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Gordana Pavlovic Delko Barisic Ivanka Lovrencic Visnja Orescanin Esad Prohic 《Environmental Geology》2005,47(4):475-481
This paper attempts to determine the impact of former Pb-Zn-Ba mining activities in Slovenian drainage basin on overbank sediments of the Sava river (West Croatia). Among the four studied sequences (S7, S8, S9, S10), the most upstream profile S7 showed the most pronounced impact of ore mining. Mercury was enriched more than 100-fold; Pb and Zn had a strong positive correlation (r > 0.99). Two factor models clearly revealed the Pb-Ba-Hg association in the lower-lying carbonate (CA) population of all four profiles, but only in the overlying silicate (SI) population of profile S7. Factor analysis confirmed this association in the total sediment (90 samples) as well as separately in the CA (33 samples) and SI (57 samples) populations. Based on a comparison with an undisturbed soil profile, the vertical distribution of 137Cs in profile S7 was interpreted to be the combination of caesium deposition caused by a flood in 1964 and by post-depositional redistribution. 相似文献
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Granulometric and chemical composition of the Sava River sediments upstream and downstream of the Krsko nuclear power plant 总被引：2，自引：2，他引：0
Visnja?OrescaninEmail author Stipe?Lulic Gordana?Pavlovic Luka?Mikelic 《Environmental Geology》2004,46(5):605-614
Total concentrations of 13 elements (K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Y, Zr, Pb) in the size-fractionated Sava River sediments upstream and downstream of the Krsko nuclear power plant together with metal speciation within bulk sediment have been investigated. Trace metals generally increase with decreasing particle size, however, because of entrapment of organic matter in the 0.63–1 mm fraction, concentrations in the coarser sediment fraction are higher than expected. Exchangeable Pb, Zn, Cu, Mn, Cr and Fe are generally found to represent a negligible fraction of the total metal concentration of the bulk sediment. Seasonal variations of the Pb, Zn and Cu concentrations in the <0.5 mm fraction reflect decreased values during the spring period. Heavy metal concentrations in the 2003 waste water discharges from the Krsko nuclear power plant released into the Sava River were much lower than their maximum allowed values. Combined rubidium and organic matter normalization of the Zn, Pb and Cu concentrations, which was applied on the minus 0.063 mm fraction, indicated three potential sources of contaminants. 相似文献
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Shear-wave splitting and reservoir crack characterization: the Coso geothermal field 总被引：1，自引：0，他引：1
Gordana Vlahovic Maya Elkibbi J.A Rial 《Journal of Volcanology and Geothermal Research》2003,120(1-2):123-140
This paper aims to improve current understanding of the subsurface fracture system in the Coso geothermal field, located in east-central California. The Coso reservoir is in active economic development, so that knowledge of the subsurface fracture system is of vital importance for an accurate evaluation of its geothermal potential and day-to-day production. To detect the geometry and density of fracture systems we applied the shear-wave splitting technique to a large number of high-quality seismograms from local microearthquakes recorded by a permanent, 16-station, down-hole, 3-component seismic array running at 480 samples/s. The analysis of shear-wave splitting (seismic birefringence) provides parameters directly related to the strike of the subsurface fractures and their density (number of cracks per unit volume), and, consequently, is an important technique to outline zones of high permeability. Three major fracture directions N10–30W, N0–20E, and N40–50E, of which the first and the second are the most prominent, were identified from the seismograms recorded by the 16-station down-hole array. All orientations are consistent with the known strike of local sets of faults and fractures in local wells and at the surface, as well as with previous analyses of seismic anisotropy in the region. The high quality of the recordings has allowed us to launch an unprecedented investigation into the characteristics of the temporal variations in crack polarization and crack density in a producing geothermal environment. Preliminary results point to significant temporal changes in shear-wave time delays, probably influenced by temporal changes in crack density within a period of 5 years (1996–2000). They are tentatively interpreted as due to a local 3% increase in shear-wave velocity in the southwestern part of the field during 1999. 相似文献
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Visnja Orescanin Delko Barisic Ivanka Lovrencic Luka Mikelic Martina Rozmaric-Macefat Gordana Pavlovic Stipe Lulic 《Environmental Geology》2005,49(1):53-64
