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1.
Acta Geotechnica - The elastic stiffness of a fine sand at small to moderate strains ( $$\varepsilon \le 2 \times 10^{-4}$$ ) has been studied based on cyclic triaxial tests on cube-shaped samples...  相似文献   
2.
Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ11B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ11B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO2 and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   
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4.
In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ18O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ18O = ~15‰) to the rim (δ18O = ~11‰) suggests that the 18O/16O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the 18O/16O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ18O value of the garnet rim, together with the previously reported low δ18O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ18O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   
5.
Melting experiments of calcite were performed on the join CaCO3‐H2O at a pressure of 1000 bars. The system evolves to the ternary CaO‐H2O‐CO2 system during melting experiments. Our experiments show that partial melting of calcite begins at a low temperature, below 650 °C. Such a low partial melting temperature for carbonates revives the debate about the presence of carbonate melts in the upper crust. More specifically, the conditions for carbonate partial melting are present in carbonate host rocks undergoing contact metamorphism at high temperatures in the presence of water‐rich fluid. The presence of carbonate melts influences physical parameters such as viscosity and permeability in contact aureoles, and, furthermore, decarbonation reactions release massive amounts of CO2.  相似文献   
6.
The Martian meteorites comprise mantle‐derived mafic to ultramafic rocks that formed in shallow intrusions and/or lava flows. This study reports the first in situ platinum‐group element data on chromite and ulvöspinel from a series of dunitic chassignites and olivine‐phyric shergottites, determined using laser‐ablation ICP‐MS. As recent studies have shown that Ru has strongly contrasting affinities for coexisting sulfide and spinel phases, the precise in situ analysis of this element in spinel can provide important insights into the sulfide saturation history of Martian mantle‐derived melts. The new data reveal distinctive differences between the two meteorite groups. Chromite from the chassignites Northwest Africa 2737 (NWA 2737) and Chassigny contained detectable concentrations of Ru (up to ~160 ppb Ru) in solid solution, whereas chromite and ulvöspinel from the olivine‐phyric shergottites Yamato‐980459 (Y‐980459), Tissint, and Dhofar 019 displayed Ru concentrations consistently below detection limit (<42 ppb). The relatively elevated Ru signatures of chromite from the chassignites suggest a Ru‐rich (~1–4 ppb) parental melt for this meteorite group, which presumably did not experience segregation of immiscible sulfide liquids over the interval of mantle melting, melt ascent, and chromite crystallization. The relatively Ru‐depleted signature of chromite and ulvöspinel from the olivine‐phyric shergottites may be the consequence of relatively lower Ru contents (<1 ppb) in the parental melts, and/or the presence of sulfides during the crystallization of the spinel phases. The results of this study illustrate the significance of platinum‐group element in situ analysis on spinel phases to decipher the sulfide saturation history of magmatic systems.  相似文献   
7.
Renazzo‐type carbonaceous (CR) chondrites are accretionary breccias that formed last. As such they are ideal samples to study precompaction exposures to cosmic rays. Here, we present noble gas data for 24 chondrules and 3 dark inclusion samples (DIs) from Shi?r 033 (CR2). The meteorite was selected based on the absence of implanted solar wind noble gases and an anomalous oxygen isotopic composition of the DIs; the oxygen isotopes match those in CV3 and CO3 chondrites. Our samples contain variable mixtures of galactic cosmic ray (GCR)‐produced cosmogenic noble gases and trapped noble gases of presolar origin. Remarkably, all chondrules have cosmogenic 3He and 21Ne concentrations up to 4.3 and 7.1 times higher than the DIs, respectively. We derived an average 3He‐21Ne cosmic ray exposure (CRE) age for Shi?r 033 of 2.03 ± 0.20 Ma (2 SD) and excesses in cosmogenic 3He and 21Ne in chondrules (relative to the DIs) in the range (in 10?8 cm3STP/g) 3.99–7.76 and 0.94–1.71, respectively. Assuming present‐day GCR flux density, the excesses translate into average precompaction 3He‐21Ne CRE ages of 3.1–27.3 Ma depending on the exposure geometry. The data can be interpreted assuming a protracted storage of a single chondrule generation prior to the final assembly of the Shi?r 033 parent body in a region of the disk transparent to GCRs.  相似文献   
8.
