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1.
A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France.  相似文献   
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 Cerro Panizos, a large caldera in the central Andes Mountains, produced two large dacitic ignimbrites at 7.9 Ma and 6.7 Ma and many andesitic and dacitic lava flows and domes. The older rhyodacitic Cienago Ignimbrite represents the most silicic magma erupted by the system. The younger, much larger volume dacitic Cerro Panizos Ignimbrite is very crystal-rich, containing up to 50% biotite, plagioclase, and quartz crystals in the pumice. It is weakly zoned, with most of the zoning apparent between two main cooling units. Major and most trace elements show little variation through the Cerro Panizos Ignimbrite, but the small range of composition is consistent with typical fractionation trends. Sr, Nd, and Pb isotopic ratios are very “crustal”, with initial 87Sr/86Sr values of 0.711 to 0.715, ɛNd values of –7.5 to –10.2, and nearly invariant Pb isotopic ratios (206Pb/204Pb=18.85, 207Pb/204Pb=15.67, and 208Pb/204Pb=38.80). The limited zonation observed in the Cerro Panizos Ignimbrite is explained by impeded crystal settling due to high crystal content. The magma body was a crystal-liquid mush before ascent to the pre-eruption crustal levels. Crystals formed, but did not separate easily from the magma. Limited fractionation of plagioclase and biotite may have occurred, but the composition was largely controlled by lower crustal MASH processes. AFC modeling shows that the Cerro Panizos magmas resulted from a mixture of roughly equal proportions of late Miocene mantle-derived basalts and melts from ∼1.0 Ga (Grenville age) lower crust. This occurred in a MASH zone in the lower crust, and set the crustal isotopic ratios observed in the Cerro Panizos magmas. The great thickening of the crust beneath the central Andes Mountains sent upper and middle crustal rock types to lower crustal (and deeper) depths, and this explains the “upper crustal” isotopic signatures of the Cerro Panizos rocks. Minor upper crustal assimilation of early Miocene volcanic or subvolcanic rocks produced much of the isotopic variation seen in the system. The nearly invariant high Pb isotopic values and high Pb concentrations indicate that Pb came almost entirely from the crustal source, and was little altered by any subsequent upper crustal assimilation. This Pb signature is isotopically similar to that of the southern Bolivian Tin Belt, suggesting a widely distributed Pb source. The great difference between compositions of Miocene and Quaternary central Andean volcanic rocks is explained by crustal thickening in early Miocene time leading to abundant lower crustal water and associated fluxed melting during the time of the earlier eruptions. The lower crust dried out considerably by Quaternary time, so less crustal component is present. Received: 22 December 1994 / Accepted: 13 September 1995  相似文献   
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This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.  相似文献   
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Multipath remains one of the major challenges in Global Navigation Satellite System (GNSS) positioning because it is considered the dominant source of ranging errors, which can be classified into specular and diffuse types. We present a new method using wavelets to extract the pseudorange multipath in the time domain and breaking it down into the two components. The main idea is an analysis-reconstruction approach based on application of both continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The proposed procedure involves the use of L1 code-minus-carrier (CMC) observable where higher-frequency terms are isolated as residuals. CMC residuals are analyzed by applying the CWT, and we propose the scalogram as a technique for discerning time–frequency variations of the multipath signal. Unlike Fourier transform, the potential of the CWT scalogram for examining the non-stationary and multifrequency nature of the multipath is confirmed as it simultaneously allows fine detection and time localization of the most representative frequencies of the signal. This interpretation of the CWT scalogram is relevant when choosing the levels of reconstruction with DWT, allowing accurate time domain extraction of both the specular and diffuse multipath. The performance and robustness of the method and its boundary applicability are assessed. The experiment was carried out using a receiver of Campania GNSS Network. The results are given in which specular multipath error is achieved using DWT level 7 approximation component and diffuse multipath error is achieved using DWT level 6 denoised detail component.  相似文献   
