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1.
M.J. Bickle 《地学学报》1996,8(3):270-276
The seawater 87Sr/86Sr curve implies a 50–100 Myr episodicity in weathering rate which requires a corresponding variation in CO2 degassing from the solid earth to the atmosphere. It is proposed that this is caused by orogenesis, which both produces CO2 as a result of metamorphic decarbonation reactions, and consumes extra CO2 as a consequence of erosion-enhanced weathering. Global climate on the geological time-scale is therefore contTolled by the difference between the relatively large and variable orogenic-moderated degassing and weathering CO2 fluxes.  相似文献   
2.
Fluxes of Sr into the headwaters of the Ganges   总被引:1,自引:0,他引:1  
Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, 87Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated 87Sr/86Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the 87Sr flux in excess of the seawater 87Sr/86Sr ratio of 0.709.  相似文献   
3.
Nd, Sr, and O isotope analyses have been made on metamorphic and igneous rocks and minerals from a 310–340 Ma Hercynian-age metamorphic terrane in the Pyrenees, France. Lower Paleozoic shales and phyllites have 87Sr/86Sr values of 0.707–0.717 at 310 Ma, but model values at 310 Ma of 0.709–0.736 (based on assumed depositional age of 450 Ma and an initial 87Sr/86Sr=0.707). On a regional scale, 87Sr/86Sr was homogenized to about 0.713 to 0.717 in the higher-grade pelitic schists during metamorphism. Much of this 87Sr/86Sr exchange occurred at very low grades (below the biotite isograd), but significant changes also accompanied the δ 18O lowering of the phyllites (+13 to +16) during their transformation to andalusite- and sillimanite-grade schists (δ 18O=+11 to +12); all of these effects are attributed to pervasive interactions with hydrothermal fluids (Wickham and Taylor 1985). The data also show that a syn-metamorphic plutonic complex, dominated by a biotite granite body, was derived by mixing of a relatively mafic magmatic end-member (87Sr/86Sr~ 0.7025–0.7050 and δ 18O~ +7.5 to +8.0) with two metasedimentary sources, both having 87Sr/86Sr~0.715 and δ 18O~ +10.0 to +12.0, but with one being more homogeneous than the other. The more homogeneous component and the (mantle-derived?) magmatic end-member dominate at low structural levels within the complex. The less homogeneous end-member that dominates at high levels is clearly derived from the local Paleozoic pelitic schists. A Rb-Sr age of 330±20 Ma was obtained on hornblende from a deep level within the complex, which fixes this age for the regional metamorphism, as well. Although a post-metamorphic granodiorite magma body at Trois Seigneurs also displays heterogeneities in δ 18O and 87Sr/86Sr (and thus does not give a clear-cut Rb-Sr isochron), the data are consistent with an emplacement age between 260 and 310 Ma, similar to ages of other late granodiorites in the Pyrenees. 143Nd/ 144Nd is very uniform within the Hercynian crust, both at Trois Seigneurs (? Nd=?3 to ?7) and elsewhere in the Pyrenees; almost all igneous lithologies have depleted-mantle, mid-Proterozoic model ages, consistent with efficient recycling of crustal material following original crustal accretion in this area at about 1600 Ma or earlier. Rb-Sr mineral ages exhibit a complex cooling history reflecting late Hercynian and Mesozoic thermal events. Our results show that profound homogenization of the 87Sr/86Sr and 18O/16O ratios of large volumes of the crust can occur during regional metamorphism and crustal anatexis, particularly in regions undergoing extensional tectonics. Such processes can significantly modify the isotopic compositions of the protoliths of granitic magmas; this may explain why many peraluminous Hercynian granitoids of Western Europe have anomalously low (87Sr/86Sr) initial values compared to their probable sedimentary parent rocks.  相似文献   
4.
The maximum potential temperature of the Archaean mantle is poorly known, and is best constrained by the MgO contents of komatiitic liquids, which are directly related to eruptive temperatures. However, most Archaean komatiites are significantly altered and it is difficult to assess the composition of the erupted liquid. Relatively fresh lavas from the SASKMAR suite, Belingwe Greenstone Belt, Zimbabwe (2.7 Ga) include chills of 25.6 wt.% MgO, and olivines ranging to Fo93.6, implying eruption at around 1520°C. A chill sample from Alexo Township, Ontario (also 2.7 Ga) is 28 wt.% MgO, and associated olivines range to Fo94.1, implying eruption at 1560°C. However, inferences of erupted liquids containing 32–33 wt.% MgO, from lavas in the Barberton Greenstone Belt, South Africa (3.45 Ga) and from the Perseverance Complex, Western Australia (2.7 Ga) may be challenged on the grounds that they contain excess (cumulate) olivine, or were enriched in Mg during alteration or metamorphism. Re-interpretation of olivine compositions from these rocks shows that they most likely contained a maximum of 29 wt.% MgO corresponding to an eruption temperature of 1580°C. This composition is the highest liquid MgO content of an erupted lava that can be supported with any confidence. The hottest modern magma, on Gorgona Island (0.155 Ga) contained 18–20% MgO and erupted at circa 1400°C.

