LREE distribution in perovskite,apatite and titanite from South West Ugandan xenoliths and kamafugite lavas     

F. E. Lloyd  A. D. Edgar  K. V. Ragnarsdottir 《Mineralogy and Petrology》1996,57(3-4):205-228

Summary In-situ microprobe LREE analyses of perovskite and titanite (La, Ce, Nd), and apatite (La, Ce), from SW Ugandan clinopyroxenite xenoliths and kamafugite lavas indicate that LREE distribution in these minerals is determined by a number of factors related to their different parageneses: In particular LREE content is affected by whether the LREE-bearing minerals have crystallised from metasomatic carbonate or from silicate (i.e. metasomatic or magmatic) melts in the mantle. In this situation LREE partition favours carbonate over silicate melts. Distribution of LREE in perovskite and apatite crystallised from magmatic mantle melts or mantle-derived lavas is chiefly determined by preference of LREE for perovskite > apatite > titanite. LREE zoning in perovskite is influenced by changes in melt structure: increasing melt polymerisation enhancing mineral_LREE/melt_LREE partition into perovskite rims in magmatic xenoliths; decreasing melt polymerisation depleting LREE in lava perovskite rims. This zoning is reinforced by perovskite competition with apatite for LREE: perovskite (cores/rims) co-crystallising with apatite is reduced in LREE. There are 37 instances of perovskitewith Ce below detection while La and Nd levels are normal. These occur in both xenoliths and lavas; in grain zones or whole grains. Likewise Ce alone of the LREE is below detection in six out of ten titanite analyses. These observations are interpreted as evidence for increased f_{O 2}, Ce⁴ + being excluded from these mineral structures. Recognition of these various processes can elucidate the interpretation of bulk rock and bulk mineral LREE signatures in kamafugite volcanism.

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LREE Verteilung in Perovskit, Apatit und Titanit aus Xenolithen und kamafugitischen Laven Südwest-Ugandas

Zusammenfassung In-situ LREE Analysen von Perovskit und Titanit (La, Ce, Nd) und Apatit (La, Ce) aus Klinopyroxenit-Xenolithen und kamafugitischen Laven Südwest-Ugandas zeigen, daß die LREE Verteilung in diesen Mineralen durch eine Vielzahl von Faktoren, die mit Unterschieden in den Paragenesen zusammenhängen, bestimmt wird: Der LREE-Gehalt wird im besonderen davon bestimmt, ob die LREE-führenden Minerale aus metasomatischen Karbonat- oder aus (metasomatischen oder magmatischen) Silikatschmelzen im Mantel auskristallisierten. Dabei erfolgt die LREE Fraktionierung zu Gunsten der Karbonatschmelzen. Die LREE-Verteilung von Perovskit und Apatit, die aus magmatischen Mantelschmelzen oder -laven kristallisierten, wird vorrangig durch den bevorzugten Einbau der LREE in Perovskit > Apatit > Titanit kontrolliert. Der LREE Zonarbau von Perovskit wird durch die Änderungen der Schmelzstruktur beinflußt: Verstärkte Schmelzpolymerisation führt zu verstärkter Mineral_LFEE/Schmelze_LREE Fraktionierung in den Perovskiträndern magmatischer Xenolithe, eine Abnahme der Schmelzpolymerisation hingegen resultiert in einer Abreicherung der LREE in den Perovskiträndern. Diese Art der Zonierung wird durch den Wettbewerb von Perovskit mit Apatit um die LREE verstärkt. Perovskit (Kerne/Ränder), der mit Apatit gemeinsam auskristallisierte, ist ärmer an LREE. 37 Fälle, in denenCe nicht nachweisbar war, La und Nd aber in normaler Konzentration auftreten, wurden sowohl in den Xenolithen als auch in den Laven gefunden; und zwar entweder in Kornbereichen oder in ganzen Körnern. Vergleichsweise liegt Ce nur in sechs von zehn Titanitproben unterhalb der Nachweisgrenze. Diese Beobachtungen werden als Hinweise auf erhöhte SauerstoffFugazitäten, bei denen Ce^4– aus der Mineralstruktur ausgeschlossen wird, angesehen.Ein Verständnis dieser verschiedenen Prozesse kann zur besseren Interpretation von LREE Gesamtgesteins- und Gesamtmineral-Signaturen in Kamafugiten beitragen.

