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1.
运用电子探针和显微Fourier变换红外光谱技术，对新疆西天山3个榴辉岩样品中的石榴石进行了详细的主量元素和结构水分析。结果显示，石榴石发育以核部富锰铝榴石组分、边部富镁铝榴石组分进变质作用的成分环带。石榴石中OH^-1分布也具有规律：核部→边缘。其结构水OH^-1逐步增加，即从核部的89-239ppm增加到边部的367-658ppm；与石榴石边部相比，石榴石的核部含有较低的OH^-1，却含有较高的H2O和Mn含量。这表明，在蓝片岩向榴辉岩进变质作用过程中，含水矿物脱水反应而释放出大量的分子水，这部分水促进了高压变质反应，形成榴辉岩相矿物，石榴石核部的结晶就是在富水和Mn的条件下进行的。随着高压变质作用的继续，石榴石核部的分子水逐步失水而进入石榴石晶格，形成结构水。因此，在高压变质作用过程中，OH^-1演化实际上是一个由内部不平衡逐步向平衡转变过程。P588．348 相似文献
2.
Ultrahigh-Temperature Metamorphism and Multistage Evolution of Garnet-Orthopyroxene Granulites from the Proterozoic Epupa Complex, NW Namibia 总被引：2，自引：0，他引：2
Migmatitic semipelitic granulites of the Proterozoic Epupa Complex,NW Namibia, underwent ultrahigh-temperature metamorphism asis indicated by the high alumina contents of orthopyroxene (8–11wt % Al2O3) coexisting with garnet. Peak P–T conditionsof 相似文献
3.
M. BRÖCKER R. KLEMD M. COSCA W. BROCK A. N. LARIONOV N. RODIONOV 《Journal of Metamorphic Geology》2009,27(5):385-403
The Orlica–?nie?nik complex (OSC) is a key geological element of the eastern Variscides and mainly consists of amphibolite facies orthogneisses and metasedimentary rocks. Sporadic occurrences of eclogites and granulites record high‐pressure (HP) to ultrahigh‐pressure (UHP) metamorphic conditions. A multimethod geochronological approach (40Ar–39Ar, Rb–Sr, Sm–Nd, U–Pb) has been used to gain further insights into the polymetamorphic evolution of eclogites and associated country rocks. Special attention was given to the unresolved significance of a 370‐ to 360 Ma age group that was repeatedly described in previous studies. Efforts to verify the accuracy of c. 370 Ma K–Ar phengite and biotite dates reported for an eclogite and associated country‐rock gneiss from the location Nowa Wie? suggest that these dates are meaningless, due to contamination with extraneous Ar. Extraneous Ar is also considered to be responsible for a significantly older 40Ar–39Ar phengite date of c. 455 Ma for an eclogite from the location Wojtowka. Attempts to further substantiate the importance of 370–360 Ma zircon dates as an indicator for a melt‐forming high‐temperature (HT) episode did not provide evidence in support of anatectic processes at this time. Instead, SHRIMP U–Pb zircon dating of leucosomes and leucocratic veins within both orthogneisses and (U)HP granulites revealed two age populations (490–450 and 345–330 Ma respectively) that correspond to protolith ages of the magmatic precursors and late Variscan anatexis. The results of this study further underline the importance of Late Carboniferous metamorphic processes for the evolution of the OSC that comprise the waning stages of HP metamorphism and lower pressure HT overprinting with partial melting. Eclogites and their country rocks provided no chronometric evidence for an UHP and ultrahigh‐temperature episode at 387–360 Ma, as recently suggested for granulites from the OSC, based on Lu–Hf garnet ages ( Anczkiewicz et al., 2007 ). 相似文献
4.
The evolution of the mineral assemblages and P–T conditions during partial melting of upper‐amphibolite facies paragneisses in the Orue Unit, Epupa Complex, NW Namibia, is modelled with calculated P–T–X phase diagrams in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O system. The close concordance of predictions from the phase diagrams to petrographic observations and thermobarometric results documents that quantitative phase diagrams are suitable to explain the phase relationships in migmatitic upper‐amphibolite facies low‐ and medium‐pressure metapelites, which occur in many high‐grade metamorphic terranes worldwide. Different mineral assemblages in the migmatitic metapelites of the Orue Unit reflect regional discrepancies in the metamorphic grade: in a Northern Zone, early biotite–sillimanite–quartz assemblages were replaced via melt‐producing reactions by cordierite‐bearing assemblages. In a Southern Zone, they were replaced via melt‐producing reactions by garnet‐bearing assemblages while cordierite is restricted to rare metapelitic granofelses, which preserve Grt–Sil–Crd–Bt peak assemblages. Peak‐metamorphic conditions of 700–750 °C at 5.5–6.7 kbar in the Southern Zone and of ～750 °C at 4.5 kbar in the Northern Zone are estimated by integrating thermobarometric calculations with data from calculated mineral composition isopleths. Retrograde back‐reactions between restite and crystallizing melt are recorded by the replacement of garnet by biotite–sillimanite and/or biotite–muscovite intergrowths. Upper‐amphibolite facies metamorphism and partial melting (c. 1340–1320 Ma) in the rocks of the Southern Zone of the Orue Unit, which underwent probably near‐isobaric heating–cooling paths, are attributed to contact metamorphism induced by the coeval (c. 1385–1319 Ma) emplacement of the Kunene Intrusive Complex, a huge massif‐type anorthosite body. The lower‐pressure metapelites of the Northern Zone are interpreted to record contact metamorphism at an upper crustal level. 相似文献
5.
