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1.
Despite the importance of organic-rich shales, microstructural characterization and theoretical modeling of these rocks are limited due to their highly heterogeneous microstructure, complex chemistry, and multiscale mechanical properties. One of the sources of complexity in organic-rich shales is the intricate interplay between microtextural evolution and kerogen maturity. In this study, a suite of experimental and theoretical microporomechanics methods are developed to associate the mechanical properties of organic-rich shales both to their maturity level and to the organic content at micrometer and sub-micrometer length scales. Recent results from chemomechanical characterization experiments involving grid nanoindentation and energy-dispersive X-ray spectroscopy (EDX) are used in new micromechanical models to isolate the effects of maturity levels and organic content from the inorganic solids. These models enable attribution of the role of organic maturity to the texture of the indented material, with immature systems exhibiting a matrix-inclusion morphology, while mature systems exhibit a polycrystal morphology. Application of these models to the interpretation of nanoindentation results on organic-rich shales allows us to identify unique clay mechanical properties that are consistent with molecular simulation results for illite and independent of the maturity of shale formation and total organic content. The results of this investigation contribute to the design of a multiscale model of the fundamental building blocks of organic-rich shales, which can be used for the design and validation of multiscale predictive poromechanics models.  相似文献   
2.
The excessive loss of soil nitrogen through drainage losses causes different environmental problems. The depth and spacing drain of drains play an important role in the quality and quantity of discharged drainage into the environment. In this paper, a simple but comprehensive model using system dynamic approach for water cycle and nitrogen dynamics was used to simulate the effect of drain depth and spacing on nitrate and ammonium losses in a sugarcane agro-industrial company. Twenty-four scenarios were modeled including the combination of four different drain depths and six drain spacing to compare the effect of drain depth and spacing on the nitrogen uptake by plant, denitrification, net mineralization, the amount of ammonium losses through runoff, nitrate and ammonium losses through drainage water, the sum of excessive water, the stress day index and the relative yield. The results indicated that optimal drainage system density is obtained in the depth of 1.1 m and spacing of 80 m, in a way that the total drainage losses would be reduced up to an acceptable level. The optimum designing of the drainage systems according to environmental criteria can control nitrogen pollution load at farm level and can therefore have appropriate results both in terms of economic and environmental considerations.  相似文献   
3.
A novel, simple, fast, and efficient ionic liquid‐based dispersive liquid–liquid extraction (IL‐DLLE) has been applied to extract and remove Congo Red (CR; a carcinogenic textile dye) from aqueous solutions. In this methodology a binary solution, containing the extraction solvent (1‐hexyl‐3‐methylimmidazolium bis(trifluormethylsulfonyl) imid) and a suitable disperser solvent, was rapidly injected into the water sample containing CR dye. Therewith, a cloudy solution was formed, and most of the dye molecules were extracted into fine IL droplets and removed from aqueous phase. The effects of pH, type, and amount of IL, initial concentration of the dye, type and volume of the dispersant, and concentrations of salt on the extraction of the dye were studied. Experimental surveys were also accomplished for recovery of the IL by applying a reverse dispersive liquid–liquid extraction using acidic stripping solutions.  相似文献   
4.
This paper presents a neural network approach to determine 2D inverse modeling of a buried structure from gravity anomaly profile. The results of the applied neural network method are compared with the results of two other methods, least-squares minimization and the simple method. Sphere, horizontal cylinder and vertical cylinder and their gravity effects are considered as the synthetic models and the synthetic data, respectively. The synthetic data are also corrupted with noise to evaluate the capability of the methods. Then the Dehloran bitumen map in Iran is chosen as a real data application. Anomaly value of the cross-section, which is taken from the gravity anomaly map of Dehloran bitumen, is very close to those obtained from these methods.  相似文献   
5.
Radon transform is a powerful tool with many applications in different stages of seismic data processing, because of its capability to focus seismic events in the transform domain. Three-parameter Radon transform can optimally focus and separate different seismic events, if its basis functions accurately match the events. In anisotropic media, the conventional hyperbolic or shifted hyperbolic basis functions lose their accuracy and cannot preserve data fidelity, especially at large offsets. To address this issue, we propose an accurate traveltime approximation for transversely isotropic media with vertical symmetry axis, and derive two versions of Radon basis functions, time-variant and time-invariant. A time-variant basis function can be used in time domain Radon transform algorithms while a time-invariant version can be used in, generally more efficient, frequency domain algorithms. Comparing the time-variant and time-invariant Radon transform by the proposed basis functions, the time-invariant version can better focus different seismic events; it is also more accurate, especially in presence of vertical heterogeneity. However, the proposed time-invariant basis functions are suitable for a specific type of layered anisotropic media, known as factorized media. We test the proposed methods and illustrate successful applications of them for trace interpolation and coherent noise attenuation.  相似文献   
6.
