Mercury cycling during acid rain recovery at the forested Lesní potok catchment,Czech Republic     

Tomáš Navrátil  James B. Shanley  Jan Rohovec  Irena Dobešová  Šárka Matoušková  Michal Roll  Tereza Nováková  Filip Oulehle 《水文研究》2021,35(6):e14255

From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m⁻² year⁻¹, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m⁻² year⁻¹ for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m⁻² year⁻¹, compared to the estimated Hg output in runoff of 0.5 μg m⁻² year⁻¹, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m⁻², only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by ¹⁴C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.  相似文献   

Fluvial dynamics and 14C-10Be disequilibrium on the Bolivian Altiplano     

Kristina Hippe  Tiemen Gordijn  Vincenzo Picotti  Irka Hajdas  John D. Jansen  Marcus Christl  Christof Vockenhuber  Colin Maden  Naki Akçar  Susan Ivy-Ochs 《地球表面变化过程与地形》2019,44(3):766-780

Determining sediment transfer times is key to understanding source-to-sink dynamics and the transmission of environmental signals through the fluvial system. Previous work on the Bolivian Altiplano applied the in situ cosmogenic ¹⁴C-¹⁰Be-chronometer to river sands and proposed sediment storage times of ~10–20 kyr in four catchments southeast of Lake Titicaca. However, the fidelity of those results hinges upon isotopic steady-state within sediment supplied from the source area. With the aim of independently quantifying sediment storage times and testing the ¹⁴C-¹⁰Be steady-state assumption, we dated sediment storage units within one of the previously investigated catchments using radiocarbon dating, cosmogenic ¹⁰Be-²⁶Al isochron burial dating, and ¹⁰Be-²⁶Al depth-profile dating. Palaeosurfaces appear to preserve remnants of a former fluvial system, which has undergone drainage reversal, reduction in catchment area, and local isostatic uplift since ~2.8 Ma. From alluvium mantling the palaeosurfaces we gained a deposition age of ~580 ka, while lower down fluvial terraces yielded ≤34 ka, and floodplains ~3–1 ka. Owing to restricted channel connectivity with the terraces and palaeosurfaces, the main source of channel sediment is via reworking of the late Holocene floodplain. Yet modelling a set of feasible scenarios reveals that floodplain storage and burial depth are incompatible with the ¹⁴C-¹⁰Be disequilibrium measured in the channel. Instead we propose that the ¹⁴C-¹⁰Be offset results from: (i) non-uniform erosion whereby deep gullies supply hillslope-derived debris; and/or (ii) holocene landscape transience associated with climate or human impact. The reliability of the ¹⁴C-¹⁰Be chronometer vitally depends upon careful evaluation of sources of isotopic disequilibrium in a wide range of depositional and erosional landforms in the landscape. © 2018 John Wiley & Sons, Ltd.  相似文献   

Mercury capture by selected Bulgarian fly ashes: Influence of coal rank and fly ash carbon pore structure on capture efficiency   总被引：1，自引：0，他引：1  

Irena J. Kostova  Maria MastalerzStanislav V. Vassilev 《Applied Geochemistry》2011,26(1):18-27

Mercury capture by fly ash C was investigated at five lignite- and subbituminous-coal-burning Bulgarian power plants (Republika, Bobov Dol, Maritza East 2, Maritza East 3, and Sliven). Although the C content of the ashes is low, never exceeding 1.6%, the Hg capture on a unit C basis demonstrates that the low-rank-coal-derived fly ash carbons are more efficient in capturing Hg than fly ash carbons from bituminous-fired power plants. While some low-C and low-Hg fly ashes do not reveal any trends of Hg versus C, the 2nd and, in particular, the 3rd electrostatic precipitator (ESP) rows at the Republika power plant do have sufficient fly ash C range and experience flue gas sufficiently cool to capture measurable amounts of Hg. The Republika 3rd ESP row exhibits an increase in Hg with increasing C, as observed in other power plants, for example, in Kentucky power plants burning Appalachian-sourced bituminous coals. Mercury/C decreases with an increase in fly ash C, suggesting that some of the C is isolated from the flue gas stream and does not contribute to Hg capture. Mercury capture increases with an increase in Brunauer-Emmett-Teller (BET) surface area and micropore surface area. The differences in Hg capture between the Bulgarian plants burning low-rank coal and high volatile bituminous-fed Kentucky power plants suggests that the variations in C forms resulting from the combustion of the different ranks also influence the efficiency of Hg capture.  相似文献   

Ten-year record of Thalassiosira nordenskioeldii population dynamics: comparison of aquaculture and non-aquaculture sites in the Quoddy Region     

Smith  Aaron C.; Martin  Jennifer L.; Ehrman  James M.; Kaczmarska  Irena 《ICES Journal of Marine Science》2001,58(2):391-397

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Regional deformation of late Quaternary fluvial sediments in the Apennines foreland basin (Emilia,Italy)     

Stefani  Marco  Minarelli  Luca  Fontana  Alessandro  Hajdas  Irka 《International Journal of Earth Sciences》2018,107(7):2433-2447

International Journal of Earth Sciences - Our research is aimed at estimating the vertical deformation affecting late Quaternary units accumulated into the foreland basin of the Northern Apennines...  相似文献   

Alpine thermal events in the central Serbo-Macedonian Massif (southeastern Serbia)     

Milorad D. Antić  Alexandre Kounov  Branislav Trivić  Andreas Wetzel  Irena Peytcheva  Albrecht von Quadt 《International Journal of Earth Sciences》2016,105(5):1485-1505