俯冲带是地球上岩浆活动、高压—超高压变质作用、中深源地震、壳幔物质交换、元素循环和铜金大规模成矿的集中发生场所。富水流体不仅调控了这些地质作用,而且也深刻影响了全球C、S等挥发分的循环。当蚀变大洋岩石圈及上覆沉积物进入俯冲带中深部（15~300 km）,伴随由葡萄石- 绿纤石相至超高压榴辉岩相的递进变质作用,含水矿物在不同深度的分解造成流体释放为一连续过程。除极端高地温梯度环境之外,大多数俯冲带洋壳释放的流体为富水流体。但,俯冲带不同深度所产生的流体特征有明显差异。出露于全球造山带的高压—超高压变质地体保存了分凝体、脉体、水压致裂角砾岩等流体作用的有力证据,绿辉石、石榴子石、绿帘石等矿物中原生流体包裹体为流体的直接记录。在俯冲带中等深度（＜65 km）,流体是溶质含量很低的含卤化物水溶液,可含CO2-3、SO2-4、HS-等组分,其所含Si、Al、Ca、Mg、Fe、Na主量元素溶质相当于海水中固化物量的2~3倍,并具大离子亲石元素（LILE）、轻元素（B、Li）富集和高场强元素（HFSE）亏损的特点。当深度≥65 km时,流体转化为类似于超临界性质的溶液,含CH4、C2H6、H2S等挥发分,其所含主量元素溶质显著增加,微量元素除LILE等外,还负载相当量的HFSE和过渡族成矿元素。俯冲带65~100 km深度,为富水流体向超临界流体转变的区间。这种流体具有“亚超临界”性质,发生了氧化还原性质和元素溶解能力的渐变,并伴随硬柱石和角闪石的最终耗尽。高压变质岩石及相关脉体的O、Sr、Nd和金属同位素示踪研究表明俯冲带流体的源区多样,有蚀变基性洋壳、地幔橄榄岩和沉积物,并保存了海底热液蚀变作用的印迹。流体以脉冲方式沿网络状裂隙呈隧道式运移和传输,规模可达千米级,时间尺度在数月至数百年。目前通过高压—超高压变质岩的研究对俯冲带流体已经有了深入的了解,但展望未来,该领域依然有诸多争议和科学问题值得探索。 相似文献
6.
俯冲洋壳的脱水作用对于岛弧火山岩的成因具有重要意义。西天山高压低温变质带中切割主岩蓝片岩/榴辉岩的榴辉岩相脉体记录了古生代俯冲带中的脱水过程。脉体具有典型高压矿物组合：石榴石(＞8%)+绿辉石(15%)+石英(＞55%)+蓝闪石(5%)+冻蓝闪石(10%)±黝帘石±方解石。高压脉及其主岩的岩相学与矿物化学研究表明流体是在俯冲过程中蓝片岩向榴辉岩进变质条件下释放。脉的主量元素成分显示流体富Si。主岩的稀土元素和微量元素表明其原岩为洋岛玄武岩(OIB)。脉和主岩具有相似的微量元素配分模式,并且相对N-MORB都显示富Li、Be、Cs、Rb、Ba、Pb、La的特点。通过模拟计算,在高压脉、与脉平衡的流体以及模拟的原生流体中都富集流体活动性元素(Li、Be、Pb)和LILE(Cs、Rb、Ba),贫HFSE(Nb)和REE(Nd、Sm)。证实了在古生代南天山洋俯冲时洋岛玄武岩脱水释放出富Li、Be、LILE、La和Pb,贫HFSE和HREE的流体。 相似文献
7.
