Temporal variations of heavy metals in Mercenaria mercenaria     

Behrens  William J.; Duedall  Iver W. 《ICES Journal of Marine Science》1981,39(3):219-222

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CO₂ solubility in dacitic melts equilibrated with H₂O-CO₂ fluids: Implications for modeling the solubility of CO₂ in silicic melts     

Harald Behrens  Susanne Ohlhorst  Michel Champenois 《Geochimica et cosmochimica acta》2004,68(22):4687-4703

The solubility of CO₂ in dacitic melts equilibrated with H₂O-CO₂ fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO₂ is dissolved in dacitic glasses as molecular CO₂ and carbonate. The quantification of total CO₂ in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm⁻¹ can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO_2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO₂ species concentrations from the MIR spectra we have measured total CO₂ contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO₂ solubility in dacitic melts on x^fluid_CO2,total shows a strong positive deviation from linearity with almost constant CO₂ solubility at x_CO2fluid > 0.8 (maximum CO₂ solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO₂. A similar nonlinear variation of CO₂ solubility with x_CO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO₂ (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO₂ molecules.A thermodynamic model describing the dependence of the CO₂ solubility in hydrous rhyolitic and dacitic melts on T, P, f_CO2 and the mol fraction of water in the melt (x_water) has been developed. An exponential variation of the equilibrium constant K₁ with x_water is proposed to account for the nonlinear dependence of x_CO2,totalmelt on x_CO2fluid. The model reproduces the CO₂ solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low x_CO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO₂ at low pressures (a Henrian behavior of the CO₂ solubility is observed at low pressure and low H₂O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the x_CO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO₂ is much lower in rhyolitic melts (31.7 cm³/mol) than in dacitic melts (46.6 cm³/mol). The dissolution enthalpy for CO₂ in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO₂ solubility in silicic melts.  相似文献   

Correction to: Ferric/ferrous ratio in silicate melts: a new model for 1 atm data with special emphasis on the effects of melt composition     

Alexander?BorisovEmail authorView author&#;s OrcID profile  Harald?Behrens  Francois?Holtz 《Contributions to Mineralogy and Petrology》2018,173(12):107

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Effects of F,B2O3 and P2O5 on the solubility of water in haplogranite melts compared to natural silicate melts     

François Holtz  Donald B. Dingwell  Harald Behrens 《Contributions to Mineralogy and Petrology》1993,113(4):492-501

The effects of F, B₂O₃ and P₂O₅ on the H₂O solubility in a haplogranite liquid (36 wt. % SiO₂, 39 wt. % NaAlSi₃O₈, 25 wt. % KAlSi₃O₈) have been determined at 0.5, 1, 2, and 3 kb and 800, 850, and 900°C. The H₂O solubility increases with increasing F and B content of the melt. The H₂O solubility increase in more important at high pressure (2 and 3 kb) than at low pressure (0.5 kb). At 2 kb and 800°C, the H₂O solubility increases from 5.94 to 8.22 wt. % H₂O with increasing F content in the melt from 0 to 4.55 wt. %, corresponding to a linear H₂O solubility increase of 0.53 mol H₂O/mol F. With addition of 4.35 wt. % B₂O₃, the H₂O solubility increases up to 6.86 wt. % H₂O at 2 kb and 800°C, corresponding to a linear increase of 1.05 mol H₂O/mol B₂O₃. The results allow to define the individual effects of fluorine and boron on H₂O solubility in haplogranitic melts with compositions close to that of H₂O-saturated thermal minima (at 0.5–3 kb). Although P has a dramatic effect on the phase relations in the haplogranite system, its effect on the H₂O solubility was found to be negligible in natural melt compositions. The concominant increase in H₂O solubility and F can not be interpreted on the basis of the available spectroscopic data (existence of hydrated aluminofluoride complexes or not). In contrast, hydrated borates or more probably boroxol complexes have been demonstrated in B-bearing hydrous melts.  相似文献   

The wave forecast system of the “Deutscher Wetterdienst” and the “Bundesamt für Seeschiffahrt und hydrographie”: A verification using ERS-1 altimeter and scatterometer data     

