Mass‐dependent fractionation of nickel isotopes in meteoritic metal     

David L. COOK  Meenakshi WADHWA  Robert N. CLAYTON  Nicolas DAUPHAS  Philip E. JANNEY  Andrew M. DAVIS 《Meteoritics & planetary science》2007,42(12):2067-2077

Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ～0.4‰ amu^?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (～0.0 to ～0.3‰ amu^?1) and chondrites (～0.0 to ～0.2‰ amu^?1) are similar, whereas the range in pallasite metal (～–0.1 to 0.0‰ amu^?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (～0.0 to ～0.3‰ amu^?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ～0.4‰ amu^?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern.  相似文献   

Mbosi: An anomalous iron with unique silicate inclusions     

Edward J. OLSEN  Robert N. CLAYTON  Toshiko K. MAYEDA  Andrew M. DAVIS  Roy S. CLARKE  John T. WASSON 《Meteoritics & planetary science》1996,31(5):633-639

Abstract— The Mbosi iron meteorite contains millimeter size silicate inclusions. Mbosi is an ungrouped iron meteorite with a Ge/Ga ratio >10, which is an anomalous property shared with the five-member IIF iron group, the Eagle Station pallasites and four other ungrouped irons. Neither the IIF group nor the four other ungrouped irons are known to have silicate inclusions. Chips from three Mbosi inclusions were studied, but most of the work concentrated on a whole 3.1 mm circular inclusion. This inclusion consists of a mantle and a central core of different mineralogies. The mantle is partially devitrified quartz-normative glass, consisting of microscopic crystallites of two pyroxenes and plagioclase, which are crystalline enough to give an x-ray powder diffraction pattern but not coarse enough to permit analyses of individual minerals. The core consists of silica. The bulk composition does not match any known meteorite type, although there is a similarity in mode of occurrence to quartz-normative silicate inclusions in some HE irons. Mbosi silicate appears to be unique. The bulk rare earth element (REE) pattern of the mantle is flat at ? 7×C1; the core is depleted in REE but shows a small positive Eu anomaly. The O-isotope composition of bulk silicate lies on a unit slope mixing line (parallel and close to the C3 mixing line) that includes the Eagle Station pallasites and the iron Bocaiuva (related to the IIF irons); all of these share the property of having Ge/Ga ratios >10. It is concluded that Mbosi silicate represents a silica-bearing source rock that was melted and injected into metal. Melting occurred early in the history of the parent body because the metal now shows a normal Widmanstätten structure with only minor distortion that was caused when the parent body broke up and released meteorites into interplanetary space. The cause of Ge/Ga ratios being >10 in these irons is unknown. The fact that silicates in Mbosi, Bocaiuva (related to IIF irons) and the Eagle Station trio of pallasites, all characterized by a Ge/Ga ratio >10, lie on a unit slope mixing line in the O-isotope diagram suggests that their origins are closely related. The C3 chondrites appear to be likely precursors for silicates in Mbosi, Bocaiuva and the Eagle Station pallasites.  相似文献   

