High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile     

Cristián Frêne  Juan J. Armesto  Freddy Véliz  Fernando D. Alfaro  Kathleen C. Weathers 《水文研究》2021,35(5):e14175

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.  相似文献   

Origin and evolution of the Steamboat Springs siliceous sinter deposit, Nevada, U.S.A.     

Bridget Y. Lynne  Kathleen A. Campbell  Joseph Moore  P.R.L. Browne   《Sedimentary Geology》2008,210(3-4):111-131

Siliceous hot spring deposits from Steamboat Springs, Nevada, U.S.A., record a complex interplay of multiple, changing, primary environmental conditions, fluid overprinting and diagenesis. Consequently these deposits reflect dynamic geologic and geothermal processes. Two surface sinters were examined—the high terrace, and the distal apron-slope, as well as 13.11 m (43 ft) of core material from drill hole SNLG 87-29. The high terrace sinter consists of vitreous and massive-mottled silica horizons, while the distal deposit and core comprise dominantly porous, indurated fragmental sinters. Collectively, the three sinter deposits archive a complete sequence of silica phase diagenetic minerals from opal-A to quartz. X-ray powder diffraction analyses and infrared spectroscopy of the sinters indicate that the distal apron-slope consists of opal-A and opal-A/CT mineralogy; the core yielded opal-A/CT and opal-CT with minor opal-A; and the high terrace constitutes opal-C, moganite, and quartz. Mineralogical maturation of the deposit produced alternating nano–micro–nano-sized silica particle changes. Based on filament diameters of microbial fossils preserved within the sinter, discharging thermal outflows fluctuated between low-temperatures (< 35 °C, coarse filaments) and mid-temperatures ( 35–60 °C, fine filaments). Despite transformation to quartz, primary coarse and fine filaments were preserved in the high terrace sinter. AMS ¹⁴C dating of pollen from three horizons within core SNLG 87-29, from depths of 8.13 to 8.21 m (26′8″ to 26′11″), 10.13 to 10.21 m (33′3″ to 33′6″), and 14.81 to 14.88 m (48′7″ to 48′10″), yielded dates of 8684 ± 64 years, 11,493 ± 70 years and 6283 ±60 years, respectively. In the upper section of the core, the stratigraphically out-of-sequence age likely reflects physical mixing of younger sinter with quartzose sinter fragments derived from the high terrace. Within single horizons, mineralogical and morphological components of the sinter matrix were spatially patchy. Overall, the deposit was modified by sub-surface flow of alkali-chloride thermal fluids depositing a second generation of silica, and periodically, by acidic steam condensate formed during periods when the water table was low. Local faulting produced considerable fracturing of the sinter. Hence, the Steamboat Springs sinter experienced a complex history of primary and secondary hydrothermal, geologic and diagenetic events, and their inter-relationships and effects are locked within the physical, chemical and biological signatures of the deposit.  相似文献   

Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers     

Kathleen A. Radloff  Anya R. Manning  Brian Mailloux  Yan Zheng  M. Moshiur Rahman  M. Rezaul Huq  Kazi M. Ahmed  Alexander van Geen 《Applied Geochemistry》2008

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.  相似文献   

The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C     

Rabindra N Roy  Lakshimi N Roy  Kathleen M Vogel  C Porter-Moore  Tara Pearson  Catherine E Good  Frank J Millero  Douglas M Campbell 《Marine Chemistry》1993,44(2-4)

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell: where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell: The results have been fitted to the equations: where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.  相似文献   

The intersection of the Siqueiros Transform Fault and the East Pacific Rise     

Kathleen Crane 《Marine Geology》1976,21(1):25-46

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Why did ancient chemosynthetic seep and vent assemblages occur in shallower water than they do today? Comment     

Crispin T. Little  Kathleen A. Campbell  Richard J. Herrington 《International Journal of Earth Sciences》2002,91(1):149-153

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Paleoliquefaction study of the Clarendon–Linden fault system, western New York State     

Martitia P. Tuttle  Kathleen Dyer-Williams  Noel L. Barstow 《Tectonophysics》2002,353(1-4)