This paper examines the oceanic response off Baja California, Mexico, to the 1997–1998 El Niño and the transition to La Niña conditions. The data presented were gathered during seven cruises over a grid based on the CalCOFI station plan, from lines 100–130, out to station 80. T–S diagrams with data obtained during the peak phase of El Niño, demonstrate that warmer and saltier (spicier) than normal conditions prevailed in the upper 600 m over this region. Temperature and salinity anomalies calculated for CalCOFI line 120 revealed waters near the coast at 50 m depth to be up to 8.7 °C warmer and S=0.8 saltier than the climatology during October 1997. These large anomalies persisted through January 1998, with some slight diminution in the magnitudes near the surface. This study suggests that anomalously warm and salty waters were fed from a source of spicy water to the southwest, identified as Subtropical Surface Water (StSW), and that low-salinity Tropical surface waters (TSW) were blocked to the southeast in the vicinity of the tip of the Peninsula. Subsurface waters associated with the California undercurrent (CU), fed from the Eastern Tropical Pacific (ETP), were also warmer and saltier than normal, and indicate a significant expansion in volume of the CU, presumably a result of intensification of poleward flow at depth. We postulate that the well defined near-surface and deep poleward flows in the study area reflect anomalous large-scale cyclonic circulation affecting the flow in the southeastern region of the North Pacific subtropical gyre east of 125°W. Following the El Niño event, warm and salty upper waters retreated to latitudes south of Punta Eugenia. With the return to normal and cooler conditions, equatorward flow over the sampling grid predominated with an increased meandering and mesoscale activity. Transition to La Niña conditions would have been associated with re-establishment of normal anticyclonic flow in the southeastern quadrant of the Pacific subtropical gyre.  相似文献   
9.
We investigate an overlooked mechanism—coastal upwelling—for sea surface temperature (SST) cooling in the western side of the mean location of the Pacific warm pool (WSWP: 5°S–5°N, 140°E–150°E) prior to El Niño onset. We analyze various observed data such as the TRIangle Trans-Ocean buoy Network (TRITON) moored buoy data, Conductivity-Temperature-Depth (CTD) data, satellite data and a hindcast experiment output by a high-resolution ocean general circulation model (OGCM). We focus on the precondition of the 2002/03 El Niño event, for which many datasets are available. Relatively cool water upwelled along the north coast of Papua New Guinea (PNG) during December 2001, prior to the onset of the 2002/03 El Niño event, and then spread out over a wider area to the northeast. Simultaneously, strong west-northerly surface winds occur along the north coast. Heat budget analysis of TRITON buoy data in the WSWP reveals that negative zonal heat advection due to eastward current is the main factor for cooling the mixed layer in the WSWP in contrast to the warming effect of the surface heat flux during the period. This cooling requires a source of colder water to the west. Similar analysis of OGCM outputs also suggests that the upwelled relatively cool water along the PNG north coast, and its northeastward extension to the equatorial region, contributes to cooling of the surface water over the WSWP mainly via negative zonal heat advection. Similar mechanisms are confirmed also for the 1982/83 and 1997/98 El Niño events by analyses of OGCM outputs and historical SST data. The low SST in the WSWP generated a positive zonal SST gradient together with high SST east of the WSWP. It may contribute to enhancement of the westerly surface wind in this region, leading to the onset of the 2002/03 El Niño event.  相似文献   
10.
A four-year record from an inverted echo sounder deployed near Palmyra Island at 6°N in the central Pacific Ocean is compared with a simultaneous record of subsurface pressure from this island lagoon. A factor m, converting round-trip acoustic travel time to surface dynamic height relative to a deep pressure level, was estimated from the ratio of the spectra of the two records in the energetic synoptic oscillation band. Year-to-year variation in m was not statistically significant. For the overall record, m was found to be -70±8 dynamic m/s, where the error bounds represent a 90% confidence interval. This is consistent with first-baroclinic-mode excitation  相似文献   
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