Formation of orange hibonite,as inferred from some Allende inclusions     

S. B. SIMON  A. M. DAVIS  L. GROSSMAN 《Meteoritics & planetary science》2001,36(3):331-350

Abstract— We studied three fluffy Type A refractory inclusions from Allende that contain orange hibonite. The melilite in the present samples is very Al‐rich, averaging Åk₆, Åk₁₄, and Åk₁₂ in the three samples studied. Hibonite in two inclusions, unlike that in Murchison, has low rare earth element abundances of <10 × CI; in the other inclusion, the hibonite, melilite and perovskite have Group II‐like patterns. The hibonite and melilite in all three inclusions studied have excess ²⁶Mg consistent with (²⁶Al/²⁷Al)_I = 5 × 10^?5. Much of the hibonite and some of the spinel in these inclusions is corroded. These phases are found enclosed in melilite, but based on bulk compositions and phase equilibria, hibonite should not be an early‐crystallizing phase in these inclusions. We conclude that the hibonite and probably some of the spinel is relic. Reversely zoned melilite, rounded spinel and isotopically heavy Mg in the inclusions probably reflect reheating events that involved melting and evaporation. Alteration of the gehlenitic melilite gave rise to some rare phases, including corundum and nearly pure CaTs pyroxene. Studies have shown that blue hibonite contains Ti³⁺ while orange hibonite does not (Ihinger and Stolper, 1986; Beckett et al., 1988). Orange hibonite formed either under oxidizing conditions (such as at oxygen fugacities at least seven orders of magnitude greater than that of a solar gas at 1700 K), or under conditions reducing enough (e.g., solar) that it contained Ti³⁺, which was later oxidized in situ. Although V and Ce oxides are volatile at the temperature and range of oxygen fugacities at which orange hibonite is known to be stable, we find that (a) the hibonite is V‐rich (～1 wt% V₂O₃) and (b) there are no negative Ce anomalies in Allende hibonite. This indicates that the hibonite did not form by condensation under oxidizing conditions. In addition, there are slight excesses of Ti + Si cations relative to Mg + Fe cations (up to 0.1 of 0.8 cations per 19 oxygen anions), probably reflecting the original presence of Ti³⁺. The results of this study strongly support the suggestion (Ihinger and Stolper, 1986) that Allende hibonite originally formed under reducing conditions and was later oxidized. Oxygen fugacities within ～2–3 orders of magnitude of that of a solar gas are implied; otherwise, strong Ce and V depletions would be observed.  相似文献   

Porphyroblast inclusion-trail orientation data: eppure non son girate*!     

T. H. BELL  S. E. JOHNSON  B. DAVIS  A. FORDE  N. HAYWARD  C. WILKINS 《Journal of Metamorphic Geology》1992,10(3):295-307

Extensive examination of large numbers of spatially orientated thin sections of orientated samples from orogens of all ages around the world has demonstrated that porphyroblasts do not rotate relative to geographical coordinates during highly non-coaxial ductile deformation of the matrix subsequent to their growth. This has been demonstrated for all tectonic environments so far investigated. The work also has provided new insights and data on metamorphic, structural and tectonic processes including: (1) the intimate control of deformation partitioning on metamorphic reactions; (2) solutions to the lack of correlation between lineations that indicate the direction of movement within thrusts and shear zones, and relative plate motion; and (3) a possible technique for determining the direction of relative plate motion that caused orogenesis in ancient orogens.  相似文献   

Fluid infiltration during contact metamorphism of interbedded marble and calc-silicate hornfels, Twin Lakes area, central Sierra Nevada, California     

S. R. DAVIS  J. M. FERRY 《Journal of Metamorphic Geology》1993,11(1):71-88

Abstract In the Twin Lakes area, central Sierra Nevada, California, most contact metamorphosed marbles contain calcite + dolomite + forsterite ± diopside ± phlogopite ± tremolite, and most calc-silicate hornfelses contain calcite + diopside + wollastonite + quartz ± anorthite ± K-feldspar ± grossular ± titanite. Mineral-fluid equilibria involving calcite + dolomite + tremolite + diopside + forsterite in two marble samples and wollastonite + anorthite + quartz + grossular in three hornfels samples record P± 3 kbar and T± 630° C. Various isobaric univariant assemblages record CO₂-H₂O fluid compositions of χCO₂= 0.61–0.74 in the marbles and χCO₂= 0.11 in the hornfelses. Assuming a siliceous dolomitic limestone protolith consisting of dolomite + quartz ° Calcite ± K-feldspar ± muscovite ± rutile, all plausible prograde reaction pathways were deduced for marble and hornfels on isobaric T-XCO₂ diagrams in the model system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂. Progress of the prograde reactions was estimated from measured modes and mass-balance calculations. Time-integrated fluxes of reactive fluid which infiltrated samples were computed for a temperature gradient of 150 °C/km along the fluid flow path, calculated fluid compositions, and estimated reaction progress using the mass-continuity equation. Marbles and hornfelses record values in the range 0.1–3.6 × 10⁴ cm³/cm² and 4.8–12.9 × 10⁴ cm³/cm², respectively. For an estimated duration of metamorphism of 10⁵ years, average in situ metamorphic rock permeabilities, calculated from Darcy's Law, are 0.1–8 × 10^?6 D in the marbles and 10–27 × 10^?6 D in the hornfelses. Reactive metamorphic fluids flowed up-temperature, and were preferentially channellized in hornfelses relative to the marbles. These results appear to give a general characterization of hydrothermal activity during contact metamorphism of small pendants and screens (dimensions ± 1 km or less) associated with emplacement of the Sierra Nevada batholith.  相似文献   