Estimation of reference evapotranspiration (ET0) in urban areas is challenging but essential in arid urban climates. To evaluate ET0 in an urban environment and non-urban areas, air temperature and relative humidity were measured at five different sites across the arid city of Isfahan, Iran, over 4 years. Wind speed and sunshine hours were obtained from an urban surrounding weather station over the same period and used to estimate ET0. Calculated ET0 was compared with satellite-based ET0 retrieved from the MOD16A2 PET product. Although MODIS PET was strongly correlated with the Valiantzas equation, it overestimated ET0 and showed average accuracy (r = 0.93–0.94, RMSE = 1.18–1.28 mm/day, MBE = 0.73–0.84 mm/day). The highest ET0 differences between an urban green space and a non-urban area were 1.1 and 0.87 mm/day, which were estimated by ground measurements and MODIS PET, respectively. The sensitivity of ET0 to wind speed and sunshine hours indicated a significant effect on cumulative ET0 at urban sites compared to the non-urban site, which has a considerable impact on the amount of irrigation required in those areas. Although MODIS PET requires improvement to accurately reflect field level microclimate conditions affecting ET0, it is beneficial to hydrological applications and water resource managers especially in areas where data is limited. In addition, our results indicated that using limited data methods or meteorological data from regional weather stations, leads to incorrect estimation of ET0 in urban areas. Therefore, decision-makers and urban planners should consider the importance of precisely estimating ET0 to optimize management of urban green space irrigation, especially in arid and semi-arid climates such as the city of Isfahan.  相似文献   
7.
This paper describes the application of magnetotelluric (MT) method to investigate Björkö impact structure located at west of Stockholm, Sweden. This structure has formed in crystalline rocks ca. 1.2 Ga ago and located relatively close to the district heating infrastructure of the Stockholm region, as the largest district heating system in Europe. Since impact structures mostly contain fractured rock volumes in the form of breccia formations, the occurred brecciation zones in this region are more favorable potential targets for geothermal investigations. The main objective is evaluating the capability of the study area to have potential for geothermal resources by mapping the subsurface structure. To image electrical characteristic of underground layers, 1D and 2D bimodal inversions of TE and TM modes of MT data are performed. The results are also compared with the outputs of the inversion of the determinant data (yielding a direction-independent average of the subsurface conductivity) along the same profiles, proving good accordance of the outputs. The processed resistivity sections at depth along with measuring various rock physical properties across two drilled boreholes at Björkö and Midsommar islands localized two conductors at depths of 1 km and from 2.5 to 4.5 km, which may be attributed to be a potential zone for geothermal energy retrieval.  相似文献   
8.
Forest fires are considered one of the most highly damaging and devastating of natural disasters, causing considerable casualties and financial losses every year. Hence, it is important to produce susceptibility maps for the management of forest fires so as to reduce their harmful effects. The purpose of this study is to map the susceptibility to forest fires over Nowshahr County in Iran, using an integrated approach of index of entropy (IOE) with fuzzy membership value (FMV), frequency ratio (FR), and information value (IV) with a comparison of their precision. The spatial database incorporated the inventory of forest fire and conditioning factors. As a whole, 41 forest fire locations were identified. Out of these, 29 locations (≈70%) were randomly chosen for the forest fire susceptibility modeling (FFSM), and the remaining 12 locations (≈30%) were utilized for the validation of the models. Subsequently, utilizing FMV‐IOE, FR‐IOE, and IV‐IOE models, forest fire susceptibility maps were acquired. Finally, the modeling ability of the models for FFSM was assessed using an area under the receiver operating characteristic (AUROC) curve. The results manifested that the prediction accuracy of the FMV‐IOE model is slightly higher than that of the FR‐IOE and IV‐IOE models. The incorporation of IOE with FMV, FR, and IV models had AUROC values of 0.890, 0.887, and 0.878, respectively. The resulting FFSM can be effective in fire repression resource planning, sustainable development, and primary warning in regions with similar conditions.  相似文献   
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