If 1580°C is taken as the temperature of the most magnesian known eruption, then the source mantle from which the liquids rose would have been at up to 2200°C at pressures of 18 GPa corresponding to a mantle potential temperature of 1900°C. These temperatures are in excess of the mantle temperatures predicted by secular cooling models, and thus komatiites can only be formed in hot rising convective jets in the mantle. This result requires that Archaean mantle jets may have been 300°C hotter than the Archaean ambient mantle temperature. This temperature difference is similar to the 200–300°C temperature difference between present day jets and ambient mantle temperatures. An important subsidiary result of this study is the confirmation that spinifex rocks may be cumulates and do not necessarily represent liquid compositions.  相似文献   

5.
In the aureole of the Beinn an Dubhaich granite, Skye, the minimum observed median forsterite-calcite-calcite dihedral angle varies from 110° at the olivinein isograd to about 165° (the equilibrium value) at the granite-limestone contact. Laboratory experiments were performed to investigate the kinetics of this textural change. It was found that the rate of change of the forsterite-calcite-calcite dihedral angle followed approximately first-order kinetics with an activation energy of 48±4 kJ mol-1 for fluid-present conditions, and 90 ±4 kJ mol-1 for fluid-absent conditions. Scanning ion imaging demonstrated that, at least in the early stages of textural change, solution-reprecipitation of the calcite was the rate determining step in the fluid-present runs. The latter result and the value of the activation energy are both consistent with the activation energy found by previous authors for (albeit zeroth order) silicate-aqueous solution solution-reprecipitation reactions. The value of activation energy for the dry data does not correspond to those for either grain boundary or volume diffusion of oxygen or magnesium in forsterite. The mechanism for textural equilibration in the fluid-absent runs is uncertain. Application of the experimentally-derived rate equation to the Beinn an Dubhaich marbles gave activation energies higher than those obtained experimentally. It is concluded from consideration of grain growth effects that activation energies derived from the Beinn an Dubhaich marbles probably reflect textural equilibration under predominantly fluid-absent conditions.  相似文献   
6.
Non-dimensional solutions to the equations for the combined advective and diffusive one-dimensional transport of heat and solute in a layer are derived for fixed temperature/concentration on the boundaries and initial conditions of a linear gradient across the layer or a step function at the lower boundary. The solutions allow distinction of regimes in which advective or diffusive transport of either heat or solute predominate as a function of fluid flux, time and a length scale. The much lower diffusive coefficients for solute than heat results in a significant range of length scales and fluid flux rates characterised by advection of matter and diffusion of heat. The advective velocity of a component is a function of its fluid:rock partition coefficient. The most rapidly transported tracers which partition largely into the fluid phase, such as He, will travel orders of magnitude faster than heat or compatible solutes such as oxygen. Geochemical profiles in boundary layer regions where both advective and diffusive transport are significant are shown to be particularly informative as to properties of the rocks related to fluid flow such as porosity, permeability, time scales and fluid flux rates. The importance of advection can be directly estimated from the asymmetry of the geochemical profiles across individual layers.  相似文献   
7.
 Sr isotope profiles across marble-silicate rock contacts are used in conjunction with previously published oxygen isotope profiles to constrain fluid movement, porosity and permeability contrasts in migmatitic rocks from Lizzies Basin in the East Humboldt Range, Nevada. The 18O/16O systematics in the high-grade sequence have been interpreted to reflect infiltration of ∼2×102 m3/m2 of a relatively low 18O hydrous fluid through the sequence, but with preservation of δ18O anomalies in thin marble bands due to a 30-fold lower porosity in the marble compared with silicate rocks (Wickham and Peters 1992). The Sr isotope profiles confirm that tracer exchange between marble and silicate rock was primarily by diffusion, and in one case, indicate that porosities differed by less than a factor of four in the ∼10 cm boundary layer which exhibits diffusive modification of 87Sr/86Sr ratios. This contrasts with modelling of the oxygen isotope profiles which imply porosity contrasts >10 for one marble band and >50 for a second marble band. Either strontium and oxygen isotope diffusion reflect different events (possible if fluid Sr contents varied with time) or porosity varied substantially with the silicate rocks. Oxygen isotope profiles in the deeper part of the metamorphic section in which δ18O values of silicate rocks have been homogenised and lowered, indicate similar diffusion distances (and thus porosity-time evolution) to oxygen isotopic profiles higher in the section. Comparison of strontium and oxygen isotope diffusion distances constrains fluid Sr contents to between ∼50 and ∼500 ppm deep in the section, but less than ∼10 ppm higher in the section. The difference is related to release of relatively saline, Sr-rich fluids, by the abundant leucogranites and associated skarns deep in the section (cf. Peters and Wickham 1995). Received: 9 December 1994/Accepted: 13 April 1995  相似文献   
8.
