In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

Syn-metamorphic nappe complex in the Rhodope Massif. Structure and kinematics     

Jean-Pierre Burg  Luc-Emmanuel Ricou  Zivko Ivano  Ivan Godfriaux  Dimo Dimov  Laslo Klain 《地学学报》1996,8(1):6-15

Mylonitic gneisses of the Bulgarian and Greek Rhodope were deformed under medium pressure-type metamorphism. The kinematic information contained in these gneisses shows that shear-deformation occurred during development of a nappe complex. Lithologies and metamorphic histories allow a lower (footwall) and an upper (hanging wall) terrane to be distinguished that define a crustal-scale duplex. As oceanic crust is involved, collision between two continental units with subsequent crustal thickening is inferred. The blocks would be Moesia to the north, and the Lower-Rhodope promontory to the south, which collided in the Mesozoic to early Cenozoic. The nappe complex is characterized by south to southwestward (foreland directed) piling-up and is associated with both coeval and subsequent extension. The late extension is associated with the establishment of a high temperature-low pressure metamorphic gradient and plutonism that predates, but makes a transition to, the lithospheric extension of the Aegean Arc.  相似文献   

Chemical characterization of fine particulate matter during peak PM10 episodes in Apulia (South Italy)     

Martino Amodio  Paolo Bruno  Maurizio Caselli  Gianluigi de Gennaro  Paolo Rosario Dambruoso  Barbara Elisabetta Daresta  Pieirna Ielpo  Francesco Gungolo  Claudia Marcella Placentino  Vincenzo Paolillo  Maria Tutino 《Atmospheric Research》2008,90(2-4):313-ICNAA07

Some peak PM10 episodes, occurred during PM monitoring campaigns performed on October 2005 and February and June 2006 in Bari town, have been characterized. Moreover back trajectories of air masses and Principal Component Analyses were applied. Three of the peak PM10 episodes investigated were related to local emissions of primary pollutants during poor atmospheric dispersion conditions. The other two peak PM10 episodes considered are related with long range transport air masses toward Apulia region: in one case the chemical characterization and the back trajectories analysis indicate that high PM10 value detected is due to the Saharan dust advection in the Apulia region; in the other case air masses with different origin give rise to high PM10 value.Moreover PM10 daily mean concentrations, presented in this paper collected from January 2005 to August 2007 and obtained by automatic device in six stations of air quality monitoring networks in Bari territory, do not show a seasonal trend for PM10 concentrations, contrary to the PM10 trend shown in the towns of North Italy. This can be explained mostly considering that our region presents generally meteo-climatic conditions that favour pollutants dispersion.  相似文献   

Performance of a Pier Group Foundation in Swelling Rock   总被引：1，自引：0，他引：1  

Gennaro Marino  Abdolreza Osouli  Siavash Zamiran  Iman Shafii 《Geotechnical and Geological Engineering》2017,35(1):91-109

Foundations on claystone with swell potential may experience upward movement and failure. In this case study, the cause of 58 mm upward movement of drilled-in piers is analyzed using survey data, extensometer readings, and moisture content monitoring of claystone at the site. Laboratory swell tests were conducted to characterize the swelling characteristics of the weathered rock. A swell potential analysis for the pier group foundations is presented. The interaction of the pier group with the swelling rock is considered in analyzing the initiation of the upward movement. Furthermore, a novel inverse analysis method is presented to integrate the laboratory swell test results and numerical modeling to identify the representative swell pressures acting on the pier group as well as upward movement of the pier system. The numerical analysis indicates that the studied pier system is expected to have 135 mm heave and its rate of upward movement is compared with field observations. The behavior of the pier group foundation in swelling rock under various pier spacings and superstructure pressures shows that the uplift is considerably less for piers with smaller center-to-center spacing. The results of pier group numerical modeling provide the correlation of upward deformation changes due to center-to-center spacing of the piers, pier diameters and superstructure pressures.  相似文献   

Quantifying the building stock from optical high-resolution satellite imagery for assessing disaster risk     

Daniele Ehrlich  Gunter Zeug  Javier Gallego  Andrea Gerhardinger  Ivano Caravaggi  Martino Pesaresi 《国际地球制图》2013,28(4):281-293

This study uses high-resolution (HR) satellite imagery to quantify the stock of buildings, referred herein as building stock. The risk assessment requires information on the natural hazards and on the element at risk, that is the building stock in this article. This study combines (1) texture-based image processing to map built-up areas, (2) statistical sampling that allows locating the building samples and (3) photo-interpretation to encoding building footprints. Statistical inference is then used to quantify the building stock per class of building size. Legaspi in the Philippines is used as a case study. The results show that texture-based computer algorithms provide accurate area estimations of the built-up, that the detail of HR imagery allows the mapping of single buildings using photo-interpretation, and that a systematic sampling approach that uses building encoding and built-up maps can be used to quantify the building stock.  相似文献   