Gould Pond, Maine: late-glacial transitions from marine to upland environments     

R. SCOTT ANDERSON  GEORGE L. JACOBSON JR.    RONALD B. DAVIS  ROBERT STUCKENRATH 《Boreas: An International Journal of Quaternary Research》1992,21(4):359-371

Gould Pond sediments are unusual in North America in that they include a continuous record of change from marine to freshwater conditions during the late-glacial period, with a wide array of micro- and macrofossils deposited during a period of high sedimentation rate. Marine waters, much colder than those in the present Gulf of Maine, covered the site at the time of deglaciation (c. 13,200 BP). Plants characteristic of modem tundra grew on nearby uplands. Marine recession, due to isostatic rebound of the land, occurred from c . 12,800–12,200 BP. The lake water was completely freshened by 12,000 BP. A sparse shrub-herb tundra became established around Gould Pond as marine waters receded. Subsequent to 11,300 BP, sedges and other herbs became more abundant, and willow and Dryas less abundant, signifying increased warmth and decreased frost action. At least six tree species, all now common in the area, arrived around Gould Pond between c . 10,800 and 10,500 BP. This rapid transition was coincident with the most rapid major non-anthropogenic change of vegetation at sites across eastern North America during the postglacial period.  相似文献   

燕山地区褶皱冲断带和盆地中的晚侏罗世土城子组/后城组形成分析(英文)     

Gregory A.DAVIS 《地学前缘》2005,(4)

土城子组/后城组为广泛分布在中国北方的燕山褶皱冲断带和盆地中晚侏罗世的典型碎屑岩沉积。本文主要是针对目前在燕山地区的通行的有关土城子组/后城组、及其之下的髫髻山组/蓝旗组,和上覆的张家口组/东岭台组火山岩的相关对比方法提出质疑。其他同行近期发表相关的氩-氩法和铀-铅法同位素测年数据指出髫髻山组/蓝旗组年龄为175~147Ma、土城子组/后城组年龄为156~139Ma、张家口组/东岭台组年龄为147~127Ma,显而易见,上述地层组的年龄是相互重叠的。这些测年数据说明以往的地层对比是有问题的,燕山造山带在中、晚侏罗世所发育的火山岩和沉积岩地层是穿时的。因此,传统上用(165±5)Ma和(135±5)Ma之间的区域不整合来作为划分髫髻山组和后城组的层序界限是值得商榷的。尽管一些髫髻山组的火山岩和土城子组/后城组的沉积岩是与向南或向北的冲断作用相伴生的,但在髫髻山组和土城子组/后城组沉积之间的30~35Ma的时间间隔内却是相对的构造平静期。这一结论是基于以往的髫髻山组和土城子组之间为假整合或平行不整合的观点所得出的。新近基于对承德盆地土城子组地层形成研究分析认为承德冲断层的实际位移距离应小于Davis等2001年所提出的位移距离,笔者接受这一观点。但笔者并不同意在承德地区土城子组的沉积主要是受控于承德北部的向南冲断作用。现今承德向形盆地主要是由于向北冲断的承德县冲断层下盘变形的结果,主要是(1)它向北发生倒转;(2)盆地南部的粗碎屑沉积的物源主要是来源于承德县的异地体。土城子组/后城组的沉积没有必要完全受控于构造作用。土城子组/后城组的沉积是紧随着在燕山部分地区发生的,持续了20~25Ma的髫髻山组/蓝旗组火山及岩浆活动。在中、晚侏罗世期间,燕山地区的岩浆活动必定导致地形的起伏,这就为快速剥蚀及粗碎屑的沉积提供了有利条件。最后需要指出的是,从前所提及的有关燕山带的土城子组/后城组和阴山带的大青山组的地层对比的依据并不存在。  相似文献   

