Spatio‐temporal variability of the isotopic input signal in a partly forested catchment: Implications for hydrograph separation     

Carles Cayuela  Jrme Latron  Josie Geris  Pilar Llorens 《水文研究》2019,33(1):36-46

The isotopic composition of precipitation (D and ¹⁸O) has been widely used as an input signal in water tracer studies. Whereas much recent effort has been put into developing methodologies to improve our understanding and modelling of hydrological processes (e.g., transit‐time distributions or young water fractions), less attention has been paid to the spatio‐temporal variability of the isotopic composition of precipitation, used as input signal in these studies. Here, we investigated the uncertainty in isotope‐based hydrograph separation due to the spatio‐temporal variability of the isotopic composition of precipitation. The study was carried out in a Mediterranean headwater catchment (0.56 km²). Rainfall and throughfall samples were collected at three locations across this relatively small catchment, and stream water samples were collected at the outlet. Results showed that throughout an event, the spatial variability of the input signal had a higher impact on hydrograph separation results than its temporal variability. However, differences in isotope‐based hydrograph separation determined preevent water due to the spatio‐temporal variability were different between events and ranged between 1 and 14%. Based on catchment‐scale isoscapes, the most representative sampling location could also be identified. This study confirms that even in small headwater catchments, spatio‐temporal variability can be significant. Therefore, it is important to characterize this variability and identify the best sampling strategy to reduce the uncertainty in our understanding of catchment hydrological processes.  相似文献   

The early Cambrian Chahmir shale-hosted Zn–Pb deposit,Central Iran: an example of vent-proximal SEDEX mineralization     

Abdorrahman?Rajabi  Ebrahim?RastadEmail author  Carles?Canet  Pura?Alfonso 《Mineralium Deposita》2015,50(5):571-590

The Chahmir zinc–lead deposit (1.5 Mt @ 6 % Zn + 2 % Pb) in Central Iran is one among several sedimentary-exhalative Zn–Pb deposits in the Early Cambrian Zarigan–Chahmir basin (e.g., Koushk, Darreh-Dehu, and Zarigan). The deposit is hosted by carbonaceous, fine-grained black siltstones, and shales interlayered with volcaniclastic sandstone beds. It corresponds to the upper part of the Early Cambrian volcano-sedimentary sequence (ECVSS), which was deposited on the Posht-e-Badam Block during back-arc rifting of the continental margin of Central Iran. Based on crosscutting relationships, mineralogy, and texture of sulfide mineralization, four different facies can be distinguished: stockwork (feeder zone), massive ore, bedded ore, and distal facies (exhalites with barite). Silicification, carbonatization, sericitization, and chloritization are the main wall-rock alteration styles; alteration intensity increases toward the proximal feeder zone. Fluid inclusion microthermometry was carried out on quartz associated with sulfides of the massive ore. Homogenization temperatures are in the range of 170–226 °C, and salinity is around 9 wt% NaCl eq. The size distribution of pyrite framboids of the bedded ore facies suggests anoxic to locally suboxic event for the host basin. δ³⁴S_(V-CDT) values of pyrite, sphalerite, and galena range from +10.9 to +29.8?‰. The highest δ³⁴S values correspond to the bedded ore (+28.6 to +29.8?‰), and the lowest to the massive ore (+10.9 to +14.7?‰) and the feeder zone (+11.3 and +12.1?‰). The overall range of δ³⁴S is consistent with a sedimentary environment where sulfide sulfur was derived from two sources. One of them was corresponding to early ore-stage sulfides in bedded ore and distal facies, consistent with bacterial reduction from coeval seawater sulfate in a closed or semiclosed basin. However, the δ³⁴S values of late ore-stage sulfides, observed mainly in massive ore, interpreted as a hydrothermal sulfur component, leached from the lower part of the ECVSS. Sulfur isotopes, along with the sedimentological, textural, mineralogical, fluid inclusion, and geochemical characteristics of the Chahmir deposit are in agreement with a vent-proximal (Selwyn type) SEDEX ore deposit model.  相似文献   

Anticipating the effects of groundwater withdrawal on seawater intrusion and soil settlement in urban coastal areas     

Josep Mas‐Pla  Agustí Rodríguez‐Florit  Manel Zamorano  Carles Roqué  Anna Menció  David Brusi 《水文研究》2013,27(16):2352-2366

Intensive pumping in urban coastal areas is a common threat to water resource quality due to seawater intrusion. In those areas where subsurface water resources are not usually used for human consumption or irrigation, intensive pumping is associated with other activities like the lowering of the water table necessary to support underground structures and building foundations. This activity also increases the likelihood of soil settlement that affects building stability and the corrosion of concrete structures due to groundwater salinity. Under these circumstances, the awareness of a certain municipality (Calonge, NE Spain) of the potential effects of groundwater withdrawal upon foundations has led to an integrated approach to anticipate seawater intrusion related to urban development. Geological mapping and correlation of borehole logs, electrical resistivity tomography, and hydrochemical data provide comprehensive knowledge of the geology and hydrogeology of the area and act as screening tools necessary to discern the influence of hydrological processes in coastal areas. Developing Strack's analytical solution, new comprehensive, dimensionless expressions are herein derived to determine the critical pumping rate necessary to prevent seawater intrusion, as well as to reproduce the evolution of the wedge toe and the water table stagnation point under different withdrawal rates. Furthermore, the Dupuit–Forchheimer well discharge formula allows the estimation of the effects of the water table lowering due to such critical pumping in the surrounding building foundations. Field data from the Calonge coastal plain illustrate this approach and provide assessment criteria for future urban development and planning. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia     