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Properties and depositional environment of the Neogene Elhovo Lignite, Bulgaria     

Alexander Zdravkov  Irena Kostova  Jordan Kortenski 《International Journal of Coal Geology》2007,71(4):488

Several Mio-Pliocene aged lignite seams occur as part of a non-marine transgressive sequence in the Elhovo graben in south-eastern Bulgaria. The present study is focused on 45 samples collected from three boreholes in the eastern part of the basin. Petrographic data along with ash and sulphur contents were used in order to determine the lateral and vertical variations of the coal facies and depositional environment of the Elhovo lignite.The lignite seams accumulated in a rheotrophic, low-lying mire with high pH value and are characterized by high ash yields and sulphur contents. Despite of the neutral to weakly alkaline environment the bacterial activity was limited and the tissue preservation and gelification were mainly controlled by the redox conditions.Vegetation rich in decay resistant conifers dominated in the Elhovo basin together with mesophytic angiosperm species. The absence of algal remains and sapropelic coal indicated that open water areas were not present during peat accumulation. The latter processed in an environment, characterized by low subsidence rate, in which prior to the burial the woods were subjected to severe mechanical destruction. According to our interpretation, the enhanced impregnation of the tissues bacteria and fungi played only a secondary role in the process of humification. The lignite from borehole 122 and partly from BH 145 deposited in an environment characterized by relatively low (ground)water table, whereas to the south an area dominated by a flooded forest swamp (BH 104) formed. This is suggested by the better tissue preservation and gelification of the organic matter in BH 104. The vertical variation of the maceral composition in the studied lignite is interpreted as a consequence of vegetational changes, rather than to changes in the depositional environment. The low contents of inertinite macerals indicate that despite of the low water level the environment was relatively wet and the thermal and oxidative destruction of the tissues was limited.Peat accumulation was terminated by a major flooding event and a short term establishment of a lake. In contrast to the West Maritsa basin, no seam formed in the Elhovo basin during the filling stage of the lake.  相似文献   

Timing of the late-glacial climate reversal in the Southern Hemisphere using high-resolution radiocarbon chronology for Kaipo bog, New Zealand     

Irka Hajdas  David J. Lowe  Georges Bonani 《Quaternary Research》2006,65(2):340-345

The pattern of climate change in the Southern Hemisphere during the Younger Dryas (YD) chronozone provides essential constraint on mechanisms of abrupt climate change only if accurate, high-precision chronologies are obtained. A climate reversal reported previously at Kaipo bog, New Zealand, had been dated between 13,600 and 12,600 cal yr B.P. and appeared to asynchronously overlap the YD chron, but the chronology, based on conventionally radiocarbon-dated bulk sediment samples, left the precise timing questionable. We report a new high-resolution AMS ¹⁴C chronology for the Kaipo record that confirms the original chronology and provides further evidence for a mid-latitude Southern Ocean cooling event dated between 13,800 and 12,400 cal yr B.P. (2σ range), roughly equivalent to the Antarctic Cold Reversal.  相似文献   

Occurrence and morphology of pyrite in Bulgarian coals   总被引：2，自引：0，他引：2  

Jordan Kortenski  Irena Kostova 《International Journal of Coal Geology》1996,29(4):273-290

Coals with different degrees of coalification (ranging from lignite to anthracite) from seven Bulgarian coal basins have been investigated. The forms of pyrite and their distribution have been established. The types found are: massive pyrite, represented by the homogeneous, cluster-like and microconcretionary varieties; framboidal pyrite, appearing in inorganic and bacterial forms; euhedral pyrite, which is either isolated or clustered; anhedral pyrite, in its infilling and replacement varieties; and infiltrational pyrite, as a replacement or infilling mineral.Most of the forms of the euhedral, framboidal and massive pyrite developed during peat deposition. The anhedral replacement pyrite formed in the peat bed during early diagenesis. Infiltrational pyrite filled fractures and cleats formed during the diagenesis, catagenesis and metagenesis.Both similarities and differences with respect to the distribution of the pyrite types have been determined between coals of different ranks from Bulgarian coal basins. These differences are due to: the presence of Fe and S in the rocks adjacent to ancient peat bogs; the activities of ground and surface waters which brought Fe and S into the peat bogs; the geochemical character (pH and Eh) of the peat bogs and the sulphur bacteria development; and the tectonic situation during diagenesis, catagenesis and metagenesis.  相似文献   

Climatically relevant periodicities in the thickness of biogenic carbonate varves in Spooensee, Switzerland (9740-6870 calendar yr BP)     

David M. Livingstone  Irka Hajdas 《Journal of Paleolimnology》2001,25(1):17-24

Accurate determination of the thicknesses of 2717 biogenic carbonate varves from a Swiss lake (Soppensee), spanning the period from about 9740 to 6870 calendar yr BP, allowed the computation of a power spectrum using classical FFT methods. The presence of pronounced peaks at 40-50 and 20-25 yr agrees with the results of other studies on varve thickness and D¹⁴C which have been interpreted as indicating an association between solar forcing and varve thickness. The presence in the Soppensee varve series of an additional peak at 10.9 yr, corresponding to the Schwabe sunspot cycle, lends further support to this hypothesis. Because the Soppensee varves are of biogenic rather than clastic origin, any influence fluctuations in solar irradiance may have had on sedimentation rates is likely to have been exerted via primary production.  相似文献