Evolution of Bishop Tuff Rhyolitic Magma Based on Melt and Magnetite Inclusions and Zoned Phenocrysts   总被引：15，自引：7，他引：8  

ANDERSON  ALFRED T.; DAVIS  ANDREW M.; LU  FANGQIONG 《Journal of Petrology》2000,41(3):449-473

The evolution of large bodies of silicic magma is an importantaspect of planetary differentiation. Melt and mineral inclusionsin phenocrysts and zoned phenocrysts can help reveal the processesof differentiation such as magma mixing and crystal settling,because they record a history of changing environmental conditions.Similar major element compositions and unusually low concentrationsof compatible elements (e.g. 0·45–4·6 ppmBa) in early-erupted melt inclusions, matrix glasses and bulkpumice from the Bishop Tuff, California, USA, suggest eutectoidfractional crystallization. On the other hand, late-eruptedsanidine phenocrysts have rims rich in Ba, and late-eruptedquartz phenocrysts have CO₂-rich melt inclusions closest tocrystal rims. Both features are the reverse of in situ crystallizationdifferentiation, and they might be explained by magma mixingor crystal sinking. Log(Ba/Rb) correlates linearly with log(Sr/Rb)in melt inclusions, and this is inconsistent with magma mixing.Melt inclusion gas-saturation pressure increases with CO₂ fromphenocryst core to rim and suggests crystal sinking. Some inclusionsof magnetite in late-erupted quartz are similar to early-eruptedmagnetite phenocrysts, and this too is consistent with crystalsinking. We argue that some large phenocrysts of late-eruptedquartz and sanidine continued to crystallize as they sank severalkilometers through progressively less differentiated melts.Probable diffusive modification of Sr in sanidine phenocrystsand the duration of crystal sinking are consistent with an evolutionaryinterval of some 100 ky or more. Crystal sinking enhanced thedegree of differentiation of the early-erupted magma and pointsto the importance of H₂O (to diminish viscosity and enhancethe rate of crystal sinking) in the evolution of silicic magmas. KEY WORDS: crystal settling; differentiation; melt inclusions; rhyolite; trace elements  相似文献   

The Yanshan Allochthon of North China: ≥ 40 Million Years of Late Jurassic-Early Cretaceous Mid-Crustal Detachment     

Gregory A DAVIS  XIA Haoran 《《地质学报》英文版》2013,87(Z1):127-130

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失水对海洋沉积物磁学性质的影响     

李明坤  欧阳婷萍  田成静  朱照宇  唐志华  彭学超  邱燕  钟和贤． 《热带地理》2016,36(3):438-447

为了探究沉积物的干燥过程及方式对其磁学性质的影响,选取含水率高的南海沉积物样品,对其中685个样品在自然条件下逐步晾干,并每间隔40 d测量1次低频磁化率（κlf）、高频磁化率（κhf）、饱和等温剩磁（SIRM）、S-300和频率磁化率系数（κfd）,共测量5次;对另外60个样品进行冷冻干燥,并在干燥前后测量相同的磁学参数。结果表明：1）自然晾干过程中,除少数异常点（约7%）外,大多数样品的κlf和κhf呈减小趋势,少数样品呈增大趋势,S-300和κfd均呈减小趋势,SIRM先减后增,整体上呈增大趋势;2）冷冻干燥过程中,样品的κlf、κhf、S-300和κfd呈增大趋势,SIRM呈减小趋势;3）2种干燥方法均不影响κlf、κhf、SIRM和S-300的剖面变化趋势,但对κfd的影响较大,这在磁学指标的古环境研究中具有关键的指示意义。磁学参数的变化,可能是由于失水过程发生的微弱氧化作用、失水导致水的抗磁性“负贡献”降低、细粒磁铁矿和磁赤铁矿在湿润状态下转变成顺磁性和不完全反铁磁性等综合因素造成的。建议对同一批次的样品采取相同的干燥方法。  相似文献