Ben Ameur W  Ben Hassine S  Eljarrat E  El Megdiche Y  Trabelsi S  Hammami B  Barceló D  Driss MR 《Marine environmental research》2011,72(5):258-264

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.  相似文献   

Interannual variability in the biochemical composition of newly hatched larvae of the spider crab Maja brachydactyla (Decapoda,Majidae)     

Guiomar Rotllant  Carles G. Simeó  Guillermo Guerao  Marta Sastre  Daniel F. R. Cleary  Ricardo Calado  Alicia Estévez 《Marine Ecology》2014,35(3):298-307

The spider crab Maja brachydactyla is an important commercial species in Europe and supports intensive fisheries in the NE Atlantic. A field survey was performed to assess long‐term and consecutive interannual (2005–2010) variation of the biochemical composition of newly hatched larvae of M. brachydactyla. Larval biochemical profiles differed significantly among years, with pronounced differences being recorded in 2010. Differences among batches of newly hatched larvae were mainly explained by the contribution of triacylglycerols and, to a lesser degree, by protein and lipid content. The use of different nutrition indices is discussed. The biochemical composition of newly hatched larvae from M. brachydactyla was highly variable, even though surveyed broodstock was obtained from the same local population and was always sampled during the same season. The unpredictable biochemical profiles of newly hatched larvae may condition their survival and recruitment. This largely overlooked aspect of larval variability should be considered in future fisheries management strategies and captive production of marine organisms that still rely on wild seeds.  相似文献   

Masses for which triple collision is regularizable     

Carles Simó 《Celestial Mechanics and Dynamical Astronomy》1980,21(1):25-36

We consider the regularization by continuity w.r.t. initial conditions (geometric or Easton method) which has a sense both in physical and computational aspects. Using the idea of triple collision manifold of McGehee we study the values of masses for which the invariant manifolds of equilibrium points coincide. Local analytical equations are continuated numerically. So one gets the masses satisfying a necessary condition. Again analytically we discuss the neighbourhood of t.c.m. at the equilibrium points. A necessary and sufficient condition in terms of integrals along invariant manifolds is found for the rectilinear case. This can be tested for the masses obtained above. Only a countable (symmetric) set of masses remains. Then, due to errors in physical measurements or numerical integrations we can never expect a regular behaviour. Extension to the planar case is also taken into account.Proceedings of the Sixth Conference on Mathematical Methods in Celestial Mechanics held at Oberwolfach (West Germany) from 14 to 19 August, 1978.  相似文献   

Conduit-vent structures and related proximal deposits in the Las Cañadas caldera, Tenerife, Canary Islands     

Carles Soriano  Inés Galindo  Joan Martí  John Wolff 《Bulletin of Volcanology》2006,69(2):217-231

The Las Cañadas caldera wall and the outer slopes of the caldera provide three-dimensional exposures of numerous proximal-welded fallout deposits and have been mapped in detail. As a result, some parts of the Ucanca and Guajara Formations of the stratigraphy of Martí et al. (1994) have been divided into members that correspond to individual eruptions. Mapping has also revealed the occurrence of conduit-vent structures associated with proximal-welded fallout deposits. Conduit-vent structures consist of an upper flaring area and a lower narrow conduit. Conduit-vent geometry and dimensions include cylindrical plugs and eruptive fissures steeply dipping towards the caldera depression and elongated vents. The flaring area can be rather asymmetric and is usually filled by down-vent rheomorphic flow of the proximal fallout deposit. The lower conduits are filled by lava plug, agglutination of juveniles onto conduit walls and dyke intrusion with eventual dome extrusion. The eruption dynamics of welded fallout deposits and magma fragmentation within the conduit are consistent with an evolution from explosive to effusive. In this context conduit flow regimes evolve from turbulent to annular flow in which the conduit is progressively choked, and laminar flow leading to the final conduit closure.  相似文献   

The additive logistic skew-normal distribution on the simplex     

G. Mateu-Figueras  V. Pawlowsky-Glahn  C. Barceló-Vidal 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(3):205-214

There is a dearth of suitable models with which to adequately model compositional data sets, especially those which exhibit skewness after additive logratio-transformation. In order to address this deficit we propose the additive logistic skew-normal distribution, an extension to the additive logistic normal model on the simplex derived from the skew-normal distribution in real space. The purpose of this paper is to outline the potential of this distribution in the modelling of compositional data. We present its most important properties and use an example to exhibit the potential of this distribution.  相似文献   

Boundary manifolds for energy surfaces in celestial mechanics     

Ernesto A. Lacomba  Carles Simó 《Celestial Mechanics and Dynamical Astronomy》1982,28(1-2):37-48

We complete Mc Gehee's picture of introducing a boundary (total collision) manifold to each energy surface. This is done by constructing the missing components of its boundary as other submanifolds. representing now the asymptotic behavior at infinity.It is necessary to treat each caseh=0,h>0 orh<0 separately. In the first case, we repeat the known result that the behavior at total escape is the same as in total collision. In particular, we explain why the situation is radically different in theh>0 case compared with the zero energy case. In the caseh<0 we have many infinity manifold components. and the general situation is not quite well understood.Finally, our results forh0 are shown to be valid for general homogeneous potentials.Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.The research conducted in this paper has been partially supported by CONACYT (México), under grant PCCBNAL 790178.Partially supported by an Ajut a l'Investigacio of the University of Barcelona.  相似文献   

The Holocene Evolution of the Ebre Delta Catalonia, Spain   总被引：2，自引：0，他引：2  

Antoni Canicio  Carles Iban～ez 《地理学报》1999,54(5)

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