Reaction textures and fluid behaviour in very high pressure calc-silicate rocks of the Münchberg gneiss complex, Bavaria, Germany 总被引：2，自引：0，他引：2
Calc-silicate rocks occur as elliptical bands and boudins intimately interlayered with eclogites and high-pressure gneisses in the Münchberg gneiss complex of NE Bavaria. Core assemblages of the boudins consist of grossular-rich garnet, diopside, quartz, zoisite, clinozoisite, calcite, rutile and titanite. The polygonal granoblastic texture commonly displays mineral relics and reaction textures such as post kinematic grossular-rich garnet coronas. Reactions between these mineral phases have been modelled in the CaO-Al2O3-SiO2-CO2-H2O system with an internally consistent thermodynamic data base. High-pressure metamorphism in the calc-silicate rocks has been estimated at a minimum pressure of 31 kbar at a temperature of 630d? C with XH2, O ≥ 0.03. Small volumes of a CO2-N2-rich fluid whose composition was buffered on a local scale were present at peak-metamorphic conditions. The P-T conditions for the onset of the amphibolite facies overprint are about 10 kbar at the same temperature. XCo2 of the H2O-rich fluid phase is regarded to have been <0.03 during amphibolite facies conditions. These P-T estimates are interpreted as representing different stages of recrystallization during isothermal decompression. The presence of multiple generations of mineral phases and the preservation of very high-pressure relics in single thin sections preclude pervasive post-peak metamorphic fluid flow as a cause of a re-equilibration within the calc-silicates. The preservation of eclogite facies, very high-pressure relics as well as amphibolite facies reactions textures in the presence of a fluid phase is in agreement with fast, tectonically driven unroofing of these rocks. 相似文献
8.
A petrogenetic grid in the model system CaO–FeO–MgO–Al2O3–SiO2–H2O is presented, illustrating the phase relationships among the minerals grunerite, hornblende, garnet, clinopyroxene, chlorite, olivine, anorthite, zoisite and aluminosilicates, with quartz and H2O in excess. The grid was calculated with the computer software thermocalc , using an upgraded version of the internally consistent thermodynamic dataset HP98 and non‐ideal mixing activity models for all solid solutions. From this grid, quantitative phase diagrams (P–T pseudosections) are derived and employed to infer a P–T path for grunerite–garnet‐bearing amphibolites from the Endora Klippe, part of the Venetia Klippen Complex within the Central Zone of the Limpopo Belt. Agreement between calculated and observed mineral assemblages and garnet zonation indicates that this part of the Central Zone underwent a prograde temperature and pressure increase from c. 540 °C/4.5 kbar to 650 °C/6.5 kbar, followed by a post‐peak metamorphic pressure decrease. The inferred P–T path supports a geotectonic model suggesting that the area surrounding the Venetia kimberlite pipes represents the amphibolite‐facies roof zone of migmatitic gneisses and granulites that occur widely within the Central Zone. In addition, the P–T path conforms to an interpretation that the Proterozoic evolution of the Central Zone was controlled by horizontal tectonics, causing stacking and differential heating at c. 2.0 Ga. 相似文献
9.
那拉提山北缘寒武纪玄武岩的元素地球化学特征及构造意义 总被引：3，自引：2，他引：3
我国西南天山地区那拉提北缘断裂北侧出露寒武纪（516.3±7.4Ma）橄榄拉斑玄武岩，其Al2O3（120.71％-14.14％）、P2O5（0.09％-0．21％）含量较低，TiO2（1.39％-2．35％）、MgO（5.35％-8.14％）含量中等，全Fe2O3（11.74％-16．03％）含量较高，球粒陨石标准化稀土分布型式平坦，（La／Sm）.和（Y／Nb）.比值接近1，为过渡型洋脊玄武岩（T-MORB）；并且Th／Ta比值（0．8—1.5）低，高场强元素（Nb，Ta，Zr，Hf，P）没有明显亏损，缺乏陆壳混染或俯冲带流体活动的印迹.部分T-MORB的Fe、Ti含量较高（FeO^T〉12％，TiO2〉2％，FeO^T／MgO〉1．75），Mg^#值（0．40—0.49）和Cr（53×10^-6-110×10^-6）含量较低，属于Fe-Ti玄武岩（ferrobasalt），应为岩浆依Fenner趋势发生较高程度结晶分离演化的产物，很可能形成于洋中脊的扩展型裂谷环境.我们认为，那拉提北缘寒武纪T-MORB和Fe-n玄武岩可能与境外吉尔吉斯斯坦境内北天山南缘的旱古生代Terskey蛇绿岩带相连，为Terskey蛇绿岩的残片；寒武纪我国境内发育Terskey洋.那拉提北缘断裂可能与尼古拉耶夫线相连，代表西南天山地区Terskey洋闭合形成的一条早古生代缝合带. 相似文献
10.
南天山：晚古生代还是三叠纪碰撞造山带？ 总被引：56，自引：42，他引：56
伊犁-哈萨克斯坦板块和塔里木-卡拉库姆板块之间的南天山造山带是‘中亚型造山带’的典型代表之一，经历了复杂的构造演化与地壳增生过程。传统上，它被视为华力西期褶皱带或晚古生代碰撞造山带。但近年来，部分学者提出它可能为三叠纪碰撞造山带。本文在综述南天山造山带的蛇绿岩、高压变质岩、花岗岩类等方面研究成果的基础上，讨论了其碰撞造山的时限。我国境内南天山西段碰撞造山可能开始于早石炭世（345Ma），结束于晚石炭世末（300Ma左右）。二叠纪时期，南天山至整个中亚地区进入后碰撞演化阶段。现有资料证实南天山为一晚古生代碰撞造山带，并非一三叠纪碰撞造山带。 相似文献