Diel variation of selenium and arsenic in a wetland of the Great Salt Lake, Utah   总被引：1，自引：0，他引：1  

Gennaro DicataldoWilliam P. Johnson  David L. NaftzDonald F. Hayes  William O. MoellmerTheron Miller 《Applied Geochemistry》2011,26(1):28-36

Diel (24-h) changes in Se and As concentrations in a freshwater wetland pond bordering the Great Salt Lake (GSL) were examined. Selenium concentrations (filtered and unfiltered) changed on a diel basis, i.e., were depleted during early morning and enriched during daytime over August 17-18. During the May 24-25, 2006 and September 29-30 diel studies, no significant 24-h trends were observed in Se concentrations compared to August, which showed daily maximums up to 59% greater than the daily minimum. Both filtered and unfiltered As concentrations also varied on a diel cycle, with increased concentrations during early morning and decreased concentrations during daytime. Filtered As concentrations increased 110% during the May 24-25, 2006 diel study. Selenium varied in phase with pH, dissolved O₂ (DO), and water temperature (T_w) whereas As varied opposite to Se, pH, DO and T_w. Changes in pH, DO and T_w showed a direct linear correlation (r = 0.74, 0.75, and 0.55, respectively) to filtered Se. Also pH, DO and T_w were inversely correlated to filtered As concentration (r = −0.88, −0.87, and −0.84, respectively). Equilibrium geochemical speciation and sorption models were used to examine the potential oxidation state changes in Se and As, and sorption and desorption reactions corresponding to the observed 24-h variations in pe and pH. In this wetland it was postulated that diel Se variation was driven by sorption and desorption due to photosynthesis-induced changes in pH and redox conditions. Diel variations of As were hypothesized to be linked to pH-driven sorption and desorption as well as co-precipitation and co-dissolution with mineral phases of Mn.  相似文献   

The thermal stability of sideronatrite and its decomposition products in the system Na2O–Fe2O3–SO2–H2O     

Gennaro Ventruti  Fernando Scordari  Giancarlo Della Ventura  Fabio Bellatreccia  Alessandro F. Gualtieri  Andrea Lausi 《Physics and Chemistry of Minerals》2013,40(8):659-670

The thermal stability of sideronatrite, ideally Na₂Fe³⁺(SO₄)₂(OH)·3(H₂O), and its decomposition products were investigated by combining thermogravimetric and differential thermal analysis, in situ high-temperature X-ray powder diffraction (HT-XRPD) and Fourier transform infrared spectroscopy (HT-FTIR). The data show that for increasing temperature there are four main dehydration/transformation steps in sideronatrite: (a) between 30 and 40 °C sideronatrite transforms into metasideronatrite after the loss of two water molecules; both XRD and FTIR suggest that this transformation occurs via minor adjustments in the building block. (b) between 120 and 300 °C metasideronatrite transforms into metasideronatrite II, a still poorly characterized phase with possible orthorhombic symmetry, consequently to the loss of an additional water molecule; X-ray diffraction data suggest that metasideronatrite disappears from the assemblage above 175 °C. (c) between 315 and 415 °C metasideronatrite II transforms into the anhydrous Na₃Fe(SO₄)₃ compound. This step occurs via the loss of hydroxyl groups that involves the breakdown of the [Fe³⁺(SO₄)₂(OH)] _∞ ^2? chains and the formation of an intermediate transient amorphous phase precursor of Na₃Fe(SO₄)₃. (d) for T > 500 °C, the Na₃Fe(SO₄)₃ compound is replaced by the Na-sulfate thenardite, Na₂SO₄, plus Fe-oxides, according to the Na₃Fe³⁺(SO₄)₃ → 3/2 Na₂(SO₄) + 1/2 Fe₂O₃ + SO_x reaction products. The Na–Fe sulfate disappears around 540 °C. For higher temperatures, the Na-sulfates decomposes and only hematite survives in the final product. The understanding of the thermal behavior of minerals such as sideronatrite and related sulfates is important both from an environmental point of view, due to the presence of these phases in evaporitic deposits, soils and sediments including extraterrestrial occurrences, and from the technological point of view, due to the use of these materials in many industrial applications.  相似文献   

Red micas from basal ignimbrites of Mt. Vulture (Italy): interlayer content appraisal by a multi-methodic approach     