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With 3 Figures  相似文献   

Surface effects of triggered fault slip on Reykjanes Peninsula, SW Iceland     

Amy E. Clifton  Carolina Pagli  Jna Finndís Jnsdttir  Kristjana Eythorsdttir  Kristin Vogfjr 《Tectonophysics》2003,369(3-4):145-154

Three large earthquakes (M_w>4.5) were triggered within 5 min, 85 km west of a M_w 6.5 earthquake in the South Iceland Seismic Zone (SISZ). We report on surface effects of these triggered earthquakes, which include fresh rupture, widespread rockfall, disrupted rockslides and block slides. Field data confirm that the earthquakes occurred along N-striking right-lateral strike-slip faults. Field data also support the conclusion from modeling of InSAR data that deformation from the second triggered event was more significant than for the other two. A major hydrological effect was the draining of water through an open fissure on a lake bed, lowering the lake level by greater than 4 m. Field relationships suggest that a component of aseismic slip could have been facilitated by water draining into the fault zone.  相似文献   

Ecophysiology of the saguaro cactus (Carnegiea gigantea) in the Saguaro National Monument: relationship to symptoms of decline     

Kate Lajtha  Kristin Kolberg  Jenna Getz 《Journal of Arid Environments》1997,36(4):579-590

The purpose of this study was to examine physiological correlates to the phenomenon of epidermal browning and saguaro decline in Saguaro National Monument. Gas exchange characteristics, surface temperatures, and the extent of epidermal browning in tissues of both healthy and declining saguaro cacti (Carnegiea gigantea) at different solar orientations were examined in eight long-term monitoring plots in the Rincon Mountain District of the Saguaro National Monument near Tucson, Arizona during both wet and dry seasons and years.Daily maximum surface temperatures were greatest on west-oriented tissues, as predicted by a simple model. However, south- and south-west-oriented tissues showed the highest browning indices, suggesting that browning may be more related to cumulative thermal loading than to extreme late afternoon temperature events. During the wet season, maximum nocturnal CO₂uptake rates and total nocturnal CO₂uptake were negatively correlated with browning index. Uptake rates during dry seasons and dry years was minimal, and not related to browning indices. However, healthy tissues of saguaros that also had tissues with high browning indices had wet-season maximum CO₂uptake rates as high as saguaros without damaged tissues, suggesting that the browning is not systemic but rather is tissue- and angle-specific. Instantaneous measures of water-use efficiency did not vary significantly or predictably by angle, but rather were greatest during night-time and in tissues when CO₂uptake was greatest. We suggest that browning symptoms on cacti are most likely due to natural abiotic stress, and are unrelated to systemic pollution stress or increased UV-B radiation.  相似文献   

Greenhouse Gas Emissions and Costs over the Life Cycle of Wood and Alternative Flooring Materials     

Ann Kristin Petersen  Birger Solberg 《Climatic change》2004,64(1-2):143-167

Increased use of wood can substitute more energy demanding products and thus contribute to a long-term solution to the global warming problem. The aim of this article is to provide an empirical study on this substitution impact, its cost-effectiveness, and which methodological assumptions that are of highest importance for the results obtained. We have made a case study where we compare use of various flooring materials. The results show that floor covering in solid oak causes lower greenhouse gas (GHG) emissions than the other materials. The difference can be ranked in the following order, after their potential for reduction in GHG emissions: Carpet in wool, carpet in polyamide, vinyl, and linoleum. At 2% pro anno discount rate, the avoided GHG emission in tons per m³ of oak flooring used is 0.1–1.9 for linoleum, and 11.8–15.5 for wool carpets. Unless the solution in solid oak is on total less expensive over the lifetime of the building, only the price of avoided emissions from a substitution between solid oak and carpet in wool is reasonable, compared to present carbon fees. The assumptions that influence the result most are choice of discount rate, carbon fixation on forest area, and waste handling. Empirical case studies like this indicate GHG emission reduction potentials caused by substitution, but should be complemented by dynamic input/output analyses and econometric studies. To analyse the flow of CO₂ over time, they should also be linked to forest management models.  相似文献   

Arsenic mobility in alteration products of sulfide-rich, arsenopyrite-bearing mine wastes, Snow Lake, Manitoba, Canada   总被引：2，自引：0，他引：2  

Kristin A. Salzsauler  Nikolay V. Sidenko  Barbara L. Sherriff 《Applied Geochemistry》2005,20(12):2303-2314

The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).  相似文献   

Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system,at Svartsengi,Iceland     

Kristín Vala Ragnarsdóttir  John V Walther  Stefán Arnórsson 《Geochimica et cosmochimica acta》1984,48(7):1535-1553

