regional scale. The analysis is based on spatially averaged datasets of GCMs and observation for the period of 1970 to 2000. Ranking is provided to each of the GCMs based on the performance evaluated against gridded observational data on various temporal scales (daily, monthly, and seasonal). Results have provided insight into each of the methods and various statistical properties addressed by them employed in ranking GCMs. Further; evaluation was also performed for raw GCM simulations against different sets of gridded observational dataset in the area.  相似文献   

Evaluation of effective management plan for an agricultural watershed using AVSWAT model,remote sensing and GIS     

V. K. Pandey  S. N. Panda  Ashish Pandey  S. Sudhakar 《Environmental Geology》2009,56(5):993-1008

In the present investigation, an effort has been made to identify the critical sub-watersheds for the development of best management plan for a small watershed of Eastern India using a hydrological model, namely, AVSWAT2000. A total of 180 combinations of various management treatments including crops (rice, maize ground nut and soybean), tillage (zero, conservation, field cultivator, mould board plough and conventional practices) and fertilizer levels (existing half of recommended and recommended) have been evaluated. The investigation reveled that rice cannot be replaced by other crops such as groundnut, maize, mungbean, sorghum and soybean since comparatively these crops resulted in higher sediment yield. The tillage practices with disk plough have been found to have more impact on sediment yield and nutrient losses than conventional tillage practices for the existing level of fertilizer. Sediment yield decreased in the case of zero tillage, conservation tillage, field cultivator, moldboard plough, and conservation tillage as compare to conventional tillage. Lowest NO₃–N loss was observed in zero tillage in all the fertilizer treatments, whereas field cultivator, moldboard plough and disk plough resulted in increase of NO³–N loss. As compared to conventional tillage, the losses of soluble phosphorus were increased in moldboard plough. The losses of organic nitrogen were also increased as fertilizer dose increased. After zero tillage the conservation tillage preformed better in all the fertilizer treatments as per loss of organic nitrogen and organic phosphorus is concerned. It can be concluded that the sediment yield was found to be the highest in the case of disk plough followed by moldboard plough, field cultivator, conventional tillage, field cultivator and least in zero tillage practices. The nutrient losses were found to be in different order with tillage practices, resulted highest in disk plough tillage practices. In view of sediment yield and nutrient losses, the conservation tillage practice was found to be the best as the sediment yield is less than the average soil loss whereas nutrient loss is within the permissible limit.  相似文献   

Magnetic and radiometric signatures over a Proterozoic massive sulfide setting of northern fringe of Dalma Volcanics,eastern India: An implication to metallogeny     

Pramod Kumar Yadav  P. K. Adhikari  Shalivahan  Anurag Tripathi  Shailendra Singh  Roshan K. Singh  Ashish K. Bage 《Journal of the Geological Society of India》2017,89(6):705-710

Magnetic and radiometric surveys were carried out over a felsic dominated rifted margin of Proterozoic volcanic terrain of a mobile belt in the eastern India. The studies were made in blocks I and II of 0.65 sq km and 0.70 sq km respectively over a previously identified conductor in the northern fringe of Dalma Volcanics (DVs). In general, both the blocks show high magnetic signature associated with sulfide mineralisation. The interpretation of magnetic data suggests that nature of the causative source is mainly horizontal cylinder in both the blocks. The depth to the top of the causative source is about 25 m in both the blocks and extends upto 60 m in block I and 40m in block II. Gamma count rate exhibits about a factor of two to three enhancements above the field background for both the blocks. The obtained iso-rad maps are similar to uranium and copper belt in the Singhbhum shear zone south of the study area. The anomalous radiometric signature of the residual soil/rock of the area indicates towards hydrothermal alteration. The detailed magnetic surveys and preliminary iso-rads results seems quite encouraging and may be attributed to VMS setting in the area and potential sulfide mineralisation with uranium mineral association in the DVs province.  相似文献   

Residual Exchange Flows in Subtropical Estuaries   总被引：1，自引：0，他引：1  

Arnoldo Valle-Levinson  Guillermo Gutierrez de Velasco  Armando Trasviña  Alejandro J. Souza  Reginaldo Durazo  Ashish J. Mehta 《Estuaries and Coasts》2009,32(1):54-67

Observations of residual exchange flows at the entrance to four subtropical estuaries, two of them semiarid, indicate that these flows are mainly tidally driven, as they compare favorably with theoretical patterns of tidal residual flows. In every estuary examined, the tidal behavior was that of a standing or near-standing wave, i.e., tidal elevation and tidal currents were nearly in quadrature. The pattern of exchange flow that persisted at every estuary exhibited inflow in the channel and outflow over the shoals. Curiously, but also fortuitously, this pattern coincides with the exchange pattern driven by density gradients in other estuaries. The tidal stresses and the residual elevation slopes should be the dominant mechanisms that drive such tidal residual pattern because the Stokes transport mechanism is negligible for standing or near-standing waves. Time series measurements from the semiarid estuaries showed fortnightly modulation of the residual flow by tidal forcing in such a way that the strongest net exchange flows developed with the largest tidal distortions, i.e., during spring tides. This modulation is opposite to the modulation that typically results in temperate estuaries, where the strongest net exchange flows tend to develop during neap tides. The fortnightly modulation on tidal residual currents could be inferred from previous theoretical results because residual currents arise from tidal distortions but is made explicit in this study. The findings advanced herein should allow the drawing of generalities about exchange flow patterns in subtropical estuaries where residual flows are mainly driven by tides.  相似文献