The objective of this study was chemical and radiological characterization of Kastela Bay sediments exposed to numerous anthropogenic sources like deposition of fly and bottom ash enriched in radionuclides and heavy metals, chemical plant, cement plant, iron plant, shipyard, electroplating facility, untreated industrial and domestic waste waters as well as heavy traffic. Totally, 33 samples of the mixture of fly and bottom ash, 12 sediment cores ranging from 0 to 40 cm and nine surface sediment samples were analyzed. Enrichment in heavy metals in the mixture of fly and bottom ash was ranging from 1.5 to 36 times compared to flysch soil while 226Ra and 238U were up to 50 times enriched compared to average activities characteristic for surrounding soils developed on the Middle and Upper Eocene flysch. Maximum 238U activity was approximately 32 times higher and 226Ra approximately 40 times higher in the Kastela Bay sediment compared to mean value determined for Adriatic sediments. The highest enrichment in sediment cores compared to background values were found for Zn (35.6 times), Pb (16 times), Cr (9.1 times) and Ni (4 times) 相似文献
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Gordana DEVIC Petar PFENDT Branimir JOVANCICEVIC Zoran POPOVIC 《《地质学报》英文版》2006,80(4):574-588
The early diagenetic characteristics of pyrite formation processes in a Miocene freshwater sequence of mixed sediments （coal fragments in clays, sandstones or shales） alternating with continuous brown coal layers was investigated. Based on abundant minerals, the following main sedimentary environments were distinguished： the illite-montmorillonitic （I-M）, calcitic （Ct） and coal-forming environment （CL）. For these hydrogeochemically differing environments the effects of limiting factors on the pyrite formation process （availability of sulphate and Fe, amount of organic matter and participation of organic sulphur） were assessed by correlation analysis. Significant differences in the effects of these limiting factors in the particular environments were observed. These differences were explained taking in account the different oxidative activity, Fe-complex and surface complex forming properties of humic substances in dependence of pH of environment and the abundance of sorptionally active clay minerals. In environments having a relatively low pH and containing clay minerals （I-M- and CL-environments） the oxidative activity of humic substances （Hs） on pyrite precursors was greatly prevented however pyrite formation depended on reactive Fe availability as the consequence of complex formation. On the contrary, in environments with a relatively high pH, as it was the calcitic, the oxidative activity of Hs was greatly enhanced, thus oxidizing the sulfur precursors of pyrite. The oxidation degree of organic matter was probably also a consequence of the differing activity of the humic electron-acceptors. 相似文献
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The composition of the saturated hydrocarbon fraction of soluble organic matter (bitumen) from the Krepoljin brown coal basin (East Serbia) of Miocene age was investigated. The Krepoljin basin is especially interesting from a geochemical point of view. Namely, by the end of Tertiary Period, the basin was covered by powerful Mesozoic formations of great possibilities, the bedding became hermetically enclosed and protected from subsequent external influences. The nature of early diagenetic processes in the environment with abundant accumulation of organic substance is defined by the molecular content of bitumen through the connections of molecular structures to potential precursors in paleoplant phylla, as well as by the degree of their diagenetic transformations. The hierarchy of parameters based on molecules of saturated hydrocarbons was determined by applying the principal component analysis to the soluble organic matter. The most significant, most “loadings” values of component C1, are the plant types such as precursors or participants in early diagenetic transformations of steranes Cs27-algal precursor material, Cs28-moulds, Cs29-higher land and water plants; resinous from the group of higher plant gymnosperms (G); also triterpanes α and β-amirin-dicotyledonous angiosperms (A) and bacterial and/or terrestrial plants population represented by hopanes/moretanes; as well as the parameters which describe the degree of diagenetic/maturation transformation of precursor biomass, and based on next reactions: (1) shifting of methyl group, influenced by the inorganic sediment constitutents, sterane-rearranged steranes, (2) isomerization in the ring system, ααα→βββ C29 sterane as well as (3) isomerization on chiral center of the side chain sequence R→S C29 sterane S/(S+R). Additionally, a pyrite-derived inhibitory effect on the rearrangment of C29 steranes must be taken into account, but not on triterpanes reaction. Non-appearance of statistically important correlations, before all with maturational depended parameters, and after all also with source indicators contributies to the affirmation of the newly-suggested parameter α-Phyllocladane/S27 as the real source biomarker of coal. Indicators derived from the distribution and abundance of n-alkanes and isoprenoid alkanes are of less significance in hierarchy of parameters. 相似文献
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本文对赋存于中新统混杂沉积物中淡水序列(如粘土中的煤层夹矸,砂岩以及页岩)与连续的褐煤层相互交替的地层中的黄铁矿及黄铁矿形成过程中早期的成岩特征进行了研究。根据大量的矿物特征观察,黄铁矿形成的主要沉积环境为:伊利石-蒙脱石环境(I-M),方解石环境(Ct)和成煤环境。根据热液地球化学环境与黄铁矿二者的相互关系,本文对不同的热液地球化学环境对黄铁矿形成的影响因素进行了分析。由于影响因素的差异,特定环境下的黄铁矿形成过程具有较大的不同。根据所处环境的pH值以及粘土矿物的吸附性中不同的氧化活动性、铁离子的络合物以及腐殖… 相似文献