Dr. Arno Behrens  Dieter Schrader 《Ocean Dynamics》1994,46(2):131-149

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Studies on the Treatment of Distillery Effluents by Anaerobic Filters     

E. Schulze  U. Behrens 《洁净——土壤、空气、水》1985,13(6):697-707

In the present work the kinetics and the feasibility of batch anaerobic filter operations for the treatment of beet molasses distillery slops have been investigated. Up to 50% of the influent COD up to 25 g/l are removed after 5… 10 h and up to 80% after 24… 40 h treating time. Highest removal rates were obtained for 50% removal and influent COD concentration ≧13 kg. m^?3. The highest methane productivity was observed in the same range of COD influent concentration during the first 10 hours (initial velocity) of the treatment. The benefits of the anaerobic treatment of waste water applying systems with biomass retention are discussed.  相似文献   

Zum Abbau von Formaldehyd durch adaptierte Bakterien     

U. Behrens  J. Hannes 《洁净——土壤、空气、水》1984,12(1):39-45

Municipal activated sludge was cultivated in a medium composed of formaldehyde, glucose and mineral salt. By passages with increasing formaldehyde content a bacterial culture was selected which remained active also at initial concentrations of 1 g/1 formaldehyde. With this culture, formaldehyde and glucose were oxidized simultaneously to formate and gluconate, which subsequently served simultaneously as substrate for the growth of bacteria. Glucose alone was also oxidized to gluconate, which then was used as substrate for growth. Formaldehyde alone was only oxidized. If the actual formaldehyde concentration was kept low, however, by fed-batch cultivation, it was assimilated also through formate formation. The biochemical background and the importance of the findings for the purification of formaldehyde-containing wastewaters are discussed.  相似文献   

Organic carbon isotope ratios in Quaternary cores from the Gulf of Mexico     

Juanita W Newman  Patrick L Parker  E.W Behrens 《Geochimica et cosmochimica acta》1973,37(2):225-238

All of the major deep-water sedimentary provinces of the Gulf of Mexico were sampled with 48 piston cores, representative of the late Quaternary. The amount (per cent) and δ5C¹³ of the organic carbon in the sediment was measured at intervals within each core.Graphs of δC¹³ versus depth for each core give an indication of the sedimentological history of the Gulf. They show the extent of terrestrial influence on the Gulf during the late Pleistocene.Changes in δC¹³ of up to 6.0%.(from ~ ?19%.to ?25%. vs NBS-20) were measured across the Pleistocene-Holocene boundary in cores from the abyssal plain. These changes are consistent with a model wherein varying amounts of land-derived organic carbon were transported to the Gulf basin during glacial periods.By comparing graphs for cores from different areas, it was concluded that the major parameter affecting the δC¹³ values of organic carbon from marine sediments is the relative amount of terrestrial material present in the sediment. The maximum possible effect of the Pleistocene-Holocene temperature change in the Gulf was determined to be ~1.0%, if such an effect occurs at all.  相似文献   

Effects of melt composition on Fe3+/Fe2+ in silicate melts: a step to model ferric/ferrous ratio in multicomponent systems     

Alexander Borisov  Harald Behrens  Francois Holtz 《Contributions to Mineralogy and Petrology》2015,169(2):1-12

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Challenges in global ballast water management   总被引：3，自引：0，他引：3  

Endresen Ø  Lee Behrens H  Brynestad S  Bjørn Andersen A  Skjong R 《Marine pollution bulletin》2004,48(7-8):615-623

Ballast water management is a complex issue raising the challenge of merging international regulations, ship's specific configurations along with ecological conservation. This complexity is illustrated in this paper by considering ballast water volume, discharge frequency, ship safety and operational issues aligned with regional characteristics to address ecological risk for selected routes. A re-estimation of ballast water volumes gives a global annual level of 3500 Mton. Global ballast water volume discharged into open sea originating from ballast water exchange operations is estimated to approximately 2800 Mton. Risk based decision support systems coupled to databases for different ports and invasive species characteristics and distributions can allow for differentiated treatment levels while maintaining low risk levels. On certain routes, the risk is estimated to be unacceptable and some kind of ballast water treatment or management should be applied.  相似文献