Ozone production due to emissions from vegetation burning     

Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献   

Variscan ore formation and metamorphism at the Felbertal scheelite deposit (Austria): constraining tungsten mineralisation from Re–Os dating of molybdenite     

Johann G. Raith  Holly J. Stein 《Contributions to Mineralogy and Petrology》2006,152(4):505-521

The Felbertal scheelite deposit in the Eastern Alps has been regarded as the type locality for stratabound scheelite deposits. It is hosted by a Cambro-Ordovician metavolcanic arc sequence with minor Variscan granitoids (∼ 340 Ma) in the central Tauern Window. Re–Os model ages for molybdenite from the Felbertal tungsten deposit range between ∼ 358 and ∼ 336 Ma and record several pulses of magmatic-hydrothermal-metamorphic molybdenite formation. Molybdenite ages from the K2 orebody, a scheelite-rich quartz mylonite in the Western ore field, indicate that both mineralisation and mylonite are Variscan in age and suggest that the shear zone was active for ∼ 20 million years. Early stage tungsten mineralisation (Scheelite 1) in quartzitic ores in the Eastern ore field, which is free of molybdenite, yielded very low to near blank levels of Re and Os and thus could not be dated. However, molybdenite from scheelite–quartz stringers, previously interpreted as a feeder stockwork to quartzitic scheelite ore of presumed Cambrian age, yielded Variscan Re–Os ages of ∼ 342 and ∼ 337 Ma. Dating of molybdenite contained in scheelite ores thus far provides no indication of a Cambrian component to the tungsten mineralisation. Our data are consistent with a model of either granite intrusion-related ore formation and coeval metamorphic overprint during the Early Carboniferous or, alternatively, molybdenite formation may be exclusively attributed to Variscan metamorphism (see Stein 2006).  相似文献   

Fluid overpressure in layered intrusions: formation of a breccia pipe in the Eastern Bushveld Complex, Republic of South Africa     

Sonja L. Boorman  James B. McGuire  Alan E. Boudreau  Johann F. Kruger 《Mineralium Deposita》2003,38(3):356-369

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Assimilating continental mean temperatures to reconstruct the climate of the late pre-industrial period     

Anastasios Matsikaris  Martin Widmann  Johann Jungclaus 《Climate Dynamics》2016,46(11-12):3547-3566

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Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria     

Falk Händel  Gaisheng Liu  Johann Fank  Franz Friedl  Rudolf Liedl  Peter Dietrich 《Hydrogeology Journal》2016,24(8):2079-2091

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.  相似文献   

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite     

Sven-Ulf Weber  Michael Grodzicki  Werner Lottermoser  Günther J. Redhammer  Gerold Tippelt  Johann Ponahlo  Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.  相似文献   

Parameterisation of the vertical transport in a small thermally stratified lake     

Christoph von Rohden  Karl Wunderle  Johann Ilmberger 《Aquatic Sciences - Research Across Boundaries》2007,69(1):129-137

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Depth–transport functions and erosion–deposition diagrams as indicators of slope inclination and time-averaged traction forces: applications in tropical reef environments     

Johann Hohenegger  & Elza Yordanova 《Sedimentology》2001,48(5):1025-1046

The trigonometric relationship between slope inclination, the horizontally acting time‐averaged traction force and the vertical depth of transport allows the estimation of one factor, when both others are known. Depth–transport functions can be deduced by comparing the depth distributions of living organisms and their skeletal remains, and this paper simplifies this comparison using foraminifera in which a single test represents an individual. Differences in distribution parameters between living individuals and empty tests allow depth–transport functions to be determined; these functions differ between species at a single transect according to the varying buoyancies of the tests. Within a single species, differences in depth–transport functions between locations are based on either slope inclination or traction intensities. After establishing a mean depth–transport function by averaging species‐characteristic functions, the time‐averaged traction force acting on the studied transect can be calculated. Transport intensities are also estimated using an erosion–deposition diagram that combines the relative frequency distributions of living individuals and empty tests. The proportion of ‘eroded’, ‘parautochthonous’ and ‘allochthonous’ tests mirrors the influence of both slope inclination and traction force for the deposition of empty tests. To test the model, six species of symbiont‐bearing benthic foraminifers were investigated at two transects in front of a NW Pacific coral reef. One transect is distinguished by a strong slope flattening below the steep reef slope (30 m), whereas further steepening characterizes the equivalent part in the other transect. These differences are mirrored in the depth–transport functions as well as in the erosion–deposition diagrams of all species. The time‐averaged traction forces differ in intensities between transects, because of the position of the reef front with respect to the predominant wind direction. However, the form of the functions is identical and distinguished by an increase from the surface to 35 m depth, followed by a decrease down to 105 m. This can be explained by successive onshore and offshore forces acting on the shallow slope, such as the tropical cyclones that cross the region every summer.  相似文献   

GIOVE-A initial signal analysis     

Oliver Montenbruck  Christoph Günther  Sebastian Graf  Miquel Garcia-Fernandez  Johann Furthner  Hanspeter Kuhlen 《GPS Solutions》2006,10(2):146-153

In late December 2005 the GIOVE-A test satellite was launched by the European Space Agency (ESA) to secure the frequencies for the Galileo system and to provide a platform for testing the new navigation signals. We performed an initial assessment of these signals using the 30 m deep space antenna of the DLR ground station in Weilheim (Germany). The antenna gain raised the signals above the noise level, thus allowing a detailed analysis even without knowledge of the ranging codes. The present paper covers the analysis of the L1/E1 signals, which includes a discussion of the spectrum, the time domain signal and a decoding of the spreading codes for the Open Service.  相似文献   

A Reanalysis and Reinterpretation of Geodetic and Geological Evidence of Glacial-Isostatic Adjustment in the Churchill Region, Hudson Bay     

Detlef Wolf  Volker Klemann  Johann Wünsch  Fei-peng Zhang 《Surveys in Geophysics》2006,27(1):19-61

We review the historical, geological, tide-gauge, GPS and gravimetric evidence advanced in favour of, or against, continuing land uplift around Hudson Bay, Canada. We also reanalyse the tide-gauge and GPS data for Churchill using longer time series than those available to previous investigators. The dependence of the mean rate of relative sea-level change obtained from the tide-gauge record on the length and mid-epoch of the observation interval considered is investigated by means of a newly developed linear-trend analysis diagram. For studying the shorter-period variability of the tide-gauge record, the wavelet transform is used. The mean rate of land uplift obtained from GPS is based on a new analysis using IGS solutions of GFZ. To include the post-glacial land uplift, sea-level indicators from the Churchill region representing the relative sea-level history during the past 8000 years are also used. Finally, the values of the four observables are jointly inverted in terms of mantle viscosity. The optimum values are ~3.2 × 10²⁰ Pa s and ~1.6 × 10²² Pa s for the upper- and lower-mantle viscosities, respectively.  相似文献