The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm³ is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO₂, 10 gm H₂S and 4 gm Na₂O and a release of 57 gm SiO₂, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K₂O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous.  相似文献   

A potentiometric study of Eu complexation with acetate ligand from 25 to 170°C at P_sat     

Alexander V Zotov  Boris R Tagirov  Igor I Diakonov  K.Vala Ragnarsdottir 《Geochimica et cosmochimica acta》2002,66(20):3599-3613

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A numerical simulation of residual circulation in Tampa Bay. Part I: Low-frequency temporal variations   总被引：1，自引：0，他引：1  

Steven D. Meyers  Mark E. Luther  Monica Wilson  Heather Havens  Amanda Linville  Kristin Sopkin 《Estuaries and Coasts》2007,30(4):679-697

The residual (time-average) salinity and circulation in a numerical ocean model of the Tampa Bay estuary are shown to experience significant temporal variation under realistic forcing conditions. A version of the Estuarine Coastal Ocean Model developed for Tampa Bay with 70 by 100 horizontal grid points and 11 sigma levels is examined for the years 2001–2003. Model output variables are averaged over the entire time of the simulation to generate long-term residual fields. The residual axial current is found to be dominated by the buoyancy-driven baroclinic circulation with an outflow (southwestward) at the surface and to the sides of the shipping channel, and an inflow (northeastward) usually occurring subsurface within or above the shipping channel. Averages over 30 d are used to examine variations in the residual fields. During the simulation the average surface salinity near the head of Tampa Bay varies with the freshwater inflow, from 12‰ to 33%. At the bay mouth salinity varies from 30%. to 36%.. A localized measure of the baroclinic circulation in the shipping channel indicates the residual circulation can vary strongly, attaining a magnitude triple the long-term mean value. The baroclinic circulation can be disrupted, going to near zero or even reversing, when the buoyancy-driven flow is weak and the surface winds are to the northeast. Three time periods, representing different environmental conditions, are chosen to examine these results in detail. A scaling argument indicates the relative strength of buoyancy versus wind as ΔρgH²(LC _Dω²)⁻¹, where δρ is head-to-mouth density difference across the bay,g is gravitational acceleration,H is depth,L is bay length,C _D is the surface wind drag coefficient, andw is wind speed. Tampa Bay is usually in the buoyancy dominated regime. The importance of winds in the weak-buoyancy case is demonstrated in an additional simulation without wind stress.  相似文献   

The role of horizontal impulses of the faulting continental slope in generating the 26 December 2004 tsunami     

Y. Tony Song  L.-L. Fu  Victor Zlotnicki  Chen Ji  Vala Hjorleifsdottir  C.K. Shum  Yuchan Yi 《Ocean Modelling》2008,20(4):362-379

For a long time, people have believed that the vertical displacement of seafloor due to undersea earthquakes is the primary cause of tsunami genesis. However, seismically-inverted seafloor deformation of the 2004 Sumatra–Andaman earthquake shows that the total vertical displacement is not enough to have generated the powerful Indian Ocean tsunami. Based on the seismically-inverted data and a three-dimensional ocean general circulation model (OGCM), we show that the momentum force, transferred by the horizontal impulses of the faulting continental slope in that earthquake, has accounted for two thirds of the satellite-observed tsunami height and generated kinetic energy 5 times larger than the potential energy due to the vertical displacement. The asymmetric tsunami pattern, recorded by tide-gauges showing leading-elevation waves toward Sri Lanka and leading-depression waves toward Thailand, is best explained by the horizontally-forced mechanism. The same mechanism has also explained the March 2005 Nias earthquake and tsunami data, suggesting that the horizontal motions of faulting have played more important roles in tsunami genesis than previously thought.  相似文献   

The 6dF Galaxy Survey: samples, observational techniques and the first data release     

D. Heath Jones  Will Saunders  Matthew Colless  Mike A. Read  Quentin A. Parker  Fred G. Watson  Lachlan A. Campbell  Daniel Burkey  Thomas Mauch  Lesa Moore  Malcolm Hartley  Paul Cass  Dionne James  Ken Russell  Kristin Fiegert  John Dawe  John Huchra  Tom Jarrett  Ofer Lahav  John Lucey  Gary A. Mamon  Dominique Proust  Elaine M. Sadler  Ken-ichi Wakamatsu 《Monthly notices of the Royal Astronomical Society》2004,355(3):747-763

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