Fernando Scordari  Emanuela Schingaro  Gennaro Ventruti  Maria Lacalamita  Luisa Ottolini 《Physics and Chemistry of Minerals》2008,35(3):163-174

The crystal chemistry of red phlogopites from Mt. Vulture (Italy) ignimbrites has been studied by electron microprobe, secondary ion mass spectrometry (SIMS), single crystal structural investigation and Fourier transform infrared (FTIR) spectroscopy. The analysed phlogopite has Fe/(Fe + Mg) ∼ 0.35, TiO₂ (wt%): 2.8–5.0 and H₂O (wt%): 1.24–3.37. Infrared spectra revealed the presence of bands due to the NH₄⁺ and H₂O stretching and bending vibrations. The samples belong to the 1M polytype. The bimodal behaviour of several structural parameters allows red micas to be clustered into two distinct groups: K⁺ ↔ NH₄⁺, H₂O and M³⁺-vacancy substitutions dominate in the first group; M^3+,4+-oxy, in the second group. It has to be pointed out that quantitative analysis of hydrogen (via SIMS) together with the characterization of the local environment of the anionic site (via FTIR) are fundamental in assessing the correct structural formula and the substitution mechanisms in micas. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Models of Jupiter's growth incorporating thermal and hydrodynamic constraints     

Jack J. Lissauer  Olenka Hubickyj  Gennaro D'Angelo  Peter Bodenheimer 《Icarus》2009,199(2):338-350

We model the growth of Jupiter via core nucleated accretion, applying constraints from hydrodynamical processes that result from the disk-planet interaction. We compute the planet's internal structure using a well tested planetary formation code that is based upon a Henyey-type stellar evolution code. The planet's interactions with the protoplanetary disk are calculated using 3-D hydrodynamic simulations. Previous models of Jupiter's growth have taken the radius of the planet to be approximately one Hill sphere radius, RH. However, 3-D hydrodynamic simulations show that only gas within ∼0.25RH remains bound to the planet, with the more distant gas eventually participating in the shear flow of the protoplanetary disk. Therefore in our new simulations, the planet's outer boundary is placed at the location where gas has the thermal energy to reach the portion of the flow not bound to the planet. We find that the smaller radius increases the time required for planetary growth by ∼5%. Thermal pressure limits the rate at which a planet less than a few dozen times as massive as Earth can accumulate gas from the protoplanetary disk, whereas hydrodynamics regulates the growth rate for more massive planets. Within a moderately viscous disk, the accretion rate peaks when the planet's mass is about equal to the mass of Saturn. In a less viscous disk hydrodynamical limits to accretion are smaller, and the accretion rate peaks at lower mass. Observations suggest that the typical lifetime of massive disks around young stellar objects is ∼3 Myr. To account for the dissipation of such disks, we perform some of our simulations of Jupiter's growth within a disk whose surface gas density decreases on this timescale. In all of the cases that we simulate, the planet's effective radiating temperature rises to well above 1000 K soon after hydrodynamic limits begin to control the rate of gas accretion and the planet's distended envelope begins to contract. According to our simulations, proto-Jupiter's distended and thermally-supported envelope was too small to capture the planet's current retinue of irregular satellites as advocated by Pollack et al. [Pollack, J.B., Burns, J.A., Tauber, M.E., 1979. Icarus 37, 587-611].  相似文献   

Characterization of particulate matter in the Apulia Region (South of Italy): features and critical episodes     

Martino Amodio  Eleonora Andriani  Maurizio Caselli  Paolo R. Dambruoso  Barbara E. Daresta  Gianluigi de Gennaro  Pierina Ielpo  Claudia M. Placentino  Maria Tutino 《Journal of Atmospheric Chemistry》2009,63(3):203-220

The chemical composition of PM₁₀ and PM_2.5 samples collected during two seasonal monitoring campaigns at residential, urban and industrial Apulia Region- sites was investigated. Ionic fraction, carbonaceous compounds and Polycyclic Aromatic Hydrocarbons were determined for all samples. High correlations among PM data collected in the investigated sites suggested the regional character of particulate matter. It was also confirmed by five days back trajectories analysis. Moreover, no significant seasonal trend in PM mass concentration was observed in the investigated sites. These results, relevant for the area under investigations, were not observed in the North of Italy and Europe and allow to conclude that PM₁₀ and PM_2.5 cannot be considered ‘good’ indicators for the evaluation of local anthropic contributions to air quality. On the contrary, the high levels of Polycyclic Aromatic Hydrocarbons found in Taranto sampling sites suggested that PAHs can be a better indicator for this purpose. This result is also relevant in order to weigh the importance of industrial area and to suggest right policy control to decision makers.  相似文献