The lack of earthquake-induced liquefaction features in Late Wisconsin and Holocene sediments in Genesee, Wyoming, and Allegany Counties suggests that the Clarendon–Linden fault system (CLF) did not generate large, moment magnitude, M≥6 earthquakes during the past 12,000 years. Given that it was the likely source of the 1929 M 4.9 Attica earthquake, however, the Clarenden–Linden fault system probably is capable of producing future M5 events. During this study, we reviewed newspaper accounts of the 1929 Attica earthquake, searched for earthquake-induced liquefaction features in sand and gravel pits and along tens of kilometers of river cutbanks, evaluated numerous soft-sediment deformation structures, compiled geotechnical data and performed liquefaction potential analysis of saturated sandy sediments. We found that the 1929 M 4.9 Attica earthquake probably did not induce liquefaction in its epicentral area and may have been generated by the western branch of the Clarendon–Linden fault system. Most soft-sediment deformation structures found during reconnaissance did not resemble earthquake-induced liquefaction features, and even the few that did could be attributed to non-seismic processes. Our analysis suggests that the magnitude threshold for liquefaction is between M 5.2 and 6, that a large (M≥6) earthquake would liquefy sediments at many sites in the area, and that a moderate earthquake (M 5–5.9) would liquefy sediments at some sites but perhaps not at enough sites to have been found during reconnaissance. We conclude that the Clarendon–Linden fault system could have produced small and moderate earthquakes, but probably not large events, during the Late Wisconsin and Holocene.  相似文献   

Paleoecology of a Middle Wisconsin Deposit from Southern California     

R. Scott Anderson  Mitchell J. Power  Susan J. Smith  Kathleen Springer  Eric Scott 《Quaternary Research》2002,58(3):310

Analysis of a buried deposit in the Diamond Valley of southern California has revealed well-preserved pollen, wood, and diatom remains. Accelerator mass spectrometry dates of 41,200±2100 and 41,490±1380 ¹⁴C yr B.P. place this deposit in marine isotope stage 3. Diatoms suggest a shallow lacustrine environment. Pollen data suggest that several plant communities were present near the site, with grassland, scrub, chaparral, forest, and riparian communities represented. Comparison with modern pollen suggests similarities with montane forests in the nearby San Bernardino and San Jacinto ranges, indicating vegetation lowering by at least 900 m elevation and temperatures 4°–5°C cooler than today. An increase in high-elevation conifer pollen documents climatic cooling near the profile top. Early-profile diatoms are typical of warm water with high alkalinity and conductivity, whereas later diatoms suggest a higher flow regime and input of cooler water into the system. We suggest that the sequence is part of the cooling phase of an interstadial Dansgaard–Oeschger cycle. Records of the middle Wisconsin period are rare in southern California, but the Diamond Valley site is similar to records from Tulare Lake in the San Joaquin Valley and the ODP Site 893A record from Santa Barbara Basin. It is probable that the Diamond Valley assemblage is a local expression of a vegetation type widespread in the ranges and basins of southwestern California during the middle Wisconsin.  相似文献   

Transfer of Taiwanese ideas and technology to The Gambia, West Africa: a viable approach to rural development?   总被引：1，自引：0，他引：1  

Kathleen M Baker  Richard Louis Edmonds 《The Geographical journal》2004,170(3):189-211

The development of Taiwan's agricultural sector contributed significantly to the country's transformation from virtual poverty after World War II to a modern industrial nation. Success resulted from the use of appropriate technologies, developed through an exceptionally close working relationship between government, research and development institutions, extension services and farmers in Taiwan. As part of their overseas development aid programme, the Republic of China on Taiwan has established Technical Missions in those developing countries where it receives political recognition. Among these is The Gambia, West Africa, where one focus of Taiwan's current Technical Mission is the development of women's market gardens. Although the gardens have proved successful, there is doubt as to whether their achievements will be sustained once Taiwan's Technical Mission in The Gambia has ended. Field research in Taiwan and in The Gambia, based largely on participatory techniques, has revealed that the low-tech methods introduced from Taiwan are appropriate for the Gambian environment. However, much depends on whether women participating in the schemes can commit sufficient time and energy to the gardens, as at present this is a limiting factor. The potential of the gardens may also be constrained by a lack of appropriate institutional infrastructure, particularly the scope for profitable disposal of garden produce. A major conclusion of the article is that successful transfer of appropriate technology to The Gambia is likely to be impeded by poorly developed coordination between groups that proved to be key 'players' in the development of agriculture in Taiwan: government, research and development institutions, extension services and producers.  相似文献   

Developing Contradictions: Women's Participation as a Site of Struggle Within an Indian NGO*     

Kathleen O'Reilly 《The Professional geographer》2004,56(2):174-184

Women are being hired in increasing numbers by development projects to facilitate women's participation components. Once employed, however, women often find themselves marginalized within their organizations. In this paper, I find that the women's participation component of an Indian drinking water project has enabled the exclusion of women fieldworkers employed by the project. Drawing on the work of Bakhtin, I show participatory approaches as multiple, partial, and contentious. Moves to thwart women fieldworkers and women's participation give rise to struggles over development geography. Analysis of project records, interviews with staff, and observation of staff activities provide evidence for results.  相似文献