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Coalbed methane (CBM) is a worldwide exploration target of the petroleum industry. In Brazil, the most important coal-bearing succession is associated with the Permian Rio Bonito Formation of the Paraná Basin. The gas-prone areas are located at the southeastern margin of the Paraná Basin and possibly in the offshore region of the northern part of the Pelotas Basin. Coalfields end abruptly at the present day shoreline, a result of rifting of Gondwana and the evolution of the South Atlantic Ocean. All geologic indicators suggest that in pre-rift times the coal seams extended further eastwards, probably now lying deeply buried below the sedimentary succession of the Pelotas Basin. The present paper discusses structural, stratigraphic, seismic and aeromagenetic data that support the preservation of continental crust beneath ocean sediment. If the coal beds had similar lateral extent to known onshore coals, and coal beds extended across the projected extension of the Parana basin, and there was a conservative 5 m of cumulative coal thickness, then a potential methane volume can be estimated for this newly inferred resource. Average onshore coal gas content is 32 scf/ton (1.00 m3/ton). If this is similar in the offshore coal deposits, then the hypothetical methane volume in the offshore area could be in excess of 1.9 × 1012 scf (56 × 109 m3). Metamorphism from dikes associated with rifting are potential complicating factors in these deposits, and since no borehole reaching the deep-lying strata in the offshore area are available, this is a hypothetical gas resource with a certain level of uncertainty which should be tested in the future by drilling a deep borehole.  相似文献   
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Partial spilitization of a 9 km thick pile of flood basalts with highly vesicular flow tops gave rise to patterns of secondary mineralogy at different scales: (a) a local pattern of mineralogical variation from the almost unaltered bottom towards the altered top of each flow, and (b) an overall pattern, comparing flow tops throughout the pile, with changes in mineralogical composition within a sequence of metamorphic zones and facies. The local patterns mimic the trend of the overall pattern, but are of opposite direction and telescoped. Thus, a gradual ordering and Andepletion of the secondary albite and increases in the Fe*/Al ratio of epidote and pumpellyite upwards within individual flows are comparable in range to corresponding overall changes downwards throughout several kilometres. The mineralogical changes within the flows diminish in range towards the more altered deeper part of the pile.The local and overall patterns cannot be interpreted in terms of grade. They represent trends from metastable towards stable equilibrium, this latter only approached in the flow tops of the lower part of the pile. The patterns of secondary mineralogy were formed by an interplay of metamorphic gradients at different scales at any given time, and as burial proceeded. The overall pattern was caused by depth-controlled gradients: increasing P fluid, temperature and temperature-induced increase of reaction rates, and decreasing fO2 (downwards in the pile). The local patterns resulted from permeability-controlled gradients: increasing reaction rates, fO2 and contrast in chemical activity between different domains, and decreasing P fluid (upwards in each flow). The mineralogical observations reported in this paper fall into line if the overall temperature-induced increase of reaction rates and the local permeability-controlled rate factors played the leading role during burial metamorphism of the pile.  相似文献   
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An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.  相似文献   
10.
The Polochic and Motagua faults define the active plate boundary between the North American and Caribbean plates in central Guatemala. A splay of the Polochic Fault traverses the rapidly growing city of San Miguel Uspantán that is periodically affected by destructive earthquakes. This fault splay was located using a 2D electrical resistivity tomography (ERT) survey that also characterized the fault damage zone and evaluated the thickness and nature of recent deposits upon which most of the city is built. ERT images show the fault as a ~50 m wide, near-vertical low-resistivity anomaly, bounded within a few meters by high resistivity anomalies. Forward modeling reproduces the key aspects of the observed electrical resistivity data with remarkable fidelity thus defining the overall location, geometry, and internal structure of the fault zone as well as the affected lithologies. Our results indicate that the city is constructed on a ~20 m thick surficial layer consisting of poorly consolidated, highly porous, water-logged pumice. This soft layer is likely to amplify seismic waves and to liquefy upon moderate to strong ground shaking. The electrical conductivity as well as the major element chemistry of the groundwater provides evidence to suggest that the local aquifer might, at least in part, be fed by water rising along the fault. Therefore, the potential threat posed by this fault splay may not be limited to its seismic activity per se, but could be compounded its potential propensity to enhance seismic site effects by injecting water into the soft surficial sediments. The results of this study provide the basis for a rigorous analysis of seismic hazard and sustainable development of San Miguel Uspantán and illustrate the potential of ERT surveying for paleoseismic studies.  相似文献   
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