9.
Talat  Ahmad  Kabita C.  Longjam  Baishali  Fouzdar  Mike J.  Bickle  Hazel J.  Chapman 《Island Arc》2009,18(1):155-174
The Sakoli Mobile Belt comprises bimodal volcanic rocks that include metabasalt, rhyolite, tuffs, and epiclastic rocks with metapelites, quartzite, arkose, conglomerate, and banded iron formation (BIF). Mafic volcanic rocks are tholeiitic to quartz‐tholeiitic with normative quartz and hypersthene. SiO2 shows a large compositional gap between the basic and acidic volcanics, depicting their bimodal nature. Both the volcanics have distinct geochemical trends but display some similarity in terms of enriched light rare earth element–large ion lithophile element characteristics with positive anomalies for U, Pb, and Th and distinct negative anomalies for Nb, P, and Ti. These characteristics are typical of continental rift volcanism. Both the volcanic rocks show strong negative Sr and Eu anomalies indicating fractionation of plagioclases and K‐feldspars, respectively. The high Fe/Mg ratios for the basic rocks indicate their evolved nature. Whole rock Sm–Nd isochrons for the acidic volcanic rocks indicate an age of crystallization for these volcanic rocks at about 1675 ± 180 Ma (initial 143Nd/144Nd = 0.51017 ± 0.00017, mean square weighted deviate [MSWD] = 1.6). The εNdt (t = 2000 Ma) varies between ?0.19 and +2.22 for the basic volcanic rock and between ?2.85 and ?4.29 for the acidic volcanic rocks. Depleted mantle model ages vary from 2000 to 2275 Ma for the basic and from 2426 to 2777 Ma for the acidic volcanic rocks, respectively. These model ages indicate that protoliths for the acidic volcanic rocks probably had a much longer crustal residence time. Predominantly basaltic magma erupted during the deposition of the Dhabetekri Formation and part of it pooled at crustal or shallower subcrustal levels that probably triggered partial melting to generate the acidic magma. The influence of basic magma on the genesis of acidic magma is indicated by the higher Ni and Cr abundance at the observed silica levels of the acidic magma. A subsequent pulse of basic magma, which became crustally contaminated, erupted as minor component along with the dominantly acidic volcanics during the deposition of the Bhiwapur Formation.  相似文献   
10.
Calc-alkaline plutonic rocks, intruded at 3450Ma, comprise a major component of the Shaw Batholith in the Archaean east Pilbara Block, Western Australia. New whole-rock Pb isotopic geochronology confirms the extent of these rocks, but a minor plutonic phase is dated at 3338±52 Ma and represents a second plutonic event of the same age as much of the nearby Mt Edgar Batholith. The Sm----Nd isotopic systematics of the 3450Ma rocks imply their derivation from a heterogeneous source, which probably included a slightly older crustal component as well as a depleted mantle component. The 3338±52 Ma pluton includes components derived from crustal sources older than 3600 Ma. The geochemistry and Sm---Nd isotopic systematics of these rocks are consistent with crustal growth in the early Archaean from upper mantle sources as depleted as the modern upper mantle. The Shaw Batholith calc-alkaline suites exhibit very similar chemical trends on variation diagrams to modern calc-alkaline plutonic rocks which can be modelled by a combination of mixing and fractionation. A suite collected from outcrops displaying prominent igneous layering shows distinct geochemical trends which can be modelled by differentiation into a component enriched in ferromagnesian minerals, principally hornblende, and possibly sphene, magnetite and epidote, and into a leucocratic component containing quartz, plagioclase and K-feld-par. These Archaean calc-alkaline plutonic rocks, in common with rocks from many other Archaean calc-alkaline provinces, exhibit very fractionated REE patterns with depleted HREE contents, a feature considered to result from equilibrium with garnet at depth in lower crustal regions. The geochemistry of the Pilbara Archaean calc-alkaline rocks is identical to the subset of modern continental-margin calc-alkaline plutonic rocks with fractionated REE patterns, such as those from the central and eastern Peninsular Ranges Batholith, western USA. The tectonic setting in which the Archaean calc-alkaline rocks formed is still not known. This reflects both uncertainty associated with the petrogenesis and environments of modern calc-alkaline rocks, as well as the limited knowledge of the precise timing and relationships of plutonic, depositional and tectonic events in the Pilbara Archaean.  相似文献   
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